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TITANIUM(IV) BROMIDE

Product Name
TITANIUM(IV) BROMIDE
CAS No.
7789-68-6
Chemical Name
TITANIUM(IV) BROMIDE
Synonyms
TiBr4;Titanium bromide;Tetrabromotitanium;TITANIUM(IV) BROMIDE;Titanium(Ⅳ) Bromide;TITANIUM TETRABROMIDE;Tetrabromotitanium(IV);Titanium(IV) bromide,98%;Titanium(IV) bromide 98%;Titanium(IV) tetrabromide
CBNumber
CB1202645
Molecular Formula
Br4Ti
Formula Weight
367.48
MOL File
7789-68-6.mol
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TITANIUM(IV) BROMIDE Property

Melting point:
38-40 °C(lit.)
Boiling point:
230 °C(lit.)
Density 
3.25 g/mL at 25 °C(lit.)
Flash point:
233°C
solubility 
reacts with H2O
form 
powder
color 
Orange
Specific Gravity
2.6
Water Solubility 
Soluble in absolute alcohol. Decomposes in waterSoluble in chlorocarbons, benzene and alcohol.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Merck 
14,9477
CAS DataBase Reference
7789-68-6
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
3-8-10-21
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
28275900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
307793
Product name
Titanium(IV) bromide
Purity
98%
Packaging
25g
Price
$111
Updated
2024/03/01
Sigma-Aldrich
Product number
307793
Product name
Titanium(IV) bromide
Purity
98%
Packaging
100g
Price
$325
Updated
2024/03/01
Alfa Aesar
Product number
039592
Product name
Titanium(IV) bromide
Purity
98%
Packaging
10g
Price
$71.1
Updated
2024/03/01
Strem Chemicals
Product number
93-2221
Product name
Titanium(IV) bromide, min. 98%
Packaging
5g
Price
$34
Updated
2024/03/01
Strem Chemicals
Product number
93-2221
Product name
Titanium(IV) bromide, min. 98%
Packaging
25g
Price
$91
Updated
2024/03/01
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TITANIUM(IV) BROMIDE Chemical Properties,Usage,Production

Chemical Properties

Orange low melting lumps and powder

Uses

Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates.

Purification Methods

Purify it by distillation. The distillate forms light orange hygroscopic crystals. Store it in the dark under N2 preferably in sealed brown glass ampules. [Olsen & Ryan J Am Chem Soc 54 2215 1932.]

TITANIUM(IV) BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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7789-68-6, TITANIUM(IV) BROMIDERelated Search:


  • TiBr4
  • Titanium bromide
  • Titanium bromide (TiBr4), (T-4)-
  • Titaniumbromide(TiBr4),(T-4)-
  • TITANIUM(IV) BROMIDE, ANHYDROUS, POWDER, 99.99%
  • TITANIUM(IV) BROMIDE
  • TITANIUM TETRABROMIDE
  • Titanium(IV)bromide,min.98%
  • TITANIUM(IV) BROMIDE ON METALS BASIS
  • TITANIUM TETRABROMIDE (99.% on metals basis)
  • Titanium(IV) bromide, min. 98%
  • Tetrabromotitanium(IV)
  • Titanium(IV) tetrabromide
  • Titanium(IV) bromide,98%
  • Titanium(Ⅳ) Bromide
  • Titanium(IV) bromide 98%
  • TITANIUM TETRABROMIDE (99.9% on Metals basis)
  • Tetrabromotitanium
  • TITANIUM(IV) BROMIDE ISO 9001:2015 REACH
  • 7789-68-6
  • Br4Ti
  • Catalysis and Inorganic Chemistry
  • Titanium
  • metal halide