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Boron trifluoride-methanol solution

Product Name
Boron trifluoride-methanol solution
CAS No.
373-57-9
Chemical Name
Boron trifluoride-methanol solution
Synonyms
trifluoride;BF3/METHANOL;uoride methanoL;14% in methanol;150g/L in methanol;BORON FLUORIDE-METHANOL;trifluoro(methanol)boron;BORON TRIFLUORIDE-METHANOL;Boron trifluoride solution;Boron Trifluoride in Methanol
CBNumber
CB1184013
Molecular Formula
CH3BF3O
Formula Weight
98.84
MOL File
373-57-9.mol
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Boron trifluoride-methanol solution Property

Melting point:
-93℃ (Methanol)
Boiling point:
59 °C4 mm Hg
Density 
1.203 g/mL at 25 °C
vapor pressure 
19.5 mm Hg ( 20 °C)
refractive index 
n20/D 1.328
Flash point:
52 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
0.890 (20/4℃)
Merck 
14,1349
BRN 
3611499
InChIKey
FQZVTMBNNNQKJY-UHFFFAOYSA-N
CAS DataBase Reference
373-57-9
EPA Substance Registry System
Boron, trifluoro(methanol)-, (T-4)- (373-57-9)
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Safety

Hazard Codes 
T,C,T+,F
Risk Statements 
20/22-34-48/23-39/23/24/25-35-26-24/25-11-14-23/24/25
Safety Statements 
26-28-36/37/39-45-23-16
RIDADR 
UN 3286 3/PG 2
WGK Germany 
3
RTECS 
ED2275000
F 
21
Autoignition Temperature
788 °F
HazardClass 
8
PackingGroup 
I
HS Code 
28129019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

H335May cause respiratory irritation

H370Causes damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
134821
Product name
Boron trifluoride-methanol solution
Purity
50% w/w in methanol
Packaging
4x25ml
Price
$125.4
Updated
2024/03/01
Sigma-Aldrich
Product number
134821
Product name
Boron trifluoride-methanol solution
Purity
50% w/w in methanol
Packaging
1l
Price
$420
Updated
2024/03/01
TCI Chemical
Product number
X0036
Product name
Boron Trifluoride - Methanol Reagent (10-20%) [for Esterification] (1mL×10)
Packaging
1set
Price
$97
Updated
2024/03/01
Sigma-Aldrich
Product number
B1252
Product name
Boron trifluoride-methanol solution
Purity
14% in methanol
Packaging
5ml
Price
$62.4
Updated
2024/03/01
Sigma-Aldrich
Product number
B1252
Product name
Boron trifluoride-methanol solution
Purity
14% in methanol
Packaging
100ml
Price
$76
Updated
2024/03/01
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Boron trifluoride-methanol solution Chemical Properties,Usage,Production

Chemical Properties

colorless to amber solution

Chemical Properties

Boron trifluoride etherates: (compounded with methyl ether) is moisture-sensitive, corrosive, flammable liquid.

Uses

Reagent for the GC analysis of ritalinic acid. Alternative to Cl2CHCO2H for synthesis of purine rich oligomers.
Lewis acid used in the preparation of geminal bis-peroxides from ketals and enol ethers with t-butyl hydroperoxide. Reagent used for the mild deacetylation of amines.

Uses

It was used in transmethylation of 1,2-Diacylglycerol (DAG) containing fractions which were purified using HPLC. It may be used to treat lipids during GC analysis done for determination of fatty acid methyl esters and dimethylacetals.

Uses

Trifluoro(methanol)boron is a reagent used for the GC analysis of ritalinic acid.

General Description

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

Potential Exposure

Used as a catalyst.

Shipping

Diethyl: UN2604 Boron trifluoride diethyl etherate, Hazard class: 8; Labels: 8—Corrosive material, 3—Flammable liquid. Dimethyl: UN2965 Boron trifluoride dimethyl etherate, Hazard class: 4.3; Labels: 4.3— Dangerous when wet, 8—Corrosive material, 3— Flammable liquid.

Incompatibilities

Reacts with air forming corrosive hydrogen fluoride vapors. Incompatible with oxidizers (may cause fire and explosion), water, steam or heat, forming corrosive and flammable vapors. Peroxide containing etherate reacts explosively with aluminum lithium hydride, magnesium tetrahydroaluminate. Mixtures with phenol react explosively with 1,3-butadiene. Presumed to form explosive peroxides.

Boron trifluoride-methanol solution Preparation Products And Raw materials

Raw materials

Preparation Products

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Boron trifluoride-methanol solution Suppliers

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View Lastest Price from Boron trifluoride-methanol solution manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Boron trifluoride-methanol solution 373-57-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-06-13
Career Henan Chemical Co
Product
Trifluoro(methanol)boron 373-57-9
Price
US $3.00/KG
Min. Order
1KG
Purity
99%min
Supply Ability
200kg
Release date
2020-03-06

373-57-9, Boron trifluoride-methanol solutionRelated Search:

Boron trifluoride-acetic acid complex Boron trifluoride diethyl etherate Boron trifluoride acetonitrile complex Methanol Boron nitride Boron AMMONIUM POLYSULFIDE Boron carbide BORON TRIFLUORIDE-PHENOL COMPLEX (1:2) Boron trifluoride methanol complex Boron trifluoride BORON TRIFLUORIDE-METHANOL Boron trifluoride-methanol solution BORON TRIFLUORIDE-METHANOL COMPLEX,*IN EXCESS BORON TRIFLUORIDE-METHANOL-D4 COMPLEX, I N EXCESS METHANOL-D4 (CA. 12 % BF3) BORON TRIFLUORIDE-METHANOL-D4 COMPLEX

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  • 373-57-9
  • 73-57-9
  • CH4BF3O
  • BF3CH3OH
  • BF3MeOH
  • Synthetic Reagents
  • Lewis Acids
  • BCl3, BF3, HCl-Alkanol Solutions (GC Derivatizing Reagents)
  • Boron Trifluorides
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  • GC Derivatizing Reagents
  • B (Classes of Boron Compounds)
  • Esterification & Alkylation (GC Derivatizing Reagents)
  • Alkylation
  • Acylation
  • Fine Chemical
  • BoronMicro/Nanoelectronics
  • BoronSynthetic Reagents
  • Electronic Chemicals
  • Lewis Acids
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis