ChemicalBook > CAS DataBase List > 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE

Product Name
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
CAS No.
38002-45-8
Chemical Name
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
Synonyms
(3-BroMoprop-1-yn-1-yl)triMethylsilane;)-1-propyne;(3-Bromo-1-pr;3-Bromo-1-(trimethyL;3-bromoprop-1-ynyl(trimethyl)silane;3-(trimethylsilyl)-propagyl bromide;(3-BROMO-1-PROPYNYL)TRIMETHYLSILANE;3-(TRIMETHYLSILYL)PROPARGYL BROMIDE;3-Bromo-1-(trimethulsilyl)-1-propyne;3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
CBNumber
CB1151699
Molecular Formula
C6H11BrSi
Formula Weight
191.14
MOL File
38002-45-8.mol
More
Less

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Property

Melting point:
<0°C
Boiling point:
44-45 °C2 mm Hg(lit.)
Density 
1.17 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.483(lit.)
Flash point:
145 °F
storage temp. 
2-8°C
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Oil
color 
Colourless to Pale Yellow
Specific Gravity
1.351
Water Solubility 
Immiscible with water.
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
2037650
Stability:
Hygroscopic
InChIKey
GAPRPFRDVCCCHR-UHFFFAOYSA-N
CAS DataBase Reference
38002-45-8(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-28-36/37/39
RIDADR 
UN 3334
WGK Germany 
3
8-9-19
TSCA 
No
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
377775
Product name
3-Bromo-1-(trimethylsilyl)-1-propyne
Purity
98%
Packaging
1g
Price
$50.9
Updated
2024/03/01
Sigma-Aldrich
Product number
377775
Product name
3-Bromo-1-(trimethylsilyl)-1-propyne
Purity
98%
Packaging
10g
Price
$297
Updated
2024/03/01
TCI Chemical
Product number
B1654
Product name
3-Bromo-1-(trimethylsilyl)-1-propyne
Purity
>97.0%(GC)
Packaging
1g
Price
$34
Updated
2024/03/01
TCI Chemical
Product number
B1654
Product name
3-Bromo-1-(trimethylsilyl)-1-propyne
Purity
>97.0%(GC)
Packaging
5g
Price
$99
Updated
2024/03/01
Alfa Aesar
Product number
H53451
Product name
3-Bromo-1-trimethylsilyl-1-propyne, 98%
Packaging
5g
Price
$97.9
Updated
2024/03/01
More
Less

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to pale yellow liquid

Uses

3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It may be used as reagent for the alkylation of dianion of β-keto esters at γ-carbon. It may be employed in the preparation of terminal conjugated enynes and allenic alcohols.

General Description

3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent. Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with α-keto ester using indium metal has been studied.

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
More
Less

View Lastest Price from 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-12-24
Hebei Mojin Biotechnology Co., Ltd
Product
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-16
Henan Aochuang Chemical Co.,Ltd.
Product
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-16

38002-45-8, 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNERelated Search:


  • 3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE 98%
  • (3-Bromo-1-pr
  • 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE, 98 %
  • 3-bromo-1-trimethylsilyl-1-propargyne
  • 3-Bromo-1-(trimethulsilyl)-1-propyne
  • 3-(trimethylsilyl)-propagyl bromide
  • 3-bromoprop-1-ynyl(trimethyl)silane
  • silane, (3-bromo-1-propynyl)trimethyl-
  • 3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%
  • 3-(TRIMETHYLSILYL)PROPARGYL BROMIDE 97+%
  • 3-(Trimethylsilyl)propargyl bromide, 3-Bromo-1-(trimethylsilyl)-1-propyne
  • (3-BROMO-1-PROPYNYL)TRIMETHYLSILANE
  • 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
  • (3-BroMoprop-1-yn-1-yl)triMethylsilane
  • (3-Bromo-1-propyn-1-yl)trimethyl-silane
  • 3-(TRIMETHYLSILYL)PROPARGYL BROMIDE
  • 3-Bromo-1-(trimethyL
  • 3-Bromo-1-(trimethylsilyl)-1-propyne &gt
  • Silane, (3-bromo-1-propyn-1-yl)trimethyl-
  • )-1-propyne
  • 3-Bromo-1-(Trimethylsilyl)-1-Propyne,95%
  • 38002-45-8
  • BrCH2CCSiCH33
  • C6H11BrSi
  • BrCH2C8801CSiCH33
  • Building Blocks
  • Alkynes
  • Organic Building Blocks
  • Internal
  • Acetylenes
  • Si-(C)4 Compounds
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Functionalized Acetylenes
  • Ethynylsilanes
  • Acetylenes
  • Ethynylsilanes
  • Functionalized Acetylenes
  • Si (Classes of Silicon Compounds)
  • Si-(C)4 Compounds
  • Silicon Compounds (for Synthesis)
  • Synthetic Organic Chemistry