ChemicalBook > CAS DataBase List > Acrolein diethyl acetal

Acrolein diethyl acetal

Product Name
Acrolein diethyl acetal
CAS No.
3054-95-3
Chemical Name
Acrolein diethyl acetal
Synonyms
3,3-DIETHOXYPROP-1-ENE;1-Propene, 3,3-diethoxy-;ACROLEIN ACETAL;3 3-DIETHOXYPROPENE;AVAC-013;ein DiethyL;ACROLEIN DEA;Diethoxypropene;Avacopan Impurity 6;ACROLEINDITHYLACETAL
CBNumber
CB1185045
Molecular Formula
C7H14O2
Formula Weight
130.18
MOL File
3054-95-3.mol
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Acrolein diethyl acetal Property

Melting point:
120-124 °C
Boiling point:
125 °C (lit.)
Density 
0.854 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.398(lit.)
Flash point:
40 °F
storage temp. 
2-8°C
solubility 
Chloroform (Soluble), Ethyl Acetate (Slightly)
form 
Liquid
color 
Clear colorless
Water Solubility 
Slightly soluble in water.
BRN 
1701567
Stability:
Light sensitive
InChIKey
MCIPQLOKVXSHTD-UHFFFAOYSA-N
LogP
1.560
CAS DataBase Reference
3054-95-3(CAS DataBase Reference)
NIST Chemistry Reference
1-Propene, 3,3-diethoxy-(3054-95-3)
EPA Substance Registry System
1-Propene, 3,3-diethoxy- (3054-95-3)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36
Safety Statements 
9-16-26-33-29-7/9
RIDADR 
UN 2374 3/PG 2
WGK Germany 
3
RTECS 
AS1370000
F 
8-13
HazardClass 
3
PackingGroup 
III
HS Code 
29110000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
A24001
Product name
Acrolein diethyl acetal
Purity
96%
Packaging
25g
Price
$88.4
Updated
2024/03/01
Sigma-Aldrich
Product number
A24001
Product name
Acrolein diethyl acetal
Purity
96%
Packaging
100g
Price
$135
Updated
2024/03/01
TCI Chemical
Product number
A0640
Product name
Acrolein Diethyl Acetal
Purity
>97.0%(GC)
Packaging
25g
Price
$104
Updated
2024/03/01
TCI Chemical
Product number
A0640
Product name
Acrolein Diethyl Acetal
Purity
>97.0%(GC)
Packaging
250g
Price
$469
Updated
2024/03/01
Alfa Aesar
Product number
B24821
Product name
Acrolein diethyl acetal, 96%
Packaging
10g
Price
$50.65
Updated
2024/03/01
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Acrolein diethyl acetal Chemical Properties,Usage,Production

Description

3,3-Diethoxypropene is a colorless flammableliquid; Molecular weight=130.21; Boiling point=123.5℃;Flash point=4.4℃. Hazard Identification (based on HMISRating System scale: 0-4): Health 1, Flammability 3,Reactivity 1. Water solubility=not determined.

Chemical Properties

clear colorless liquid

Uses

Acrolein diethyl acetal is a reagent used for the synthesis of a variety of compounds, including cinnamaldehydes.

Uses

Acrolein diethyl acetal is widely used to carry out chemoselective Heck arylation to synthesize either 3-arylpropanoate esters or cinnamaldehyde derivatives.

It can also be used as one of the precursors to synthesize natural products like (?)-(Z)-Deoxypukalide, (?)-Laulimalide, botryodiplodin, neolaulimalide and isolaulimalide.

General Description

A colorless liquid with an agreeable odor. Very volatile. Flash point 70°F. Less dense than water. Vapors heavier than air. Used as a solvent and to make cosmetics.

Air & Water Reactions

Highly flammable. Soluble in water. Likely to slowly form peroxidized product when exposed to air. The formed peroxide is likely to be unstable.

Reactivity Profile

Ethers, such as DIETHOXYPROPENE, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Mutation data reported. A flammable liquid. A dangerous fire hazard when exposed to heat, flame, or oxiduers. When heated to decomposition it emits acrid smoke and fumes.

