Zinc dimethyldithiocarbamate

ChemicalBook > CAS DataBase List > Zinc dimethyldithiocarbamate

Zinc dimethyldithiocarbamate

Product Name: Zinc dimethyldithiocarbamate
CAS No.: 137-30-4
Chemical Name: Zinc dimethyldithiocarbamate
Synonyms: ZIRAM;ZDMC;Mexene;Rhodiacid;Accelerator PZ;Zinc bis dimethyldithiocarbamate;ZC;z75;Z 75;ZMDC
CBNumber: CB1202261
Molecular Formula: C6H12N2S4Zn1
Formula Weight: 305.829
MOL File: 137-30-4.mol

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Zinc dimethyldithiocarbamate Property

Melting point:: 248-257 °C(lit.)
Boiling point:: 335.83℃[at 101 325 Pa]
Density: 1.66
vapor pressure: <1 x 10^-6 Pa
storage temp.: APPROX 4°C
solubility: DMSO (Sparingly), Methanol (Sparingly)
form: Powder
Specific Gravity: 1.71
color: White
Odor: odorless when pure
Water Solubility: 0.0065 g/100 mL
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Merck: 14,10172
BRN: 3707008
InChIKey: DUBNHZYBDBBJHD-UHFFFAOYSA-L
LogP: 1.65 at 20℃
CAS DataBase Reference: 137-30-4(CAS DataBase Reference)
IARC: 3 (Vol. Sup 7, 53) 1991
NIST Chemistry Reference: Zinc, bis(dimethylcarbamodithioato-s,s')-, (t-4)-(137-30-4)
EPA Substance Registry System: Ziram (137-30-4)

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Safety

Hazard Codes: T+,N
Risk Statements: 22-26-37-41-43-48/22-50/53
Safety Statements: 22-26-28-36/37/39-45-60-61
RIDADR: UN 2811 6.1/PG 2
WGK Germany: 3
RTECS: ZH0525000
TSCA: Yes
HazardClass: 6.1
PackingGroup: II
HS Code: 29302000
Hazardous Substances Data: 137-30-4(Hazardous Substances Data)
Toxicity: LD50 orally in rats: 1.4 g/kg (Hodge)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H318Causes serious eye damage

H330Fatal if inhaled

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 45708
Product name: Ziram
Purity: PESTANAL
Packaging: 250mg
Price: $34.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 329711
Product name: Zinc dimethyldithiocarbamate
Purity: 97%
Packaging: 1kg
Price: $441
Updated: 2024/03/01

TCI Chemical

Product number: D0717
Product name: Zinc Dimethyldithiocarbamate
Purity: >97.0%(T)
Packaging: 25g
Price: $21
Updated: 2024/03/01

TCI Chemical

Product number: D0717
Product name: Zinc Dimethyldithiocarbamate
Purity: >97.0%(T)
Packaging: 500g
Price: $61
Updated: 2024/03/01

TRC

Product number: Z439650
Product name: Zinc Dimethyldithiocarbamate
Packaging: 1g
Price: $80
Updated: 2021/12/16

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Zinc dimethyldithiocarbamate Chemical Properties,Usage,Production

Chemical Properties

White and odorless when pure. Almost insoluble inwater; soluble in acetone, carbon disulfide, chloroform, dilute alkalies, and concentrated hydrochloric acid.

Uses

Ziram is a protective fungicide applied to foliage to control diseases on pome fruit, stone fruit, nuts, vines, vegetables and ornamentals. It is used to control scab in apples and pears and Monilia, Alternaria, Septoria, peach leaf curl, shot hole, rusts, black rot and anthracnose. It is also used as a wildlife repellent, smeared as a paste onto tree trunks or sprayed onto ornamentals, dormant fruit trees and other crops.

Uses

Zinc Dimethyldithiocarbamate is a member of a class of dithiocarbamates, and has been used in agriculture as a fungicide and in the rubber industry as a vulcanization accelerator.

Uses

Rubber vulcanization accelerator; agricultural fungicide.

Definition

ChEBI: A dithiocarbamate salt that is the zinc salt of dimethyldithiocarbamic acid. It is a broad-spectrum fungicide and bird and animal repellent that is also used to accelerate the vulcanisation of rubber.

Air & Water Reactions

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Insoluble in water.

Reactivity Profile

Zinc bis dimethyldithiocarbamate is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. Zinc bis dimethyldithiocarbamate is corrosive to iron and copper. Zinc bis dimethyldithiocarbamate is incompatible with strong oxidizing agents and acids. Zinc bis dimethyldithiocarbamate is also incompatible with mercury.

