ChemicalBook > CAS DataBase List > (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- Product Name
- (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- CAS No.
- 443347-10-2
- Chemical Name
- (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- Synonyms
- (S)-Xyl-P-Phos;(S)-XYLYL-P-PHOS;(R)-XYLYL-P-PHOS;CTH-(S)-XYLYL-P-PHOS;CTH-(R)-XYLYL-P-PHOS;min.cth-(s)-xylyl-p-phos;(S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS&;(S)-(-)-2,2'',6,6''-Tetramethoxy-4,4''-bis(di(3,5-xylyl)phosphi;(S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE;(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- CBNumber
- CB1116203
- Molecular Formula
- C46H50N2O4P2
- Formula Weight
- 756.85
- MOL File
- 443347-10-2.mol
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(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Property
- Melting point:
- 158-162°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- white to pale yellow
- Water Solubility
- Sparingly soluble in water.
- CAS DataBase Reference
- 443347-10-2
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-36
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 675946
- Product name
- (S)-(?)-2,2′,6,6′-Tetramethoxy-4,4′-bis[di(3,5-xylyl)phosphino]-3,3′-bipyridine
- Purity
- 97%
- Packaging
- 100mg
- Price
- $89.2
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 675946
- Product name
- (S)-(?)-2,2′,6,6′-Tetramethoxy-4,4′-bis[di(3,5-xylyl)phosphino]-3,3′-bipyridine
- Purity
- 97%
- Packaging
- 500mg
- Price
- $261
- Updated
- 2023/06/20
Alfa Aesar
- Product number
- 044614
- Product name
- (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine
- Packaging
- 0.1g
- Price
- $73.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 044614
- Product name
- (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine
- Packaging
- 0.5g
- Price
- $311.65
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-5211
- Product name
- (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, min. 95% CTH-(S)-Xylyl-P-Phos
- Packaging
- 100mg
- Price
- $74
- Updated
- 2024/03/01
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(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Chemical Properties,Usage,Production
Chemical Properties
White solid
Uses
(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine is used in Pharmaceutical and industry applications.
Uses
Ligand employed in the asymmetic hydrogenation of ?-keto esters, 2-arylacrylates, aryl ketones , and other substrates.
Reactions
- Chiral ligand for the asymmetric hydrogenation of β-keto esters.
- Chiral ligand for enantioselective rhodium-catalyzed [2+2+2] carbocyclization reactions.
- Chiral ligand for ruthenium catalyzed hydrogenation of (E)-β-(acylamino)acrylates to β-amino acids.
- The Rhodium complex gives higher enantioselectivity for hydrogenation of (Z)-β-(acylamino)acrylates to β-amino acids.
- Chiral ligand for copper-catalyzed asymmetric hydrosilylation of ketones.
- Chiral ligand for asymmetric allylic substitution reactions using boronic acids as nucleophiles.
- Gives useful selectivity in asymmetric Pauson-Khand-type cyclizations.
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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