3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
- Product Name
- 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
- CAS No.
- 38002-45-8
- Chemical Name
- 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
- Synonyms
- (3-BroMoprop-1-yn-1-yl)triMethylsilane;)-1-propyne;(3-Bromo-1-pr;3-Bromo-1-(trimethyL;3-bromoprop-1-ynyl(trimethyl)silane;3-(trimethylsilyl)-propagyl bromide;(3-BROMO-1-PROPYNYL)TRIMETHYLSILANE;3-(TRIMETHYLSILYL)PROPARGYL BROMIDE;3-Bromo-1-(trimethulsilyl)-1-propyne;3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
- CBNumber
- CB1151699
- Molecular Formula
- C6H11BrSi
- Formula Weight
- 191.14
- MOL File
- 38002-45-8.mol
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Property
- Melting point:
- <0°C
- Boiling point:
- 44-45 °C2 mm Hg(lit.)
- Density
- 1.17 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.483(lit.)
- Flash point:
- 145 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
- form
- Oil
- color
- Colourless to Pale Yellow
- Specific Gravity
- 1.351
- Water Solubility
- Immiscible with water.
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 2037650
- Stability:
- Hygroscopic
- InChIKey
- GAPRPFRDVCCCHR-UHFFFAOYSA-N
- CAS DataBase Reference
- 38002-45-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-28-36/37/39
- RIDADR
- UN 3334
- WGK Germany
- 3
- F
- 8-9-19
- TSCA
- No
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 377775
- Product name
- 3-Bromo-1-(trimethylsilyl)-1-propyne
- Purity
- 98%
- Packaging
- 1g
- Price
- $50.9
- Updated
- 2024/03/01
- Product number
- 377775
- Product name
- 3-Bromo-1-(trimethylsilyl)-1-propyne
- Purity
- 98%
- Packaging
- 10g
- Price
- $297
- Updated
- 2024/03/01
- Product number
- B1654
- Product name
- 3-Bromo-1-(trimethylsilyl)-1-propyne
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $34
- Updated
- 2024/03/01
- Product number
- B1654
- Product name
- 3-Bromo-1-(trimethylsilyl)-1-propyne
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $99
- Updated
- 2024/03/01
- Product number
- H53451
- Product name
- 3-Bromo-1-trimethylsilyl-1-propyne, 98%
- Packaging
- 5g
- Price
- $97.9
- Updated
- 2024/03/01
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Chemical Properties,Usage,Production
Chemical Properties
Clear colorless to pale yellow liquid
Uses
3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It may be used as reagent for the alkylation of dianion of β-keto esters at γ-carbon. It may be employed in the preparation of terminal conjugated enynes and allenic alcohols.
General Description
3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent. Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with α-keto ester using indium metal has been studied.
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Preparation Products And Raw materials
Raw materials
Preparation Products
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE manufacturers
- Product
- 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2022-12-24
- Product
- 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-16
- Product
- 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-16