BENZYL 3-BROMOPROPYL ETHER
- Product Name
- BENZYL 3-BROMOPROPYL ETHER
- CAS No.
- 54314-84-0
- Chemical Name
- BENZYL 3-BROMOPROPYL ETHER
- Synonyms
- DK816;DKSI050;DKFELEX0213;Benzyl 3-bromopropyl;3-benzyloxybromopropane;Benzyl 3-bromoethyl ether;3-benzyloxy-1-broMopropane;1-bromo-3-benzyloxypropane;BENZYL 3-BROMOPROPYL ETHER;3-Benzyloxypropane bromide
- CBNumber
- CB1233500
- Molecular Formula
- C10H13BrO
- Formula Weight
- 229.11
- MOL File
- 54314-84-0.mol
BENZYL 3-BROMOPROPYL ETHER Property
- Boiling point:
- 130-132 °C8 mm Hg(lit.)
- Density
- 1.298 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.531(lit.)
- Flash point:
- >230 °F
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Liquid
- color
- Colorless
- Water Solubility
- Slightly soluble in water.
- InChI
- InChI=1S/C10H13BrO/c11-7-4-8-12-9-10-5-2-1-3-6-10/h1-3,5-6H,4,7-9H2
- InChIKey
- PSUXTZLDBVEZTD-UHFFFAOYSA-N
- SMILES
- C1(COCCCBr)=CC=CC=C1
- CAS DataBase Reference
- 54314-84-0(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 382043
- Product name
- Benzyl 3-bromopropyl ether
- Purity
- 98%
- Packaging
- 1g
- Price
- $34.65
- Updated
- 2025/07/31
- Product number
- 382043
- Product name
- Benzyl 3-bromopropyl ether
- Purity
- 98%
- Packaging
- 10g
- Price
- $62.32
- Updated
- 2025/07/31
- Product number
- B2818
- Product name
- Benzyl 3-Bromopropyl Ether
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $102
- Updated
- 2025/07/31
- Product number
- B2818
- Product name
- Benzyl 3-Bromopropyl Ether
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $356
- Updated
- 2025/07/31
- Product number
- B267895
- Product name
- 1-Benzyloxy-3-bromopropane
- Packaging
- 25g
- Price
- $445
- Updated
- 2021/12/16
BENZYL 3-BROMOPROPYL ETHER Chemical Properties,Usage,Production
Chemical Properties
Clear colorless to yellow liquid
Uses
Benzyl 3-bromopropyl ether may be used in the studies of preparation of (2S,3S)-1-[(triisopropylsilyl)oxy]-7-(benzyloxy)-2,3-(isopropylidenedioxy)-4(Z)-heptene, Ppeparation of 5-(3-Benzyloxypropoxy)psoralen (PAP-7), total synthesis of zincophorin and (+)-anatoxin-a.
General Description
Benzyl 3-bromopropyl ether is an ether.
Synthesis
4799-68-2
54314-84-0
GENERAL STEPS: To a dry reaction flask equipped with a magnetic stirrer under nitrogen protection, copper catalyst (2 mg, 0.002 mmol, 0.01 equiv), 3-benzyloxy-1-propanol (0.20 mmol, 1.0 equiv), carbon tetrabromide (131.6 mg, 0.4 mmol, 2.0 equiv) and sodium bromide (41 mg. 0.40 mmol, 2.0 equiv). The reaction vial was sealed and anhydrous DMF (1.5 mL) was added using a syringe. The reaction mixture was stirred under the light of a purple LED (394 nm) for 24 hours. Upon completion of the reaction, the mixture was transferred to a dispensing funnel and extracted by adding ether (10 mL) and water (10 mL). The organic phase was separated and the aqueous phase was further extracted with ether (2 x 10 mL). The organic phases were combined and washed sequentially with saturated aqueous NaHCO3 solution, Na2S2O3 solution and brine, dried with anhydrous Na2SO4 and concentrated under reduced pressure. Finally, the target product 3-benzyloxypropyl bromide was purified by silica gel column chromatography (100% hexane).
References
[1] Journal of the American Chemical Society, 2008, vol. 130, # 18, p. 6018 - 6024
[2] Beilstein Journal of Organic Chemistry, 2018, vol. 14, p. 2730 - 2736
[3] Patent: WO2008/157726, 2008, A1. Location in patent: Page/Page column 220
[4] Tetrahedron Letters, 2016, vol. 57, # 13, p. 1486 - 1488
[5] Journal of the American Chemical Society, 1982, vol. 104, # 4, p. 1054 - 1068
BENZYL 3-BROMOPROPYL ETHER Preparation Products And Raw materials
Raw materials
Preparation Products
BENZYL 3-BROMOPROPYL ETHER Suppliers
- Tel
- --
- Fax
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- Country
- Belgium
- ProdList
- 6293
- Advantage
- 73
View Lastest Price from BENZYL 3-BROMOPROPYL ETHER manufacturers
- Product
- BENZYL 3-BROMOPROPYL ETHER 54314-84-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-09
- Product
- BENZYL 3-BROMOPROPYL ETHER 54314-84-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- BENZYL 3-BROMOPROPYL ETHER 54314-84-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg,5kg,100kg
- Release date
- 2019-07-04