TITANIUM(IV) BROMIDE
- Product Name
- TITANIUM(IV) BROMIDE
- CAS No.
- 7789-68-6
- Chemical Name
- TITANIUM(IV) BROMIDE
- Synonyms
- TiBr4;Titanium bromide;Tetrabromotitanium;TITANIUM(IV) BROMIDE;Titanium(Ⅳ) Bromide;TITANIUM TETRABROMIDE;Tetrabromotitanium(IV);Titanium(IV) bromide,98%;Titanium(IV) bromide 98%;Titanium(IV) tetrabromide
- CBNumber
- CB1202645
- Molecular Formula
- Br4Ti
- Formula Weight
- 367.48
- MOL File
- 7789-68-6.mol
TITANIUM(IV) BROMIDE Property
- Melting point:
- 38-40 °C(lit.)
- Boiling point:
- 230 °C(lit.)
- Density
- 3.25 g/mL at 25 °C(lit.)
- Flash point:
- 233°C
- solubility
- reacts with H2O
- form
- powder
- color
- Orange
- Specific Gravity
- 2.6
- Water Solubility
- Soluble in absolute alcohol. Decomposes in waterSoluble in chlorocarbons, benzene and alcohol.
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Merck
- 14,9477
- CAS DataBase Reference
- 7789-68-6
Safety
- Hazard Codes
- C
- Risk Statements
- 14-34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- F
- 3-8-10-21
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 28275900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 307793
- Product name
- Titanium(IV) bromide
- Purity
- 98%
- Packaging
- 25g
- Price
- $111
- Updated
- 2024/03/01
- Product number
- 307793
- Product name
- Titanium(IV) bromide
- Purity
- 98%
- Packaging
- 100g
- Price
- $325
- Updated
- 2024/03/01
- Product number
- 039592
- Product name
- Titanium(IV) bromide
- Purity
- 98%
- Packaging
- 10g
- Price
- $71.1
- Updated
- 2024/03/01
- Product number
- 93-2221
- Product name
- Titanium(IV) bromide, min. 98%
- Packaging
- 5g
- Price
- $34
- Updated
- 2024/03/01
- Product number
- 93-2221
- Product name
- Titanium(IV) bromide, min. 98%
- Packaging
- 25g
- Price
- $91
- Updated
- 2024/03/01
TITANIUM(IV) BROMIDE Chemical Properties,Usage,Production
Chemical Properties
Orange low melting lumps and powder
Uses
Titanium(IV) bromide is used as a Lewis acid catalyst in organic synthesis. It reacts with tetrahydrofurnan and 2-methylpyridine and forms adducts such as TiBr4(THF)2 and TiBr4(2-MePy). It is also used for the formation of titanium silicide thin films on silicon substrates.
Purification Methods
Purify it by distillation. The distillate forms light orange hygroscopic crystals. Store it in the dark under N2 preferably in sealed brown glass ampules. [Olsen & Ryan J Am Chem Soc 54 2215 1932.]