METHYL 2-METHOXY-6-NITROBENZOATE

Product Name: METHYL 2-METHOXY-6-NITROBENZOATE
CAS No.: 77901-52-1
Chemical Name: METHYL 2-METHOXY-6-NITROBENZOATE
Synonyms: thyl2-Methoxy-6-nitrobenzoate;METHYL 2-METHOXY-6-NITROBENZOATE;Benzoic acid, 2-methoxy-6-nitro-, methyl ester
CBNumber: CB12465602
Molecular Formula: C9H9NO5
Formula Weight: 211.17
MOL File: 77901-52-1.mol

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METHYL 2-METHOXY-6-NITROBENZOATE Property

Melting point:: 63-65 °C(Solv: ethanol (64-17-5))
Boiling point:: 326.5±22.0 °C(Predicted)
Density: 1.294±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M219603
Product name: Methyl2-Methoxy-6-nitrobenzoate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

AK Scientific

Product number: Z3241
Product name: Methyl2-methoxy-6-nitrobenzoate
Packaging: 1g
Price: $149
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0392963
Product name: METHYL-2-METHOXY-6-NITROBENZOATE
Purity: 95.00%
Packaging: 5MG
Price: $504.67
Updated: 2021/12/16

AK Scientific

Product number: Z3241
Product name: Methyl2-methoxy-6-nitrobenzoate
Packaging: 10g
Price: $667
Updated: 2021/12/16

Matrix Scientific

Product number: 119586
Product name: Methyl2-methoxy-6-nitrobenzoate
Purity: 95+%
Packaging: 5g
Price: $810
Updated: 2021/12/16

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METHYL 2-METHOXY-6-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

4837-88-1

75-65-0

77901-52-1

General procedure for the synthesis of methyl 2-methoxy-6-nitrobenzoate from 2-methyl-3-nitroanisole and tert-butanol: Potassium permanganate (KMnO4, 5.7 g, 36 mmol) was added to a suspension of 2-methyl-3-nitroanisole (2.0 g, 12 mmol) in tert-butanol (10 mL) and water (20 mL). The reaction mixture was heated to reflux and kept for 4 hours. After completion of the reaction, the cooled mixture was filtered through diatomaceous earth. The filtrate was acidified with 12N aqueous hydrochloric acid and subsequently extracted twice with ethyl acetate (EtOAc). The organic layers were combined, washed sequentially with water and saturated saline, dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated under reduced pressure. The resulting residue was treated with excess diazomethane/ether (Et2O) solution to afford the target product methyl 2-methoxy-6-nitrobenzoate (548 mg, 22% yield).

References

[1] Patent: US2004/106791, 2004, A1. Location in patent: Page 15

METHYL 2-METHOXY-6-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-METHOXY-6-NITROBENZOATE Suppliers

China 34 India 3 United States 7 Global 44

SynAsst Chemical.

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View Lastest Price from METHYL 2-METHOXY-6-NITROBENZOATE manufacturers

Career Henan Chemical Co

Product: METHYL 2-METHOXY-6-NITROBENZOATE 77901-52-1
Price: US $0.01/KG
Min. Order: 500g
Purity: 98%; 99%
Supply Ability: 500g；1kg； 10kg; 25kg
Release date: 2020-01-08

77901-52-1, METHYL 2-METHOXY-6-NITROBENZOATERelated Search:

Dimethyl carbonate 3-Methyl-2-nitrobenzoic acid 3-Nitrophthalic acid

METHYL 2-METHOXY-6-NITROBENZOATE

thyl2-Methoxy-6-nitrobenzoate

Benzoic acid, 2-methoxy-6-nitro-, methyl ester

77901-52-1