Guanidine carbonate

High purity Guanidine carbonate synthesis method Reference quality standards

Product Name: Guanidine carbonate
CAS No.: 593-85-1
Chemical Name: Guanidine carbonate
Synonyms: GUANIDINIUM CARBONATE;Guanidonium-carbonat;Guanidinecarbonate,98%;DIGUANIDINIUM CARBONATE;GUANIDINE CARBONATE SALT;ai3-14631;C2H10N6H2CO3;Carbonate pus;GUANIDINE CARBONAT;Iminoureacarbonate
CBNumber: CB1200944
Molecular Formula: C2H7N3O3
Formula Weight: 121.1
MOL File: 593-85-1.mol

More

Less

Guanidine carbonate Property

Melting point:: >300 °C(lit.)
Density: 1.25
vapor pressure: 0Pa at 25℃
storage temp.: Store below +30°C.
solubility: 450g/l
form: Crystalline Powder
pka: 12.5[at 20 ℃]
color: White to almost white
PH: 11.7 (110g/l, H2O, 20℃)
Water Solubility: 450 g/L (20 ºC)
BRN: 3628359
InChIKey: KMSRVXJGTIRNNK-UHFFFAOYSA-N
LogP: -1.63 at 20℃
CAS DataBase Reference: 593-85-1(CAS DataBase Reference)
NIST Chemistry Reference: Guanidine carbonate(593-85-1)
EPA Substance Registry System: Guanidine carbonate (2:1) (593-85-1)

More

Less

Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38-20/21/22
Safety Statements: 26-36-22
WGK Germany: 3
RTECS: FG1750000
Autoignition Temperature: 530 °C
TSCA: Yes
HS Code: 29252000
Toxicity: LD50 orally in Rabbit: 1045 mg/kg

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: G11659
Product name: Guanidine carbonate salt
Purity: 99%
Packaging: 5g
Price: $84.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: G11659
Product name: Guanidine carbonate salt
Purity: 99%
Packaging: 1kg
Price: $114
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20611
Product name: Guanidinium carbonate
Purity: for synthesis
Packaging: 100g
Price: $53.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20611
Product name: Guanidinium carbonate
Purity: for synthesis
Packaging: 1kg
Price: $106
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20611
Product name: Guanidinium carbonate
Purity: for synthesis
Packaging: 50kg
Price: $1450
Updated: 2024/03/01

More

Less

Guanidine carbonate Chemical Properties,Usage,Production

High purity Guanidine carbonate synthesis method

Guanidine carbonate is an extremely versatile organic chemical products, it is mainly used in flame retardants, flocculants, foaming agents, synthetic sulfa drugs, etc. Guanidine carbonate is also used as synthetic detergent builders, high-quality cosmetics raw materials.Synthesis of guanidine carbonate is reported by many literatures [1-3] .The main domestic guanidine carbonate production is that molt dicyandiamide and ammonium chloride to generate guanidine hydrochloride, generate free guanidine under the action of the alkali, and then by the reaction of free guanidine and carbon dioxide to produce guanidine carbonate. this route is easy to generate melamine and its dimers, trimers and other impurities because of the high-temperature melting , and the presence of Cl-, Na + in the system is difficult to completely removed , even if the purity is> 99% of guanidine carbonate, its ash content is still up 0.2%, it is difficult to obtain high purity guanidine carbonate. in this paper, cyanamide as raw materials, reacts with carbon dioxide and ammonia in one step synthesis of guanidine carbonate, also known as ash-free guanidine carbonate, and then purify , to obtain a high purity guanidine carbonate, the reaction equation is as follows: 2NH2CN + CO2 + 2NH3 + H20 → [NH2C (: NH) NH2] 2H2CO3
Author: Zhouzhao Liang Xie Jianwei Zhou Xiaohong Jiang Yongqing
Author: Zhouzhao Liang, Xie Jianwei (Research Institute of Zhejiang University of West Branch Quzhou 324006)
Zhou Xiaohong, Jiang Yongqing (Institute of Fine Chemicals Group Technology Center Juhua Quzhou 324004)

Reference quality standards

[Industry Grade ] Name of Item Technical index
Premium grade B product
Appearance white crystalline white powder
Content of ≥ 99% 98%
Ammonium ≤ 0.45% 1.0%
Water insoluble matter ≤ 0.2% 0.2%
Moisture ≤ 0.2% 0.2%
Ash ≤ 0.15% 0.2%
Water-soluble test Qualified Qualified
PH value (4% 25 ℃) 11.4 11.4
[Pharmaceutical Grade ]
Name of Item Technical index
Premium grade
Appearance white crystals
Content ≥ 99%
Ammonium salt (with NH4Cl meter) ≤ 0.45%
Water insoluble matter ≤ 0.2%
Moisture ≤ 0.2%
Ash ≤ 0.1%
Water-soluble test Qualified
PH value (4% 25 ℃) 11.4
Heavy Metal ppm ≤10
Arsenic ppm ≤3
The above information is edited by the Chemicalbook of Tian Ye.

