ChemicalBook > CAS DataBase List > TRANS-(+)-CHRYSANTHEMIC ACID

TRANS-(+)-CHRYSANTHEMIC ACID

Product Name
TRANS-(+)-CHRYSANTHEMIC ACID
CAS No.
4638-92-0
Chemical Name
TRANS-(+)-CHRYSANTHEMIC ACID
Synonyms
d-trans-Form;rans-Chrysanthemicaci;ChrysantheMic Acid Chloride;(1r-trans)-chrysanthemicacid;(+)-trans-Chrysanthemic acid;trans-(+)-Chrysanthemic acid, 99+%;(1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanec...;2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropane-1-carboxylic acid;2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicaci(1r-trans;(E,1R)-2,2-dimethyl-3(2-methylprop-1-enyl)-cyclopropane-1-carbonic acid
CBNumber
CB1270738
Molecular Formula
C10H16O2
Formula Weight
168.23
MOL File
4638-92-0.mol
More
Less

TRANS-(+)-CHRYSANTHEMIC ACID Property

Melting point:
17-21 °C
alpha 
D25 +14.16° (c = 1.554 in abs alc)
Boiling point:
255.81°C (rough estimate)
Density 
0.9934 (rough estimate)
refractive index 
n20/D 1.477
storage temp. 
0-6°C
pka
4.90±0.33(Predicted)
form 
Liquid
color 
Clear colorless to yellow
optical activity
[α]/D +14±1°, c = 2% in ethanol
BRN 
4904351
CAS DataBase Reference
4638-92-0
EPA Substance Registry System
Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, (1R,3R)- (4638-92-0)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26
WGK Germany 
3
RTECS 
GZ1280000
10-23
HS Code 
29162090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
18509
Product name
(+)-trans-Chrysanthemic acid
Purity
≥97.0% (GC)
Packaging
500MG
Price
$559
Updated
2024/03/01
TRC
Product number
C432765
Product name
(+)-trans-Chrysanthemic acid
Packaging
500mg
Price
$925
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0000493
Product name
(+)-TRANS-CHRYSANTHEMIC ACID
Purity
95.00%
Packaging
500MG
Price
$264.87
Updated
2021/12/16
AK Scientific
Product number
6364AB
Product name
Trans-(+)-chrysanthemicacid
Packaging
500mg
Price
$337
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
63742
Product name
(+)-trans-Chrysanthemic acid
Packaging
500mg
Price
$490
Updated
2021/12/16
More
Less

TRANS-(+)-CHRYSANTHEMIC ACID Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

(+)-trans-Chrysanthemic Acid is a reactant in the synthesis of (1R,3R)-[2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropyl]methyl (R)-2-acetoxy-3-methylbutanoate, the sex pheromone of Pseudococcus calceolariae, the citrophilous mealybug

Uses

(+)-trans-Chrysanthemic acid may be used in the preparation of (+)-trans-pyrethric acid, a building block for rethrin II.

Definition

ChEBI: (+)-trans-chrysanthemic acid is a trans-chrysanthemic acid in which both stereocentres have R configuration. It is functionally related to a (R,R)-chrysanthemal. It is a conjugate acid of a (R,R)-chrysanthemate. It is an enantiomer of a (-)-trans-chrysanthemic acid.

General Description

(+)-trans-Chrysanthemic acid is the acidic component of synthetic pyrethroid insecticides. It can be prepared from (+)-Δ3-carene.

More
Less

TRANS-(+)-CHRYSANTHEMIC ACID Suppliers

Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81

4638-92-0, TRANS-(+)-CHRYSANTHEMIC ACIDRelated Search:


  • (1R,3R)-TRANS-2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANE-1-CARBOXYLIC ACID
  • (+)-(1r,3r)-2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylicacid
  • (1r-trans)-chrysanthemicacid
  • 2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicaci(1r-trans
  • 2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicaci(1theta-tr
  • 2,2-dimethyl-3-(2-methylpropenyl)-,(1r,3r)-(+)-cyclopropanecarboxylicaci
  • (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid
  • trans-(+)-Chrysanthemic acid, 99+%
  • (1R,3R)-2,2-DIMETHYL-3-(2-METHYL-1-PROPEN-1-YL)CYCLOPROPANECARBOXYLIC ACID
  • (E,1R)-2,2-dimethyl-3(2-methylprop-1-enyl)-cyclopropane-1-carbonic acid
  • (1R)-2,2-Dimethyl-3α-(2-methyl-1-propenyl)cyclopropane-1β-carboxylic acid
  • (1R)-2β-(2-Methyl-1-propenyl)-3,3-dimethylcyclopropane-1α-carboxylic acid
  • [1R,3R,(+)]-2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylic acid
  • [1R,3R,(+)]-2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid
  • (+)-trans-Chrysanthemic acid
  • (1S,3S)-2,2-DiMethyl-3-(2-Methylprop-1-enyl)cyclopropanecarboxylic acid
  • ChrysantheMic Acid Chloride
  • d-trans-Form
  • 2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropane-1-carboxylic acid
  • Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, (1R,3R)-
  • rans-Chrysanthemicaci
  • (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanec...
  • 4638-92-0 (+)-trans-Chrysanthemic acid /High quality/Best price/In stock CAS NO.4638-92-0
  • (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropane-1-carboxylic acid
  • (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylic acid
  • 4638-92-0
  • Chiral Building Blocks
  • Carboxylic Acids
  • Asymmetric Synthesis
  • Organic Building Blocks