Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

Reactions

Product Name: Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
CAS No.: 742103-27-1
Chemical Name: Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Synonyms: Mo-Phos;cBRIDP[R];cBRIDP(regR);cBRIDP®cBRIDP(regR) >Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine;ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP;Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-
CBNumber: CB11181097
Molecular Formula: C24H33P
Formula Weight: 352.49
MOL File: 742103-27-1.mol

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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Property

Melting point:: 87-91°C
Boiling point:: 427.3±45.0 °C(Predicted)
form: solid
color: white to pale yellow
Sensitive: air sensitive, store cold
CAS DataBase Reference: 742103-27-1

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Safety

WGK Germany: 3
HS Code: 2931499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

TCI Chemical

Product number: C2979
Product name: cBRIDP(regR)
Purity: >97.0%(HPLC)
Packaging: 1g
Price: $117
Updated: 2021/12/16

TCI Chemical

Product number: C2979
Product name: cBRIDP(regR)
Purity: >97.0%(HPLC)
Packaging: 200mg
Price: $34
Updated: 2021/12/16

Strem Chemicals

Product number: 15-1005
Product name: Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP
Packaging: 250mg
Price: $33
Updated: 2021/12/16

Strem Chemicals

Product number: 15-1005
Product name: Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP
Packaging: 1g
Price: $98
Updated: 2021/12/16

Strem Chemicals

Product number: 15-1005
Product name: Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP
Packaging: 5g
Price: $303
Updated: 2021/12/16

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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties,Usage,Production

Reactions

Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction.

Uses

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.

General Description

This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Preparation Products And Raw materials

Raw materials

Preparation Products

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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Suppliers

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742103-27-1, Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDPRelated Search:

Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine Cy-cBRIDP 2-(Dicyclohexylphosphino)-1,1-diphenyl-1-propene, Dicyclohexyl(1-methyl-2,2-diphenylvinyl)phosphine 1.1'-Binaphthyl-2.2'-diphemyl phosphine Tri-tert-butylphosphine DI-T-BUTYLNEOPENTYLPHOSPHINE, MIN. 95 Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

Bis-(1,1-dimethylethyl)-(1-methyl-2,2-diphenylcyclopropyl)-phosphine

Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane

Mo-Phos

cBRIDP(regR)

Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine

cBRIDP<sup>&reg

Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-

cBRIDP[R]

cBRIDP(regR) &gt

742103-27-1

Achiral Phosphine

Aryl Phosphine

organophosphine ligand