Chemical Properties

white to almost white crystalline powder. Soluble in water, slightly soluble in methanol, almost insoluble in acetone, benzene and ether.

Uses

Guanidine Carbonate is a strong organic alkali. It is used to adjust the pH of a formulation, organic intermediate, soap and cosmetic products.

Uses

Guanidine Carbonate is used in the cytidine triphosphate injection stabilization. It also acts as a powerful and versatile protein denaturants.
As a strong chemical base, guanidine carbonate is used as an intermediary in a variety of applications:
Organic synthesis materials and analytical reagents.
pH adjusting agents for amino resins, antioxidants, resin stabilizer and guanidine soap, also a grout agent, cement additives, surfactants.
In terms of synthetic detergent,it is used as a moisture agent and a synergist.
For Zinc, cadmium, manganese weight measurement, it is used as a precipitating agent, it is also used in the separation of alkali metal magnesium.

Application

Guanidine carbonate salt can be used as a reactant for the synthesis of:
An oxidizer, guanidinium dinitramide (GDN), by reacting with ammonium dinitramide.
Guanidinium cyclopropanecarboxylate by reacting with cyclopropanecarboxylic acid.

Preparation

Synthesis of guanidine carbonate: Melt double cyanide salts and ammonia to generate guanidine salts (guanidine hydrochloride, guanidine nitrate) at 170-230 ℃ . Then make guanidine salt into an alcohol solution, add soda to free guanidine, absorb carbon dioxide to obtain guanidine carbonate.

Hazard

Toxic by ingestion.

Flammability and Explosibility

Non flammable

Purification Methods

Crystallise it from MeOH. [Beilstein 3 H 86, 3 I 41, 3 II 72, 3 III 161, 3 IV 152.]

Guanidine carbonate Preparation Products And Raw materials

Raw materials

Double cyanamide Carbon dioxide Guanidine hydrochloride Guanidine nitrate

Preparation Products

Sulfometuron-methyl 4-Hydrazino-6-methylpyrimidin-2-amine 2,5-Diaminopyrimidine 6-(TERT-BUTYL)PYRIMIDINE-2,4-DIAMINE 2-AMINO-5,6-DIMETHYL-4-HYDROXYPYRIMIDINE Brodimoprim

More

Less

Guanidine carbonate Suppliers

Americas 1 Belgium 2 Canada 1 China 411 Europe 4 France 1 Germany 7 India 32 Italy 1 Japan 8 Malaysia 2 Slovakia 1 South Korea 1 Switzerland 2 Turkey 1 Ukraine 1 United Kingdom 11 United States 52 Global 539

TCI Chemicals (India) Pvt. Ltd.

Tel: --
Fax: --
Email: sales-in@tcichemicals.com
Country: India
ProdList: 6768
Advantage: 58

P C Chem

Tel: --
Fax: --
Email: info@pcchemindia.in
Country: India
ProdList: 675
Advantage: 58

Triveni chemicals

Tel: --
Fax: --
Email: sales@trivenichemical.com
Country: India
ProdList: 6088
Advantage: 58

Sisco Research Laboratories Pvt. Ltd.

Tel: --
Fax: --
Email: marketing@srlchem.com
Country: India
ProdList: 4315
Advantage: 58

Alfa Aesar

Tel: --
Fax: --
Email: tech@alfa.com
Country: India
ProdList: 6905
Advantage: 58

Deepak Nitrite Limited

Tel: --
Fax: --
Country: India
ProdList: 84
Advantage: 58

Merit International

Tel: --
Fax: --
Email: meritasia2@gmail.com
Country: India
ProdList: 226
Advantage: 58

ASM Organics

Tel: --
Fax: --
Country: India
ProdList: 1185
Advantage: 58

Vihita Chem Private Limited

Tel: --
Fax: --
Country: India
ProdList: 31
Advantage: 58

HiMedia Laboratories

Tel: --
Fax: --
Email: o@himedialabs.com
Country: India
ProdList: 1841
Advantage: 58

Anand Agencies

Tel: --
Fax: --
Email: en@gmail.com
Country: India
ProdList: 2332
Advantage: 58

Avra Synthesis Pvt Ltd

Tel: --
Fax: --
Email: info@avrasynthesis.com
Country: India
ProdList: 1603
Advantage: 30

