TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

Product Name: TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
CAS No.: 76262-87-8
Chemical Name: TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
Synonyms: Titanocene ditriflate;TITANOCENE BIS(TRIFLUOROMETHANESULFONATE);Bis(cyclopentadienyl)di(triflato)titanium;TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE);Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium;Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV);BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE);di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate);BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE);Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
CBNumber: CB1163434
Molecular Formula: C12F6O6S2Ti
Formula Weight: 466.1
MOL File: 76262-87-8.mol

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TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Property

solubility: sol CH2Cl2, MeNO2; insol benzene, hexane.
form: powder to crystal
color: Orange to Amber to Dark red
CAS DataBase Reference: 76262-87-8

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 10-23
HS Code: 2931.90.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 416681
Product name: Bis(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
Purity: 98%
Packaging: 1g
Price: $240
Updated: 2023/06/20

TCI Chemical

Product number: T1658
Product name: Titanocene Bis(trifluoromethanesulfonate)
Purity: >97.0%(T)
Packaging: 100mg
Price: $78
Updated: 2024/03/01

TCI Chemical

Product number: T1658
Product name: Titanocene Bis(trifluoromethanesulfonate)
Purity: >97.0%(T)
Packaging: 1g
Price: $268
Updated: 2024/03/01

Chem-Impex

Product number: 41287
Product name: Titanocenebis(trifluoromethanesulfonate),97%(Assaybytitration)
Purity: 97%(Assaybytitration)
Packaging: 100MG
Price: $63.84
Updated: 2021/12/16

AK Scientific

Product number: 9164AL
Product name: Titanocene Bis(trifluoromethanesulfonate)
Packaging: 100mg
Price: $147
Updated: 2021/12/16

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TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Chemical Properties,Usage,Production

Uses

Catalyst for:

Transesterification
Stereoselective carbonyl-ene cyclization reactions
Sakurai reactions
Mukaiyama cross-aldol reactions

Reactant for synthesis of heterobimetallic bridging dinitrogen complexes

Application

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is used as a catalyst for Diels-Alder reaction, Mukaiyama crossed-aldol reaction, and Sakurai reaction.

Preparation

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is prepared by treatment of a 0.06 M THF solution of Dichlorobis(cyclopentadienyl)titanium with 5.5 equiv of a 0.19 M THF solution of Silver(I) Trifluoromethanesulfonate. After stirring for 15 min the reaction mixture is filtered, the red filtrate is layered with hexane, and the resulting red crystals are collected. Recrystallization from CH2Cl2/pentane or THF/hexane affords Cp2Ti(OSO2CF3)2 (25-30%) as red needles.

reaction suitability

core: titanium
reagent type: catalyst

storage

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) [Cp2Ti(OSO2CF3)2] and Cp2Zr(OSO2CF3)2 can be handled for short periods of time in air, but are best handled and stored in a glove box. Both can be prepared in situ. The pentamethylcyclopentadienyl analog Cp*2Ti(OH2)2²⁺ is air and water stable. Titanium(IV) is reputed to be of low toxicity.

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Preparation Products And Raw materials

Raw materials

Preparation Products

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TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Suppliers

China 34 Germany 2 India 1 Japan 1 Switzerland 1 United Kingdom 3 United States 6 Global 48

Fluorochem Ltd

Tel: --
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Email: vernam@fluorochem.co.uk
Country: United Kingdom
ProdList: 6375
Advantage: 65

Fluorochem Ltd.

Tel: --
Fax: --
Email: enquiries@fluorochem.co.uk
Country: United Kingdom
ProdList: 6401
Advantage: 74

VWR International

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Email: solutions@vwr.com
Country: United Kingdom
ProdList: 6548
Advantage: 82

76262-87-8, TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)Related Search:

FLUOROSULFONIC ACID titanocene TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE)

BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE)

TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE)

di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate)

Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium

Bis(cyclopentadienyl)di(triflato)titanium

Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV)

Titanocene ditriflate

Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)

76262-87-8

C12H10F6O6S2Ti

Titanium

Catalysis and Inorganic Chemistry

Titanocene, etc.

Metallocenes

Classes of Metal Compounds

Transition Metal Compounds

Ti (Titanium) Compounds

Classes of Metal Compounds

Metallocenes

Ti (Titanium) Compounds

Titanocene, etc.

Transition Metal Compounds