1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate

ChemicalBook > CAS DataBase List > 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate

1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate

Product Name: 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
CAS No.: 119752-83-9
Chemical Name: 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
Synonyms: DABSO;1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct;DABCO-Bis(sulfur Dioxide);1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate;1,4-Diazoniabicyclo[2.2.2]octane, 1,4-disulfino-, bis(inner salt);4-diium-1;4-disulfinate;4-Diazabicyclo[2.2.2]octane-1;1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulfinate;1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
CBNumber: CB12693766
Molecular Formula: C6H12N2O4S2
Formula Weight: 240.29
MOL File: 119752-83-9.mol

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1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Property

Melting point:: 180 °C(dec.)
storage temp.: 2-8°C
Water Solubility: Soluble in water
form: powder to crystal
color: White to Almost white
InChIKey: RWISEVUOFYXWFO-UHFFFAOYSA-N
CAS DataBase Reference: 119752-83-9

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Safety

Hazard Codes: F,Xn
Risk Statements: 11-22-36/37/38-52/53
Safety Statements: 26-60
RIDADR: UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany: 3
HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 742937
Product name: 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
Purity: ≥95% (sulfur, elemental analysis)
Packaging: 1g
Price: $71.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 742937
Product name: 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
Purity: ≥95% (sulfur, elemental analysis)
Packaging: 5g
Price: $210
Updated: 2024/03/01

TCI Chemical

Product number: B3960
Product name: Bis(sulfur Dioxide)-1,4-diazabicyclo[2.2.2]octane Adduct
Purity: >97.0%(T)
Packaging: 1g
Price: $44
Updated: 2024/03/01

TCI Chemical

Product number: B3960
Product name: Bis(sulfur Dioxide)-1,4-diazabicyclo[2.2.2]octane Adduct
Purity: >97.0%(T)
Packaging: 5g
Price: $151
Updated: 2024/03/01

TRC

Product number: D417603
Product name: 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
Packaging: 50mg
Price: $60
Updated: 2021/12/16

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1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Chemical Properties,Usage,Production

Uses

1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) is a charge transfer complex that can be used as a sulfur dioxide surrogate:

In palladium-catalyzed aminosulfonylation process.
In reaction with aryl bromides to synthesize sodium aryl sulfinates.

It can also be used to activate DMSO and o-vinylanilines for the synthesis of N-aryl-1H-benzo[d]imidazol-1-amine and 4-aryl quinolines, respectively.

1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate manufacturers

Career Henan Chemical Co

Product: 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 119752-83-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-09

119752-83-9, 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinateRelated Search:

Hexane

1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate

1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct

1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct >=95% (sulfur, eleMental analysis)

DABSO

1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate

1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulfinate

Bis(sulfur Dioxide)-1,4-diazabicyclo[2.2.2]octane Adduct

1,4-diazabicyclo [2.2.2] octane-1,4-dinium-1,4-disulfonic acid

1,4-Diazoniabicyclo[2.2.2]octane, 1,4-disulfino-, bis(inner salt)

DABCO-Bis(sulfur Dioxide)

4-disulfinate

4-diium-1

4-Diazabicyclo[2.2.2]octane-1

119752-83-9