4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE

Uses

Product Name: 4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE
CAS No.: 194800-56-1
Chemical Name: 4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE
Synonyms: DK7370;Benzoicacid,10-methoxy-,hydrazide;2,2'-Bipyridine-4,4'-diphosphonic Acid;4,4'-diphosphonic acid-2,2'-bipyridine;2-amino-8-(methylsulfonyl)-Benzonitrile;2,2'-Bipyridine-4,4'-bis(phosphonic acid);2,2'-Bipyridine]-4,4'-diyldiphosphonic acid;[2,2'-Bipyridine]-4,4'-diyldiphosphonic acid;2,2'-bipyridine-4,4'-diylbis(phosphonic acid);2,2'-Bipyridine-4,4'-bis(phosphonic acid) 97%
CBNumber: CB12455432
Molecular Formula: C10H10N2O6P2
Formula Weight: 316.14
MOL File: 194800-56-1.mol

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4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE Property

Boiling point:: 741.1±70.0 °C(Predicted)
Density: 1.78±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
pka: 0.06±0.10(Predicted)
Appearance: Off-white to light yellow Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: CHM0386055
Product name: 4,4'-BIS-(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE
Purity: 95.00%
Packaging: 5MG
Price: $505.44
Updated: 2021/12/16

Alichem

Product number: 194800561
Product name: [2,2'-Bipyridine]-4,4'-diyldiphosphonicacid
Packaging: 1g
Price: $515.1
Updated: 2021/12/16

Arctom

Product number: AS514462
Product name: [2,2'-Bipyridine]-4,4'-diyldiphosphonicacid
Purity: 97%
Packaging: 1g
Price: $529
Updated: 2021/12/16

Ambeed

Product number: A306972
Product name: [2,2'-Bipyridine]-4,4'-diyldiphosphonicacid
Purity: 97%
Packaging: 1g
Price: $534
Updated: 2021/12/16

Chemenu

Product number: CM173442
Product name: [2,2''-bipyridine]-4,4''-diylbis(phosphonicacid)
Purity: 97%
Packaging: 5g
Price: $828
Updated: 2021/12/16

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4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE Chemical Properties,Usage,Production

Uses

2,2'-Bipyridine-4,4'-bisphosphonic acid is an organic intermediate that can be used to prepare two-dimensional proton-conducting MOF materials, etc.

Synthesis

174397-53-6

194800-56-1

Diethyl 2,2'-bipyridine-4,4'-bisphosphonate (1.26 g, 2.94 mmol, 1.00 eq.) was dissolved in anhydrous dichloromethane under argon protection. To this solution was added bromotrimethylsilane (4.50 g, 29.4 mmol, 10.0 eq.), and the resulting yellow solution was stirred and reacted at room temperature for 24 hours. Upon completion of the reaction, methanol was slowly added dropwise until the color of the reaction mixture changed from yellow to colorless. Subsequently, extraction was carried out with water and 2,2'-bipyridine-4,4'-bisphosphonic acid (Compound 7) was isolated as a light yellow solid (0.93 g, 4.49 mmol, quantitative yield). The structure of the product was confirmed by nuclear magnetic resonance hydrogen (1H NMR, 400 MHz, DMSO-d6) and phosphorus spectra (31P NMR, 500 MHz, CDCl3): 1H NMR δ 8.85 (t, J = 4.5 Hz, 2H), 8.67 (d, J = 13.6 Hz, 2H), 7.73 (dd, J = 12.4, 4.8 Hz, 2H); 31P NMR δ 8.45 (s).

References

[1] Dyes and Pigments, 2014, vol. 104, p. 24 - 33
[2] Tetrahedron Letters, 1998, vol. 39, # 22, p. 3689 - 3692
[3] Inorganic Chemistry, 2015, vol. 54, # 2, p. 460 - 469

4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE Suppliers

China 59 India 1 United States 2 Global 62

Bide Pharmatech Ltd.

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Zhengzhou HongSheng Pharmaceutical Co., Ltd.

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Shanghai Worldyang Chemical Co.,Ltd.

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Shanghai Uchem Inc.

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BePharm Ltd

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Zhengzhou AnMusi Chemical Products Co., Ltd.

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Zhengzhou Acme Chemical Co., Ltd.

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Amadis Chemical Company Limited

Tel: 571-89925085
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ProdList: 131957
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Zhengzhou JACS Chemical Co., Ltd.

Tel: 0371-0371-86259281 15981966935
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View Lastest Price from 4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE manufacturers

Shanghai UCHEM Inc.

Product: 2,2'-Bipyridine-4,4'-bis(phosphonic acid) 194800-56-1
Price: US $296.00-1037.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 1kg
Release date: 2023-11-24

194800-56-1, 4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINERelated Search:

2,2'-bipyridine-4-carboxylic acid 5,5'-Dibromo-2,2'-bipyridyl 4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE) 2,2'-Bipyridine-4,4'-dicarboxylic acid 4,4'-DIMETHOXY-2,2'-BIPYRIDINE 5,5'-DIMETHYL-2,2'-DIPYRIDYL 4,4'-Bis(hydroxymethyl)-2,2'-bipyridine 6,6'-Dimethyl-2,2'-dipyridyl 2,2-bipyridine-6-carboxylic acid 4'-(9-Anthracenyl)-2,2':6',2''-terpyridine 2,6-BIS(2-PYRIDYL)-4(1H)-PYRIDONE 2,2':6',2''-TERPYRIDINE-4'-CARBALDEHYDE 4'-(4-BROMOPHENYL)-2,2':6',2''-TERPYRIDINE 2,2':6',2''-TERPYRIDINE 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLIC ACID 4,4'-DIBROMO-2,2'-BIPYRIDINE 4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE TETRAETHYL 2,2'-BIPYRIDINE-4,4'-BISPHOSPHONATE

4,4'-BIS(DIHYDROXYPHOSPHORYL)-2,2'-BIPYRIDINE

2,2'-Bipyridine-4,4'-bis(phosphonic acid) 97%

2,2'-bipyridine-4,4'-diylbis(phosphonic acid)

[2,2'-Bipyridine]-4,4'-diyldiphosphonic acid

4,4'-diphosphonic acid-2,2'-bipyridine

Phosphonic acid, P,P'-[[2,2'-bipyridine]-4,4'-diyl]bis-

[2-(4-phosphonopyridin-2-yl)pyridin-4-yl]phosphonic acid

2,2'-Bipyridine-4,4'-diphosphonic Acid

Phosphonic acid, [2,2'-bipyridine]-4,4'-diylbis-

Benzoicacid,10-methoxy-,hydrazide

2-amino-8-(methylsulfonyl)-Benzonitrile

DK7370

2,2'-Bipyridine-4,4'-bis(phosphonic acid)

2,2'-Bipyridine]-4,4'-diyldiphosphonic acid

194800-56-1

C10H10N2O10P2

C10H10N2O6P2