Potential Exposure

Used by technically qualified individuals only; in organic synthesis. US EPA under TSCArestricts use of this chemical to R&D only.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—Red: Flammability Hazard: Store in aflammable liquid storage area or approved cabinet away fromignition sources and corrosive and reactive materials. Prior toworking with this chemical you should be trained on itsproper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from acids and strongoxidizers. Sources of ignition, such as smoking and openflames, are prohibited where diethoxypropene is handled,used, or stored. Metal containers involving the transfer of 5gallons or more of diethoxypropene should be grounded andbonded. Drums must be equipped with self-closing valves,pressure vacuum bungs, and flame arresters. Use only nonsparking tools and equipment, especially when opening andclosing containers of diethoxypropene. Wherever diethoxypropene is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.

Shipping

3,3-Diethoxypropene must bear a“FLAMMABLE LIQUID” label. It falls in Hazard Class 3and Packing Group II.

Purification Methods

Add Na2CO3 (ca 3.5%) and distil it using an efficient column, or better use a spinning band column. [Witzemann et al. Org Synth Coll Vol II 17 1943, Beilstein 1 H 727, 1 I 378, 1 III 2960, 1 IV 3437.]

Incompatibilities

Forms explosive mixture with air.Contact with acids and strong oxidizers may cause fire andexplosion hazard.

Acrolein diethyl acetal Preparation Products And Raw materials

Raw materials

Preparation Products

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Acrolein diethyl acetal Suppliers

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View Lastest Price from Acrolein diethyl acetal manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Acrolein diethyl acetal 3054-95-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-12-27
Hebei Fengqiang Trading Co., LTD
Product
Acrolein diethyl acetal 3054-95-3
Price
US $100.00/bag
Min. Order
1bag
Purity
99
Supply Ability
5000
Release date
2023-09-15
Hebei Mojin Biotechnology Co., Ltd
Product
Acrolein diethyl acetal 3054-95-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-15

3054-95-3, Acrolein diethyl acetalRelated Search:

DIETHOXYMETHANE Diethanolamine PROPYLENE Diethyl phthalate Methacrolein Bromoacetaldehyde diethyl acetal Acetal Diethoxymethyl acetate Diethyl malonate Ethoxyquin 2-Ethoxyphenol 2-Ethoxypropene N-Methyldiethanolamine Ethyl pyruvate 2,2,2-Trifluoroethyl acrylate tert-Butyl acrylate Acrolein Celiprolol

  • ACROLEIN ACETAL
  • ACROLEIN DEA
  • ACROLEIN DIETHYL ACETAL
  • 1,1-DIETHOXY-2-PROPENE
  • 3 3-DIETHOXYPROPENE
  • 3,3-DIETHOXY-1-PROPENE
  • 3,3-diethoxy-1-propen
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  • propenaldiethylacetal
  • ACROLEIN DIETHYL ACETAL STABILIZED &
  • ACROLEIN DIETHYL ACETAL, STAB.
  • 1-Propene, 3,3-diethoxy-
  • ein DiethyL
  • 3,3-DIETHOXYPROP-1-ENE
  • 3 3-DIETHOXYPROPENE 99%
  • ACROLEINDITHYLACETAL
  • Acrylylaldehyde diethyl acetal
  • Diethoxypropene
  • Acrolein diethyl acetal,94%
  • 2-Propenal diethyl acetal
  • Acrolein diethyl acetal ,95%
  • Acrolein diethyl acetal,3,3-Diethoxy-1-propene
  • Acrolein Acetal 1,1-Diethoxy-2-propene 3,3-Diethoxy-1-propene
  • 3,3-Diethoxyprop-1-ene, Acrylaldehyde diethyl acetal
  • Acrolein diethyl acetal 96%
  • Acroleinshrinkagetwo ethanol
  • Acrolein Diethyl Acetal , 95.0%(GC)
  • AVAC-013
  • Acrolein Diethyl Acetal &gt
  • ACROLEIN DIETHYL ACETAL CAS NO.:3054-95-3
  • Avacopan Impurity 6
  • 3054-95-3
  • 3045-95-3
  • CH2CHCHOCH2CH32
  • ACETATE
  • Oxygen Compounds
  • Organic Building Blocks
  • Acetals/Ketals/Ortho Esters
  • Building Blocks
  • pharmacetical
  • Pharmaceutical Intermediates