ChemicalBook > CAS DataBase List > 2-METHOXY-6-METHYLANILINE

2-METHOXY-6-METHYLANILINE

Product Name: 2-METHOXY-6-METHYLANILINE
CAS No.: 50868-73-0
Chemical Name: 2-METHOXY-6-METHYLANILINE
Synonyms: 6-METHYL-O-ANISIDINE;6-Methoxy-o-toluidine;2-Amino-3-methylanisole;2-METHOXY-6-METHYLANILINE;6-Methoxy-2-methylaniline;2-Methyl-6-methoxyaniline;2-Methoxy-6-methylaniline>2-Methoxy-6-methylbenzenamine;2-Methoxy-6-methylaniline 98%;2-Methoxy-6-methyl-phenylamine
CBNumber: CB1116915
Molecular Formula: C8H11NO
Formula Weight: 137.18
MOL File: 50868-73-0.mol

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2-METHOXY-6-METHYLANILINE Property

Melting point:: 26-29 °C (lit.)
Boiling point:: 62 °C/0.15 mmHg (lit.)
Density: 1.0630 (rough estimate)
refractive index: 1.5647 (estimate)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Methanol (Sparingly)
pka: 4.39±0.10(Predicted)
form: Solid
color: Clear Brown Oil to Pale Red to Dark Red
InChI: InChI=1S/C8H11NO/c1-6-4-3-5-7(10-2)8(6)9/h3-5H,9H2,1-2H3
InChIKey: HKOJYPPTIPJZAZ-UHFFFAOYSA-N
SMILES: C1(N)=C(C)C=CC=C1OC
CAS DataBase Reference: 50868-73-0

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
HS Code: 2922290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 360090
Product name: 2-Methoxy-6-methylaniline
Purity: 98%
Packaging: 5g
Price: $85
Updated: 2023/01/07

Sigma-Aldrich

Product number: 360090
Product name: 2-Methoxy-6-methylaniline
Purity: 98%
Packaging: 25g
Price: $127
Updated: 2023/01/07

TCI Chemical

Product number: M1804
Product name: 2-Methoxy-6-methylaniline
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $100
Updated: 2025/07/31

TCI Chemical

Product number: M1804
Product name: 2-Methoxy-6-methylaniline
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $401
Updated: 2025/07/31

TRC

Product number: M329148
Product name: 2-Methoxy-6-methylaniline
Packaging: 100mg
Price: $50
Updated: 2021/12/16

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2-METHOXY-6-METHYLANILINE Chemical Properties,Usage,Production

Uses

2-Methoxy-6-methylaniline may be used in the synthesis of 7-methoxy-1H-indazole, an inhibitor of nitric oxide synthase.

Synthesis

5345-42-6

50868-73-0

General procedure for the synthesis of 2-methoxy-6-methylaniline from 3-methyl-2-nitroanisole: Step A2; a) Preparation of intermediate 3: 1-methoxy-3-methyl-2-nitrobenzene (25 g, 149.7 mmol) was dissolved in ethanol (100 ml). 10% palladium/carbon catalyst (2.5 g) was added and the reaction mixture was subjected to hydrogenation at room temperature for 24 hours. Upon completion of the reaction, the catalyst was removed by diatomaceous earth filtration. The filtrate was concentrated under reduced pressure to give Intermediate 3 in a yield of 20.02 g (97% yield). The structure of intermediate 3 was confirmed by CI-MS with a molecular ion peak of 138 ([M + H]+).

References

[1] New Journal of Chemistry, 2006, vol. 30, # 2, p. 168 - 176
[2] Bioorganic and Medicinal Chemistry, 2008, vol. 16, # 6, p. 3309 - 3320
[3] Organic letters, 2000, vol. 2, # 3, p. 277 - 280
[4] Patent: WO2006/15985, 2006, A1. Location in patent: Page/Page column 54-55
[5] Journal of the Chemical Society, 1926, p. 1425

2-METHOXY-6-METHYLANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

2-Methoxy-6-methylbenzoic acid

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2-METHOXY-6-METHYLANILINE Suppliers

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View Lastest Price from 2-METHOXY-6-METHYLANILINE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-METHOXY-6-METHYLANILINE 50868-73-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-10

Career Henan Chemical Co

Product: 2-METHOXY-6-METHYLANILINE 50868-73-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98% HPLC
Supply Ability: 10 tons/month
Release date: 2020-01-08

50868-73-0, 2-METHOXY-6-METHYLANILINERelated Search:

Disperse Red 86 3-METHOXY-2-NITROBENZOIC ACID Methyl 2-amino-3,4,5-trimethoxybenzoate Actinomycin D DISPERSE VIOLET 26 3-Methyl-2-nitroanisole MEDINOTERB ACETATE METHYL 3-METHOXY-2-NITROBENZOATE Methyl 2-nitro-3,4,5-trimethoxybenzoate Disperse Red 11 2-AMINO-3,4,5-TRIMETHOXYBENZOIC ACID 3-Methoxy-2-nitrobenzaldehyde 5-Methoxy-2-methylaniline 4-Chloro-2-methoxy-N-methylaniline 96% 2-Methyl-4-methoxybenzenamine 2-Methoxy-4-methylaniline, HCl N-METHYL-P-ANISIDINE 3-METHOXY-N-METHYLANILINE

6-METHYL-O-ANISIDINE

2-METHOXY-6-METHYLANILINE

2-Methoxy-6-methyl-phenylamine

2-Amino-1-methoxy-3-methylbenzene

6-Methoxy-o-toluidine

2-Methoxy-6-methylbenzenamine

2-Methyl-6-methoxyaniline

6-Methoxy-2-methylaniline

2-Methoxy-6-methylaniline,6-Methyl-o-anisidine

BenzenaMine, 2-Methoxy-6-Methyl-

6-Methoxy-o-toluidine 2-Amino-1-methoxy-3-methylbenzene

2-Amino-3-methylanisole

2-Methoxy-6-methylaniline 98%

2-Methoxy-6-methylaniline&gt

2-METHOXY-6-METHYLANILINE ISO 9001：2015 REACH

50868-73-0

Building Blocks

Amines

Organic Building Blocks

Nitrogen Compounds

Amines

Building Blocks

Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks