ChemicalBook > CAS DataBase List > N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
Reaction- Product Name
- N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
- CAS No.
- 1237588-12-3
- Chemical Name
- N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
- Synonyms
- Mor-DalPhos;Di(1-adamantyl)-2-morpholinophenylphosphine;MorDalphos 97%;98% Mor-DalPhos;N-[2-(di-1-adamantyL;2-Morpholinophenyldi(1-adamantyl)phosphine;Bis(adamant-1-yl)(2-morpholinophenyl)phosphine;N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine;4-[2-[Di(1-Adamantyl)phosphino]phenyl]morpholine;bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane
- CBNumber
- CB12512504
- Molecular Formula
- C30H42NOP
- Formula Weight
- 463.63
- MOL File
- 1237588-12-3.mol
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Property
- Melting point:
- 219-224°C
- storage temp.
- 2-8°C
- form
- crystal
- pka
- 4.75±0.40(Predicted)
- color
- white to yellow
- Sensitive
- air sensitive
- CAS DataBase Reference
- 1237588-12-3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 751618
- Product name
- Di(1-adamantyl)-2-morpholinophenylphosphine
- Purity
- 97%
- Packaging
- 1g
- Price
- $344
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 751618
- Product name
- Di(1-adamantyl)-2-morpholinophenylphosphine
- Purity
- 97%
- Packaging
- 5g
- Price
- $1010
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1092
- Product name
- N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos
- Packaging
- 250mg
- Price
- $76
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1092
- Product name
- N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos
- Packaging
- 1g
- Price
- $232
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 751618
- Product name
- Di(1-adamantyl)-2-morpholinophenylphosphine
- Purity
- 97%
- Packaging
- 250mg
- Price
- $90.6
- Updated
- 2024/03/01
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Chemical Properties,Usage,Production
Reaction
- P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
- P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
- P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.
Uses
Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates.
Uses
MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.
reaction suitability
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Preparation Products And Raw materials
Raw materials
Preparation Products
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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Suppliers
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- +1-858-6993322
- Fax
- (+1)-858-876-1948
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View Lastest Price from N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- N-[2-(di-1-adamantylphosphino) phenyl]morpholine 1237588-12-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 0.99
- Supply Ability
- 500kg
- Release date
- 2021-11-30
Career Henan Chemical Co
- Product
- N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos 1237588-12-3
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-08