Reaction
ChemicalBook > CAS DataBase List > (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

Reaction
Product Name
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
CAS No.
56977-92-5
Chemical Name
(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms
Chiralyst Rh756;：(R,R)-(-)-1,2-Bis[(;RR-DiPAMP-Rh catalyst;(r,r)-(-)-1,2-bis((2-M;[Rh((R,R)-DiPAMP)COD]BF4;[RH(COD)(R,R-DIPAMP)] BF4;(S,S)-BF4;(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL);Chiralyst Rh756, 14% Rh, Product of UMicore;(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(...
CBNumber
CB1272499
Molecular Formula
C36H38BF4O2P2Rh
Formula Weight
754.35
MOL File
56977-92-5.mol
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Property

form 
Powder
color 
orange
Sensitive 
air sensitive
CAS DataBase Reference
56977-92-5
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Safety

Risk Statements 
36/37/38
Safety Statements 
24/25-22
HS Code 
29319019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H332Harmful if inhaled

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P390Absorb spillage to prevent material damage.

P404Store in a closed container.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Strem Chemicals
Product number
45-0225
Product name
(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
Packaging
100mg
Price
$139
Updated
2024/03/01
Strem Chemicals
Product number
45-0225
Product name
(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
Packaging
500mg
Price
$554
Updated
2024/03/01
TRC
Product number
E890335
Product name
(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I)Tetrafluoroborate
Packaging
10mg
Price
$105
Updated
2021/12/16
Arctom
Product number
AS586951
Product name
[Rh((R,R)-DiPAMP)COD]BF4
Purity
98%
Packaging
100mg
Price
$201
Updated
2021/12/16
BLDpharm
Product number
BD286833
Product name
[Rh((R,R)-DiPAMP)COD]BF4
Purity
98%
Packaging
100mg
Price
$205
Updated
2021/12/16
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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties,Usage,Production

Reaction

  1. Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.
  2. Efficient catalyst for the asymmetric reduction of enol acetates to esters.
  3. Catalyst used to prepare chiral 2-substituted succinic acid derivatives.

Chemical Properties

Orange crystalline powder

Uses

(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate is used as a catalyst in the synthesis of Sinefungin (S487100); a natural nucleoside analog of S-adenosylmethionine that inhibits Streptococcus pneumoniae biofilm growth. Its derivatives can be used as inhibitors and structure probes for human protein lysine methyltransferase SETD2.

(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Suppliers

Belgium 2 China 55 China Hong Kong 1 Germany 1 India 1 United Kingdom 1 United States 6 Global 67
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
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View Lastest Price from (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE manufacturers

Career Henan Chemical Co
Product
(r,r)-(-)-1,2-bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium (i) tetrafluoroborate 56977-92-5
Price
US $1.00/KG
Min. Order
1KG
Purity
Min98%
Supply Ability
g/kg/ton
Release date
2020-01-08

56977-92-5, (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATERelated Search:

(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE Fluoroboric acid (R,R)-DIPAMP Rhodium (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 1,5-Cyclooctadiene 1,2-Bis(diphenylphosphino)ethane 1,2-BIS(PHENYLPHOSPHINO)ETHANE 1,2-BIS[(2-METHOXYPHENYL)PHENYLPHOSPHINO]ETHANE METHYLPHOSPHINE BORANE COMPLEX BORANE-DIPHENYLPHOSPHINE COMPLEX BIS(2-METHOXYPHENYL)PHENYLPHOSPHINE (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95% (S,S)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 2-METHOXYPHENYLPHOSPHINE

  • ：(R,R)-(-)-1,2-Bis[(
  • (R,R)-(-)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I) terafluoroborate
  • (r,r)-(-)-1,2-bis((2-Methoxyphenyl)phenylphosphino)ethane(1,5-cy
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)<br />rhodium (I)tetrafluoroborate, min. 95%
  • (R,R)-(-)-1,2-Bis[(o-Methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,95%
  • Chiralyst Rh756
  • (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rho
  • [Rh((R,R)-DiPAMP)COD]BF4
  • (1R,2R)-()-Bis[(2-methoxyphenyl)phenylphosphino]ethane -(1,5-cyclooctadiene)-rhodium(I) tetrafluorobarate
  • Chiralyst Rh756, 14% Rh, Product of UMicore
  • RR-DiPAMP-Rh catalyst
  • (S,S)-<Rh(1,5-COD)(DIPAMP)>BF4
  • [RH(COD)(R,R-DIPAMP)] BF4
  • (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
  • (R,R)-(-)-1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I) BF4
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluor
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)phenylphosphino]ethane(1,5-cyclooctadiene)rhodium(I)terafluoroborate
  • Bismethoxyphenylphenylphosphinoethanecyclooctadienerhodiumtetrafluorob
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)r
  • (R,R)-(-)-1,2-Bis((o-methoxyphenyl)-(phenyl)phosphino)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
  • (R,R)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%
  • (r,r)-(-)-1,2-bis((2-M
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.95%
  • (r,r)-(-)-1,2-bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium tetrafluoroborate
  • (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE ISO 9001：2015 REACH
  • (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(...
  • 56977-92-5
  • C36H40BF4O2P2Rh
  • C28H28O2P2C8H12RhBF4
  • BF4C36H40O2P2Rh
  • C36H40O2P2RhBF4
  • metal-phosphine complexes
  • Rh