Loba Chemie Pvt Ltd

Tel: --
Fax: --
Country: India
ProdList: 498
Advantage: 58

Drexel Fine Chem

Tel: --
Fax: --
Country: India
ProdList: 24
Advantage: 58

S. M. S. Pharmaceuticals Limited

Tel: --
Fax: --
Country: India
ProdList: 1
Advantage: 58

Perfect Chemical

Tel: --
Fax: --
Country: India
ProdList: 171
Advantage: 58

Vihita Chemicals

Tel: --
Fax: --
Country: India
ProdList: 20
Advantage: 58

Welstar

Tel: --
Fax: --
Country: India
ProdList: 1
Advantage: 58

Avra Synthesis Private Limited

Tel: --
Fax: --
Country: India
ProdList: 38
Advantage: 58

Sanjay Chemicals India Private Limited

Tel: --
Fax: --
Country: India
ProdList: 16
Advantage: 58

Otto Chemie Private Limited

Tel: --
Fax: --
Country: India
ProdList: 76
Advantage: 58

Synova Chemicals

Tel: --
Fax: --
Country: India
ProdList: 21
Advantage: 58

Karni Chemicals

Tel: --
Fax: --
Country: India
ProdList: 56
Advantage: 58

LOBA CHEMIE PVT.LTD.

Tel: --
Fax: --
Email: info@lobachemie.com
Country: India
ProdList: 3075
Advantage: 58

Central Drug House(P) Ltd.

Tel: --
Fax: --
Email: sales@cdhfinechemical.com
Country: India
ProdList: 6157
Advantage: 58

A.J Chemicals

Tel: --
Fax: --
Email: sales@ajchem.in
Country: India
ProdList: 6100
Advantage: 58

CHEMSWORTH

Tel: --
Fax: --
Email: info@chemsworth.com
Country: India
ProdList: 6700
Advantage: 30

S. Nihar Exports

Tel: --
Fax: --
Email: nihar@giasbm01.vsnl.net.in
Country: India
ProdList: 232
Advantage: 50

More

Less

View Lastest Price from Guanidine carbonate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Guanidine carbonate 593-85-1
Price: US $100.00-45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-04-30

Apeloa production Co.,Limited

Product: Carbonic acid-guanidine (1:2) 593-85-1
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 1000
Release date: 2024-06-06

hebei hongtan Biotechnology Co., Ltd

Product: Guanidine carbonate 593-85-1
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000
Release date: 2024-05-13

593-85-1, Guanidine carbonateRelated Search:

Ethylene carbonate Polycarbonate Sodium bicarbonate Calcium carbonate Dimethyl carbonate Sodium carbonate Lithium carbonate Ammonium bicarbonate Guanidine sulfate Barium carbonate FERROUS CARBONATE COBALT(II) CARBONATE HYDRATE Guanidine nitrate Strontium carbonate Magnesium carbonate Cesium carbonate Manganese carbonate Magnesium carbonate

Carbonic acid, compound with guanidine (1:2)

Guanidine·carbonic acid

Guanidne carbonate

Guanidinium carbonate, synthesis grade

Carbonicacid,compd.withguanidine(1:1)

Carbonicacid,compd.withguanidine(1:2)

Guanidonium-carbonat

Iminoureacarbonate

GUANIDINE CARBONAT

Guanidinecarbonate,98%

Guanidine carbonate, 99+%

AMINOMETHANAMIDINE CARBONATE

DIGUANIDINIUM CARBONATE

GUANIDINE CARBONATE

GUANIDINE CARBONATE SALT

GUANIDINIUM CARBONATE

Guanidine carbonate salt 99%

Guanidine carbonate(2:1)

C2H10N6H2CO3

Guanidine carbonateMedicine grade, ≥ 99% (Assay)

Guanidine carbonate≥ 98% (Assay)

Guanidinium carbonate for synthesis

ai3-14631

Bis(triaminomethyl) carbonate

Bisguanidinium carbonate

bisguanidiniumcarbonate

Carbonic acid, compd. with guanidine (1:2)

GUANIDINECARBONATE,REAGENT

Carbonic acid,compd. with guanidine

Guanidine Carbonate:(GC) pur.Powder

Carbamidine carbonate

N-nitroso-N-phenylpropanamide

GuanidineCarbonate&gt

carbarnidine car-bonate

uanidine carbonate saL

Carbonic acid, compd. with guanidine (1:2)OTHER CA INDEX NAMES:Guanidine, carbonate (2:1)

Guanidine Hemicarbonate

Guanidine Carbonate extrapure, 99%

GUANIDINE CARBONATE For Synthesis

Carbonate pus

guanidine carbonated

Guanidine Carbote 99% For Synthesis

Ribavirin Impurity 17(Diguanidinium carbonate)

593-85-1

C3H12O3N6

C2H7N3O3

CH5N312H2CO3

CH5N3x05H2CO3

CH5N305H2CO3

CH5N32H2CO3

C3H12N6O3

CH5N312CH2O3

C2H10N6

C2H10N6CH2O3

NH2CNHNH22H2CO3

HNCNH222H2CO3

C3H9N3O6

CH5N32CH2O3