ChemicalBook > CAS DataBase List > (S)-1-N-Boc-2-(aminomethyl)pyrrolidine

(S)-1-N-Boc-2-(aminomethyl)pyrrolidine

Product Name
(S)-1-N-Boc-2-(aminomethyl)pyrrolidine
CAS No.
119020-01-8
Chemical Name
(S)-1-N-Boc-2-(aminomethyl)pyrrolidine
Synonyms
(S)-1-BOC-2-(AMINOMETHYL)PYRROLIDINE;-1-Boc-pyrroL;CAS:119020-01-8;(S)-2-AminomethyL;RARECHEM AL BW 2320;(S)-1-Boc-2-(aminomethyl)...;(S)-N'-BOC-2-Aminomethylpirrolidine;(S)-2-AMINOMETHYL-1-BOC-PYRROLIDINE;(S)-N-Boc-2-(aminomethyl)pyrrolidine;(s)-1-Boc-2-(AMinoMethyl ) Pyrolidine
CBNumber
CB1184725
Molecular Formula
C10H20N2O2
Formula Weight
200.28
MOL File
119020-01-8.mol
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(S)-1-N-Boc-2-(aminomethyl)pyrrolidine Property

Boiling point:
98-112℃/1mm
Density 
1.044±0.06 g/cm3(Predicted)
refractive index 
1.4670-1.4710
storage temp. 
2-8°C
solubility 
Miscible with N-methylpyrrolidinone.
pka
9.91±0.29(Predicted)
form 
clear liquid
color 
Colorless to Almost colorless
BRN 
8905233
CAS DataBase Reference
119020-01-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,N,C
Risk Statements 
36/37/38-51/53-34-22
Safety Statements 
26-36/37/39-61-45
RIDADR 
3259
WGK Germany 
3
HazardClass 
8
PackingGroup 
Ⅲ
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
A2473
Product name
(S)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$140
Updated
2025/07/31
TRC
Product number
B702248
Product name
(S)-1-Boc-2-(aminomethyl)pyrrolidine
Packaging
2.5g
Price
$110
Updated
2021/12/16
Chem-Impex
Product number
41567
Product name
(S)-2-(Aminomethyl)-1-Boc-pyrrolidine,98%(GC)
Purity
98%(GC)
Packaging
100MG
Price
$70
Updated
2021/12/16
AK Scientific
Product number
K815
Product name
(S)-1-N-Boc-2-(aminomethyl)pyrrolidine
Packaging
5g
Price
$147
Updated
2021/12/16
Activate Scientific
Product number
AS3151
Product name
(S)-N-Boc-2-(aminomethyl)pyrrolidine
Purity
97+% ee
Packaging
5G
Price
$151
Updated
2021/12/16
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(S)-1-N-Boc-2-(aminomethyl)pyrrolidine Chemical Properties,Usage,Production

Chemical Properties

Solid

Uses

(S)-2-Aminomethyl-1-Boc-pyrrolidine acts as an intermediate in organic synthesis. It is also used as a chiral and heterocyclic building block in synthetic chemistry.

Synthesis

168049-26-1

119020-01-8

GENERAL METHOD: Under stirring conditions, azide derivatives 9a or 9b (4.03 mmol) were dissolved in THF (1 mL), followed by the addition of solid triphenylphosphine (Ph3P, 4.03 mmol) and water (H2O, 6.04 mmol). The reaction mixture was stirred continuously for 12 h at room temperature. After completion of the reaction, the solvent was removed by concentration under reduced pressure. The crude product was purified by rapid column chromatography on silica gel with an eluent ratio of methanol-dichloromethane (9:1).

References

[1] Synthesis, 2005, # 14, p. 2407 - 2413
[2] Angewandte Chemie - International Edition, 2011, vol. 50, # 48, p. 11382 - 11385
[3] Synthetic Communications, 2011, vol. 41, # 17, p. 2517 - 2523
[4] Tetrahedron Letters, 2010, vol. 51, # 40, p. 5281 - 5286
[5] Phosphorus, Sulfur and Silicon and the Related Elements, 2013, vol. 188, # 4, p. 509 - 511

(S)-1-N-Boc-2-(aminomethyl)pyrrolidine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (S)-1-N-Boc-2-(aminomethyl)pyrrolidine manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(S)-1-Boc-2-(aminomethyl)pyrrolidine 119020-01-8
Price
US $1.10-9.90/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kg
Release date
2025-08-18
Hebei Chuanghai Biotechnology Co., Ltd
Product
(S)-1-N-Boc-2-(aminomethyl)pyrrolidine 119020-01-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-30
Hebei Yanxi Chemical Co., Ltd.
Product
(S)-1-N-Boc-2-(aminomethyl)pyrrolidine 119020-01-8
Price
US $40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-08

119020-01-8, (S)-1-N-Boc-2-(aminomethyl)pyrrolidineRelated Search:

Methyl anthranilate POLYURETHANE N-Vinyl-2-pyrrolidone tert-Butyl acetate Diisobutyl phthalate Butyl acetate Cyhalofop-butyl BUTYL OLEATE Buprofezin Urethane Diethylene glycol monobutyl ether Polyvinylpyrrolidone N-Methyl-2-pyrrolidone Pyrrolidine tert-Butanol 4-Aminobenzoic acid 2-Butoxyethanol Butyl acrylate

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  • (S)-2-(AMINOMETHYL)-1-N-BOC-PYYROLIDINE
  • tert-Butyl (2S)-2-(aminomethyl)pyrrolidine-1-carboxylate, (2S)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine
  • (S)-2-(Aminomethyl)-1-Boc-pyrrolidine tert-Butyl (S)-2-(Aminomethyl)-1-pyrrolidinecarboxylate (S)-2-(Aminomethyl)-1-pyrrolidinecarboxylic Acid tert-Butyl Ester
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  • (S)-2-(Aminomethyl)-1-Boc-pyrrolidine 97%
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  • -1-Boc-pyrroL
  • (S)-2-(Aminomethyl)-1-pyrrolidinecarboxylic Acid tert-Butyl Ester
  • CAS:119020-01-8
  • (<i>S</i>)-2-(Aminomethyl)-1-Boc-pyrrolidine
  • (S)-2-(Aminomethyl)-1-Boc-pyrrolidine, CAS 119020-01-8
  • 119020-01-8
  • 199020-01-8
  • 11902-01-8
  • pharmacetical
  • Pyrrole&Pyrrolidine&Pyrroline