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2-CHLORO-4-SULFAMOYLANILINE

Product Name
2-CHLORO-4-SULFAMOYLANILINE
CAS No.
53297-68-0
Chemical Name
2-CHLORO-4-SULFAMOYLANILINE
Synonyms
Diazoxide Impurity 11;2-CHLORO-4-SULFAMOYLANILINE;Hydrochlorothiazide Impurity 71;4-amino-3-chlorobenzenesulfonamide;4-amino-3-chloro-benzenesulfonamid;Benzenesulfonamide, 4-amino-3-chloro-;4-amino-3-chlorobenzene-1-sulfonamide;3-14-00-02189 (Beilstein Handbook Reference)
CBNumber
CB1261277
Molecular Formula
C6H7ClN2O2S
Formula Weight
206.65
MOL File
53297-68-0.mol
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2-CHLORO-4-SULFAMOYLANILINE Property

Melting point:
161 °C
Boiling point:
414.4±55.0 °C(Predicted)
Density 
1.558±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
solid
pka
9.83±0.60(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C6H7ClN2O2S/c7-5-3-4(12(9,10)11)1-2-6(5)8/h1-3H,8H2,(H2,9,10,11)
InChIKey
LFIOFZKZCDMGFG-UHFFFAOYSA-N
SMILES
C1(S(N)(=O)=O)=CC=C(N)C(Cl)=C1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS007881
Product name
2-chloro-4-sulfamoylaniline
Purity
AldrichCPR
Packaging
250MG
Price
$216
Updated
2025/07/31
TRC
Product number
C428993
Product name
2-Chloro-4-sulfamoylaniline
Packaging
25mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
0225CG
Product name
4-Amino-3-chlorobenzenesulfonamide
Packaging
250mg
Price
$124
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0019246
Product name
2-CHLORO-4-SULFAMOYLANILINE
Purity
95.00%
Packaging
1G
Price
$837.99
Updated
2021/12/16
AK Scientific
Product number
0225CG
Product name
4-Amino-3-chlorobenzenesulfonamide
Packaging
1g
Price
$261
Updated
2021/12/16
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2-CHLORO-4-SULFAMOYLANILINE Chemical Properties,Usage,Production

Uses

2-Chloro-4-sulfamoylanilide is an organic compound commonly used as a synthetic intermediate, especially in the synthesis of pharmaceuticals, pesticides and dyes.

Synthesis

63-74-1

53297-68-0

The general procedure for the synthesis of 4-amino-3-chlorobenzenesulfonamide from crystalline sulfonamide was as follows: 1 mmol of sulfonamide was dissolved in 12 mL of tetrahydrofuran under anhydrous and anaerobic conditions. Subsequently, 2 mmol of N-chlorosuccinimide (NCS) powder was added, and the reaction mixture was stirred at 40 °C for 25 hours. After completion of the reaction, the solvent was evaporated by rotary evaporator. The residue was extracted with 30 mL of ethyl acetate. The organic layer was washed sequentially with 5 mL of saturated potassium carbonate solution and 5 mL of saturated sodium chloride solution. The washed organic layer was dried with anhydrous sodium sulfate, filtered and purified by column chromatography (eluent ratio of dichloromethane: ethyl acetate = 7:1). Finally, 188 mg of the light yellow powdery product 4-amino-3-chlorobenzenesulfonamide was obtained in 95% yield.

References

[1] Patent: CN107400060, 2017, A. Location in patent: Paragraph 0011; 0029; 0030; 0036; 0037; 0043-0044; 0050-0051
[2] Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1988, vol. 27, # 12, p. 1028 - 1030

2-CHLORO-4-SULFAMOYLANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLORO-4-SULFAMOYLANILINE Suppliers

Taizhou FRIEND Chemical Co., Ltd.
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025-0523-86200082 15380713688
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0523-86200991
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Austin@fredchem.cn
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China
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Candia Thamtech Company Limited
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0371-86615086 18203638366 0371-86159066 13526786601
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China
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021-35122006
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ChemStrong Scientific Co.,Ltd
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Taizhou Yikang Chemical Co., Ltd.
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+86-576-88501337
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Shanghai JingRon Chemical Technology Co., Ltd.
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Shanghai Send Pharmaceutical Technology Co., Ltd.
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Shanghai YuanYe Biotechnology Co., Ltd.
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parabiochem
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025-83453382-8005
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BioPharmaMatrix,Inc.
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0510-86010668
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0510-86010668
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sales@biopharmamatrix.com
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China
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View Lastest Price from 2-CHLORO-4-SULFAMOYLANILINE manufacturers

Nanjing Fred Technology Co., Ltd
Product
2-Chloro-4-sulfamoylaniline 53297-68-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.9%HPLC
Supply Ability
5ton
Release date
2023-11-29
Career Henan Chemical Co
Product
2-CHLORO-4-SULFAMOYLANILINE 53297-68-0
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-08