ChemicalBook > CAS DataBase List > 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
- Product Name
- 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
- CAS No.
- 119752-83-9
- Chemical Name
- 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
- Synonyms
- DABSO;1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct;DABCO-Bis(sulfur Dioxide);1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulphinate;1,4-Diazoniabicyclo[2.2.2]octane, 1,4-disulfino-, bis(inner salt);4-diium-1;4-disulfinate;4-Diazabicyclo[2.2.2]octane-1;1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulfinate;1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate
- CBNumber
- CB12693766
- Molecular Formula
- C6H12N2O4S2
- Formula Weight
- 240.29
- MOL File
- 119752-83-9.mol
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1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Property
- Melting point:
- 180 °C(dec.)
- storage temp.
- 2-8°C
- Water Solubility
- Soluble in water
- form
- powder to crystal
- color
- White to Almost white
- InChIKey
- RWISEVUOFYXWFO-UHFFFAOYSA-N
- CAS DataBase Reference
- 119752-83-9
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Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 11-22-36/37/38-52/53
- Safety Statements
- 26-60
- RIDADR
- UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
- WGK Germany
- 3
- HS Code
- 2933998090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 742937
- Product name
- 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
- Purity
- ≥95% (sulfur, elemental analysis)
- Packaging
- 1g
- Price
- $71.4
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 742937
- Product name
- 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
- Purity
- ≥95% (sulfur, elemental analysis)
- Packaging
- 5g
- Price
- $210
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B3960
- Product name
- Bis(sulfur Dioxide)-1,4-diazabicyclo[2.2.2]octane Adduct
- Purity
- >97.0%(T)
- Packaging
- 1g
- Price
- $44
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B3960
- Product name
- Bis(sulfur Dioxide)-1,4-diazabicyclo[2.2.2]octane Adduct
- Purity
- >97.0%(T)
- Packaging
- 5g
- Price
- $151
- Updated
- 2024/03/01
TRC
- Product number
- D417603
- Product name
- 1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
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1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Chemical Properties,Usage,Production
Uses
1,4-Diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) is a charge transfer complex that can be used as a sulfur dioxide surrogate:
- In palladium-catalyzed aminosulfonylation process.
- In reaction with aryl bromides to synthesize sodium aryl sulfinates.
It can also be used to activate DMSO and o-vinylanilines for the synthesis of N-aryl-1H-benzo[d]imidazol-1-amine and 4-aryl quinolines, respectively.
1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Preparation Products And Raw materials
Raw materials
Preparation Products
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1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate Suppliers
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View Lastest Price from 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate manufacturers
Career Henan Chemical Co
- Product
- 1,4-Diazabicyclo[2.2.2]octane-1,4-diium-1,4-disulfinate 119752-83-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-09