DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE

Product Name: DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE
CAS No.: 124931-12-0
Chemical Name: DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE
Synonyms: Diethyl (2-(methoxy(methyl);N-Methoxy-N-methyl-diethylphosphoacetamide;DIETHYL N-METHOXY-N-METHYLPHOSPHONOACETAMIDE;N-Methoxy-N-methyl-2-(diethyl phosphono)acetamide;2-diethoxyphosphoryl-N-methoxy-N-methyl-acetamide;N-METHOXY-N-METHYL-PHOSPHONOACETAMIDE DIETHYL ESTER;Diethylphosphonoacetic acid N-methyl-N-methoxyamide;diethyl (N-ethoxy-N-methylcarbamoylmethyl)phosphonate;DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE;Diethyl (2-(Methoxy(Methyl)aMino)-2-oxoethyl)phosphonate
CBNumber: CB1135035
Molecular Formula: C8H18NO5P
Formula Weight: 239.21
MOL File: 124931-12-0.mol

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DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Property

Boiling point:: 90 °C17 mm Hg(lit.)
Density: 1.163 g/mL at 25 °C(lit.)
refractive index: n20/D 1.455(lit.)
Flash point:: >230 °F
storage temp.: Store at room temperature
form: clear liquid
color: Colorless to Almost colorless
BRN: 1875865
InChI: 1S/C8H18NO5P/c1-5-13-15(11,14-6-2)7-8(10)9(3)12-4/h5-7H2,1-4H3
InChIKey: WYLRYBDGIILFIR-UHFFFAOYSA-N
SMILES: CCOP(=O)(CC(=O)N(C)OC)OCC
CAS DataBase Reference: 124931-12-0

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29319000
Storage Class: 10 - Combustible liquids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 362433
Product name: Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate
Purity: 96%
Packaging: 5g
Price: $76
Updated: 2023/06/20

TCI Chemical

Product number: D3708
Product name: Diethyl (N-Methoxy-N-methylcarbamoylmethyl)phosphonate
Purity: >97.0%(GC)
Packaging: 1g
Price: $36
Updated: 2025/07/31

TCI Chemical

Product number: D3708
Product name: Diethyl (N-Methoxy-N-methylcarbamoylmethyl)phosphonate
Purity: >97.0%(GC)
Packaging: 5g
Price: $107
Updated: 2025/07/31

TRC

Product number: D443633
Product name: Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate
Packaging: 500mg
Price: $110
Updated: 2021/12/16

TRC

Product number: D443633
Product name: Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

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DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Chemical Properties,Usage,Production

Uses

Reactant for:

Preparation of ring-expanded bryostatin analogs as antitumor agents
Asymmertic synthesis of pinnatoxins A and G via diastereoselective Ireland-Claisen rearrangement, ring closing metathesis, and cyclization
Rh2(II)-catalyzed nitro-group migration reactions
Stereoselective synthesis of cyclohexanones via phase transfer catalyzed double addition reactions
Stereoselective synthesis of (+)-polyrhacitide A via aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction as the key steps
Preparation of substituted furans via olefin cross-metathesis

reaction suitability

reaction type: C-C Bond Formation

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials

N,O-Dimethylhydroxylamine hydrochloride Triethylamine Dichloromethane Bromoacetyl bromide Triethyl phosphite

Preparation Products

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DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Suppliers

Americas 1 CHINA 77 Europe 1 France 2 Germany 2 India 2 Japan 2 South Korea 1 Switzerland 1 United Kingdom 4 United States 15 Global 108

Jinan Kewei Biotechnology Co., LTD

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Creasyn Finechem(Tianjin) Co., Ltd.

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J & K SCIENTIFIC LTD.

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Beijing Donghualituo Techonlogy Development Co.,Ltd.

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Shanghai Hanhong Scientific Co.,Ltd.

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Hunan Hui Bai Shi Biotechnology Co., Ltd.

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124931-12-0, DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATERelated Search:

DIETHYL (FORMYLMETHYL)PHOSPHONATE (2-Aminoethyl)phosphonic acid Phosphonic acid, (carbamoylmethyl)-, diethyl ester DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE Diethyl ethoxymethylenemalonate

N-METHOXY-N-METHYL-PHOSPHONOACETAMIDE DIETHYL ESTER

DIETHYL (N-METHOXY-N-METHYLCARBAMOYLMETHYL)PHOSPHONATE

DIETHYL N-METHOXY-N-METHYLPHOSPHONOACETAMIDE

Diethyl(N-methoxy-N-methylcarbamoylmethyl)phosphonate, min. 97 %

(N-Methoxy-N-methylcarbamoylmethyl)phosphonic Acid Diethyl Ester

diethyl (N-ethoxy-N-methylcarbamoylmethyl)phosphonate

Diethyl N-methoxy-N-methylphosphonoacetamide, N-Methoxy-N-methyl-phosphonoacetamide diethyl ester

Diethyl (2-(Methoxy(Methyl)aMino)-2-oxoethyl)phosphonate

Diethylphosphonoacetic acid N-methyl-N-methoxyamide

N-Methoxy-N-methyl-2-(diethyl phosphono)acetamide

Diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate ,97%

N-Methoxy-N-methyl-diethylphosphoacetamide

Diethyl (<i>N</i>-Methoxy-<i>N</i>-methylcarbamoylmethyl)phosphonate

2-diethoxyphosphoryl-N-methoxy-N-methyl-acetamide

Diethyl (2-(methoxy(methyl)

Phosphonic acid,P-[2-(methoxymethylamino)-2-oxoethyl]-, diethyl ester

Diethyl(N-Methoxy-N-methylcarbamoylmethyl)phosphonate&gt

Diethyl P-[2-(methoxymethylamino)-2-oxoethyl]phosphonate

124931-12-0

CH3ONCH3COCH2POOC2H52

C8H18NO5P

C-C Bond Formation

Synthetic Reagents

Olefination

Horner-Wadsworth-Emmons Reagents

Synthetic Organic Chemistry

Wittig & Horner-Emmons Reaction

Horner-Emmons Reaction