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(Bromomethyl)boronic Acid Pinacol Ester

Uses
Product Name
(Bromomethyl)boronic Acid Pinacol Ester
CAS No.
166330-03-6
Chemical Name
(Bromomethyl)boronic Acid Pinacol Ester
Synonyms
90.0%(GC&2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 2-(bromomethyl)-4,4,5,5-tetramethyl-;2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >
CBNumber
CB11486488
Molecular Formula
C7H14BBrO2
Formula Weight
220.9
MOL File
166330-03-6.mol
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(Bromomethyl)boronic Acid Pinacol Ester Property

Boiling point:
68 °C / 6mmHg
Density 
1.26
refractive index 
1.4520-1.4560
Flash point:
62.8±22.6℃
storage temp. 
Inert atmosphere,2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
InChI
InChI=1S/C7H14BBrO2/c1-6(2)7(3,4)11-8(5-9)10-6/h5H2,1-4H3
InChIKey
KBGMAXNDJAGTDD-UHFFFAOYSA-N
SMILES
O1C(C)(C)C(C)(C)OB1CBr
CAS DataBase Reference
166330-03-6
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Safety

HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3199
Product name
2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Purity
>90.0%(GC)(T)
Packaging
1g
Price
$17
Updated
2025/07/31
TCI Chemical
Product number
B3199
Product name
2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Purity
>90.0%(GC)(T)
Packaging
5g
Price
$56
Updated
2025/07/31
TRC
Product number
B694688
Product name
Bromomethylboronicacidpinacolester
Packaging
500mg
Price
$65
Updated
2021/12/16
TRC
Product number
B694688
Product name
Bromomethylboronicacidpinacolester
Packaging
100mg
Price
$45
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
BOR0005413
Product name
BROMOMETHYLBORONIC ACID PINACOL ESTER
Purity
95.00%
Packaging
1G
Price
$284.55
Updated
2021/12/16
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(Bromomethyl)boronic Acid Pinacol Ester Chemical Properties,Usage,Production

Uses

Pinara bromomethylbenzoate is an organoboron compound that has been extensively studied for its potential applications in organic synthesis and catalysis. It is a versatile reagent with broad reactivity, suitable for a wide range of reactions, including Diels-Alder, Michael, and Wittig reactions. Furthermore, BMTMD has been shown to function as a catalyst for the synthesis of various compounds, such as heterocycles, amines, polymers (e.g., polyesters and polyamides), and organometallic compounds (including borates, borate esters, and boric acids).

Description

(Bromomethyl)boronic Acid Pinacol Ester, also known as 2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (BMTMD), is an organoboron compound extensively researched for its potential applications in organic synthesis and catalysis. It is a versatile reagent, exhibiting a broad range of reactivity suitable for various reactions, including Diels-Alder, Michael, and Wittig reactions. Moreover, BMTMD proves valuable as a catalyst in the synthesis of diverse compounds like heterocycles, amines, polymers (such as polyesters and polyamides), and organometallic compounds (including boronates, boronic esters, and boronic acids). Its ability to react with various functional groups, including carbonyl and carboxyl, facilitates nucleophilic addition and substitution mechanisms. Additionally, BMTMD can interact with amines, alcohols, and sulfonates, where nucleophilic addition and substitution mechanisms are involved depending on the functional group.

(Bromomethyl)boronic Acid Pinacol Ester Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (Bromomethyl)boronic Acid Pinacol Ester manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
2-(bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 166330-03-6
Price
US $3.00-9.00/KG
Min. Order
0.10000000149011612KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-07-02
PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD
Product
(Bromomethyl)boronic Acid Pinacol Ester 166330-03-6
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1000 kgs
Release date
2024-05-11
Career Henan Chemical Co
Product
Bromomethylboronic acid, pinacol ester 166330-03-6
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1000KGS
Release date
2020-01-10

166330-03-6, (Bromomethyl)boronic Acid Pinacol EsterRelated Search:


  • 2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • 90.0%(GC&amp
  • 2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane &gt
  • 1,3,2-Dioxaborolane, 2-(bromomethyl)-4,4,5,5-tetramethyl-
  • 166330-03-6
  • C7H14BBrO2
  • Organic boronic acid
  • organic boroinic acid
  • B (Classes of Boron Compounds)
  • Boronic Acids Esters
  • Organoborons
  • Alkyl