(Bromomethyl)cyclopentane
- Product Name
- (Bromomethyl)cyclopentane
- CAS No.
- 3814-30-0
- Chemical Name
- (Bromomethyl)cyclopentane
- Synonyms
- Bromomethyl cyclopentane;Cyclopentane,(bromomethyl)-;Bromomethylcyclopentane ISO 9001:2015 REACH;Bromomethylcyclopentane[(Bromomethyl)cyclopentane]
- CBNumber
- CB4971810
- Molecular Formula
- C6H11Br
- Formula Weight
- 163.06
- MOL File
- 3814-30-0.mol
(Bromomethyl)cyclopentane Property
- Boiling point:
- 58-60 °C(Press: 15 Torr)
- Density
- 1.271 g/cm3
- refractive index
- 1.48
- storage temp.
- Inert atmosphere,Room Temperature
- form
- liquid
- color
- Colourless to light brown
- InChI
- InChI=1S/C6H11Br/c7-5-6-3-1-2-4-6/h6H,1-5H2
- InChIKey
- XYZUWOHEILWUID-UHFFFAOYSA-N
- SMILES
- C1(CBr)CCCC1
- CAS DataBase Reference
- 3814-30-0(CAS DataBase Reference)
N-Bromosuccinimide Price
- Product number
- CDS005521
- Product name
- (Bromomethyl)cyclopentane
- Purity
- AldrichCPR
- Packaging
- 100MG
- Price
- $73.1
- Updated
- 2025/07/31
- Product number
- B697135
- Product name
- Bromomethylcyclopentane
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- B697135
- Product name
- Bromomethylcyclopentane
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 036984
- Product name
- (Bromomethyl)cyclopentane
- Packaging
- 250mg
- Price
- $15
- Updated
- 2021/12/16
- Product number
- 036984
- Product name
- (Bromomethyl)cyclopentane
- Packaging
- 1g
- Price
- $42
- Updated
- 2021/12/16
(Bromomethyl)cyclopentane Chemical Properties,Usage,Production
Chemical Properties
Colorless to pale yellow liquid
Uses
(Bromomethyl)cyclopentane is an alkyl cyclopentyl core analog. It could be used as a substrate to synthesize (azidomethyl)cyclopentane[1].
Synthesis
3637-61-4
3814-30-0
The general procedure for the synthesis of bromomethylcyclopentane from cyclopentanemethanol was as follows: a mixed solution of cyclopentanemethanol (48.5 g, 484 mmol), triethylamine (88.0 mL, 631 mmol) and anhydrous tetrahydrofuran (1 L) was cooled to 4 °C and stirred under nitrogen protection. Methylsulfonyl chloride (45.0 mL, 581 mmol) was added slowly, keeping the reaction temperature below 10 °C. After addition, the reaction mixture was continued to stir at 10 °C for 1 hour. Subsequently, lithium bromide (300.0 g, 3454 mmol) was added slowly, taking care to control the exotherm. After addition, the reaction mixture was stirred at room temperature for 16 hours. Upon completion of the reaction, water was added to dissolve the salts and the mixture was extracted with ether. The ether layers were combined, dried with anhydrous sodium sulfate and carefully concentrated at 25 °C at 100 Torr. The crude product was purified by vacuum distillation (35 °C, 1 Torr, collecting the first fraction) to give bromomethylcyclopentane (31.4 g, 40% yield) as a colorless oil.
References
[1] Sara Sadler. “A Facile Route to Triazolopyrimidines Using a [3+2] Cycloaddition and Continuous-Flow Chemistry.” Journal of Flow Chemistry 4 3 (2014): 140–147.
(Bromomethyl)cyclopentane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (Bromomethyl)cyclopentane manufacturers
- Product
- (Bromomethyl)cyclopentane 3814-30-0
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
- Product
- Bromomethylcyclopentane 3814-30-0
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- ask
- Release date
- 2020-01-08