(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
Reaction- Product Name
- (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- CAS No.
- 56977-92-5
- Chemical Name
- (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- Synonyms
- Chiralyst Rh756;:(R,R)-(-)-1,2-Bis[(;RR-DiPAMP-Rh catalyst;(r,r)-(-)-1,2-bis((2-M;[Rh((R,R)-DiPAMP)COD]BF4;[RH(COD)(R,R-DIPAMP)] BF4;(S,S)-BF4;(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL);Chiralyst Rh756, 14% Rh, Product of UMicore;(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(...
- CBNumber
- CB1272499
- Molecular Formula
- C36H38BF4O2P2Rh
- Formula Weight
- 754.35
- MOL File
- 56977-92-5.mol
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Property
- form
- Powder
- color
- orange
- Sensitive
- air sensitive
- CAS DataBase Reference
- 56977-92-5
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H302Harmful if swallowed
H312Harmful in contact with skin
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H332Harmful if inhaled
H413May cause long lasting harmful effects to aquatic life
- Precautionary statements
-
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P321Specific treatment (see … on this label).
P322Specific measures (see …on this label).
P330Rinse mouth.
P363Wash contaminated clothing before reuse.
P390Absorb spillage to prevent material damage.
P404Store in a closed container.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 45-0225
- Product name
- (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
- Packaging
- 100mg
- Price
- $139
- Updated
- 2024/03/01
- Product number
- 45-0225
- Product name
- (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
- Packaging
- 500mg
- Price
- $554
- Updated
- 2024/03/01
- Product number
- E890335
- Product name
- (R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I)Tetrafluoroborate
- Packaging
- 10mg
- Price
- $105
- Updated
- 2021/12/16
- Product number
- AS586951
- Product name
- [Rh((R,R)-DiPAMP)COD]BF4
- Purity
- 98%
- Packaging
- 100mg
- Price
- $201
- Updated
- 2021/12/16
- Product number
- BD286833
- Product name
- [Rh((R,R)-DiPAMP)COD]BF4
- Purity
- 98%
- Packaging
- 100mg
- Price
- $205
- Updated
- 2021/12/16
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties,Usage,Production
Reaction
- Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.
- Efficient catalyst for the asymmetric reduction of enol acetates to esters.
- Catalyst used to prepare chiral 2-substituted succinic acid derivatives.
Chemical Properties
Orange crystalline powder
Uses
(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate is used as a catalyst in the synthesis of Sinefungin (S487100); a natural nucleoside analog of S-adenosylmethionine that inhibits Streptococcus pneumoniae biofilm growth. Its derivatives can be used as inhibitors and structure probes for human protein lysine methyltransferase SETD2.
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials
Raw materials
Preparation Products
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Suppliers
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View Lastest Price from (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE manufacturers
- Product
- (r,r)-(-)-1,2-bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium (i) tetrafluoroborate 56977-92-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- Min98%
- Supply Ability
- g/kg/ton
- Release date
- 2020-01-08