Hazard

Strong irritant to eyes and mucous membranes.

Fire Hazard

Zinc bis dimethyldithiocarbamate is combustible. Zinc bis dimethyldithiocarbamate may form explosive dust-air mixtures.

Flammability and Explosibility

Not classified

Agricultural Uses

Fungicide, Microbiocide, Animal repellant: Ziram is an agricultural fungicide registered to control fungal diseases on a wide range of crops including stone fruits, pome fruits, nut crops, vegetables and commercially grown ornamentals, and as a soil and seed treatment. In addition, it is formulated as a bird and rabbit repellent for outdoor foliar applications to ornamentals. Registered for use in EU countries . Registered for use in the U.S.

Trade name

AAPROTECT®; AAVOLEX®; AAZIRA®; ACCELERATOR®-L; ACCELERATOR® MZ® Powder; ACETO ZDED®; ACETO ZDMD®; ALCOBAM ZM®; ANCANZATE ME®; CARBAZINC®; CIRAM®; CORONA COROZATE®; COROZATE®; CUMAN®; CUMAN L®; CYMATE®; DRUPINA® 90; EPTAC-1®; FUCLASIN®; FUCLASIN® ULTRA; FUKLASIN®; FUNGOSTOP®; HERMAT ZDM®; HEXAZIR®; KARBAM WHITE®; KYPZIN®; METHASAN®; METHAZATE®; MEXENE®; MEZENE®; MILBAM®; MILBAN®; MOLURAME®; MYCRONIL®; OCTOCURE ZDM-50®; ORCHARD® BRAND ZIRAM; PERKACIT ZDMC®; POMARSOL® Z FORTE; PRODARAM®; PROKIL® Ziram; RHODIACID®; SOXINAL®-PZ; SOXINOL®-PZ; TRICARBAMIX Z®; TSIMAT®; TSIRAM® (Russian); ULTRA ZINC DMC®; VANCIDE® MZ-96; VANCIDE® 51Z Dispersion (with Zinc 2-mercaptobenzothiazolate); VANCIDE® 51Z Dispersion (with Ziram); ZERLATE®; ZINCMATE®; ZIMATE®; ZIMATE®; METHYL®; ZIRAMVIS®; ZIRASAN®; ZIRBERK®; ZIREX 90®; ZIRIDE®; ZIRTHANE®; ZITOX®

Contact allergens

Ziram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.

Safety Profile

Poison by ingestion,intraperitoneal, and intravenous routes. Moderately toxicby inhalation. Questionable carcinogen with experimentalcarcinogenic and tumorigenic data. An experimentalteratogen. Other experimental reproductive effects.Human mutation d

Metabolic pathway

Ziram is one of the metal containing dithiocarbamates which generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The resulting acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.

Purification Methods

Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. [Beilstein 4 III 149, 4 IV 234.]

Degradation

Ziram is decomposed in acidic media and by UV irradiation (PM). Ziram is stable in alkaline media but unstable in acidic conditions, decomposing to dimethylamine and carbon disulfide.

Zinc dimethyldithiocarbamate Preparation Products And Raw materials

Raw materials

Sodium dimethyldithiocarbamate Zinc sulphate Fumei zinc original drug Zinc chloride Sodium formate Dimethyl disulfide

Preparation Products

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Zinc dimethyldithiocarbamate Suppliers

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View Lastest Price from Zinc dimethyldithiocarbamate manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: Zinc dimethyldithiocarbamate 137-30-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-16

Hebei Guanlang Biotechnology Co., Ltd.

Product: Zinc dimethyldithiocarbamate 137-30-4
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-03-27

Zhuozhou Wenxi import and Export Co., Ltd

Product: Zinc bis dimethyldithiocarbamate 137-30-4
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

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THIONIC

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alcobamzm

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bis(dimethylcarbamodithioato-S,S’)-,(T-4)-Zinc

bis(dimethylcarbamodithioato-s,s’)zinc

Bis(dimethyldithiocarbamat)zinc

bis(dimethyldithiocarbamato)-zin

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cumanl

Cymate

Dimethylcarbamodithioic acid, zinc salt

dimethylcarbamodithioicacid,zinccomplex

dimethylcarbamodithioicacid,zincsalt

dimethyl-carbamodithioicacizincsalt

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dimethyldithiocarbamatezincsalt

dimethyldithio-carbamicacizincsalt(2:1)

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drupina90

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