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ChemicalBook > CAS DataBase List > Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

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Product Name
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
CAS No.
742103-27-1
Chemical Name
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Synonyms
Mo-Phos;cBRIDP[R];cBRIDP(regR);cBRIDP®cBRIDP(regR) >Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine;ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP;Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-
CBNumber
CB11181097
Molecular Formula
C24H33P
Formula Weight
352.49
MOL File
742103-27-1.mol
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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Property

Melting point:
87-91°C
Boiling point:
427.3±45.0 °C(Predicted)
form 
solid
color 
white to pale yellow
Sensitive 
air sensitive, store cold
CAS DataBase Reference
742103-27-1
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Safety

WGK Germany 
3
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

TCI Chemical
Product number
C2979
Product name
cBRIDP(regR)
Purity
>97.0%(HPLC)
Packaging
1g
Price
$117
Updated
2021/12/16
TCI Chemical
Product number
C2979
Product name
cBRIDP(regR)
Purity
>97.0%(HPLC)
Packaging
200mg
Price
$34
Updated
2021/12/16
Strem Chemicals
Product number
15-1005
Product name
Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP
Packaging
250mg
Price
$33
Updated
2021/12/16
Strem Chemicals
Product number
15-1005
Product name
Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP
Packaging
1g
Price
$98
Updated
2021/12/16
Strem Chemicals
Product number
15-1005
Product name
Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP
Packaging
5g
Price
$303
Updated
2021/12/16
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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties,Usage,Production

Reactions

  1. Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
  2. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
  3. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. 

Uses

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.

General Description

This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Preparation Products And Raw materials

Raw materials

Preparation Products

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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
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96815
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
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24529
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Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
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TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
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Bide Pharmatech Ltd.
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400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
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41462
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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China
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Chengdu Dianchun Technology Co., Ltd
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400-1166-196 18502815961
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QQ:800101999
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cdhxsj@163.com
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Amadis Chemical Company Limited
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571-89925085
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0086-571-89925065
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sales@amadischem.com
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China
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131957
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LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
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9ding chemical ( Shanghai) Limited
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021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19800
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742103-27-1, Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDPRelated Search:


  • Bis-(1,1-dimethylethyl)-(1-methyl-2,2-diphenylcyclopropyl)-phosphine
  • Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine
  • Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
  • ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane
  • Mo-Phos
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  • Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine
  • cBRIDP<sup>&reg
  • Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-
  • cBRIDP[R]
  • cBRIDP(regR) &gt
  • 742103-27-1
  • Achiral Phosphine
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