2-Naphthaleneboronic acid

ChemicalBook > CAS DataBase List > 2-Naphthaleneboronic acid

2-Naphthaleneboronic acid

description Uses Solubility Application

Product Name: 2-Naphthaleneboronic acid
CAS No.: 32316-92-0
Chemical Name: 2-Naphthaleneboronic acid
Synonyms: NAPHTHALEN-1-YLBORONIC ACID;NAPHTHALEN-2-YLBORONIC ACID;2-NAPHTHYLBORONIC ACID;NAPHTHALENE-2-BORONIC ACID;NAPHTHALENE-1-BORONIC ACID;2-Naphthene;AKOS BRN-0041;AKOS BRN-0020;eneboronic Acid;RARECHEM AH PB 0126
CBNumber: CB1282654
Molecular Formula: C10H9BO2
Formula Weight: 171.99
MOL File: 32316-92-0.mol

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2-Naphthaleneboronic acid Property

Melting point:: 269-275 °C(lit.)
Boiling point:: 381.9±25.0 °C(Predicted)
Density: 1.21±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
Water Solubility: Slightly soluble in water
pka: 8.53±0.30(Predicted)
form: Crystalline Powder and/or Chunks
color: White to off-white
BRN: 2936449
InChIKey: KPTRDYONBVUWPD-UHFFFAOYSA-N
CAS DataBase Reference: 32316-92-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
TSCA: No
HazardClass: IRRITANT
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 480134
Product name: 2-Naphthylboronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $75.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 480134
Product name: 2-Naphthylboronic acid
Purity: ≥95.0%
Packaging: 25g
Price: $125
Updated: 2024/03/01

TCI Chemical

Product number: N0649
Product name: 2-Naphthaleneboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $20
Updated: 2024/03/01

TCI Chemical

Product number: N0649
Product name: 2-Naphthaleneboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $58
Updated: 2024/03/01

Alfa Aesar

Product number: B24157
Product name: 2-Naphthaleneboronic acid, 97%
Packaging: 1g
Price: $24.65
Updated: 2024/03/01

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2-Naphthaleneboronic acid Chemical Properties,Usage,Production

description

2-Naphthalene Boronic Acid is an organometallic iridium complex with applications in catalysis and Pharmaceutical manufacturing. It can be also used in the study of an enantioselective rhodium-catalyzed addition of aryl boronic acids to 2,2,2-trifluoroacetophenones leading to chiral, tertiary trifluoromethyl alcohols.

Uses

2-Naphthaleneboronic acid is a useful research chemical for organic synthesis and other chemical processes.

Solubility

Solubility in water: slightly soluble. Other solubilities: soluble in methanol

Application

It is used to study the enantioselective rhodium-catalyzed addition reaction of arylboronic acid and 2,2,2-trifluoroacetophenone to generate chiral tertiary trifluoromethanol.
It can also be used to study the palladium-catalyzed addition reaction of arylboronic acid and nitrile to generate aryl ketones, and aromatic adverbial clauses: palladium-catalyzed addition of oxynitrile to benzofuran.

Chemical Properties

yellow crystal powde

Uses

suzuki reaction

Uses

Used in a study of an enantioselective rhodium-catalyzed addition of aryl boronic acids to 2,2,2-trifluoroacetophenones leading to chiral, tertiary trifluoromethyl alcohols. Also employed in a study of a palladium-catalyzed addition of aryl boronic acids to nitriles providing aryl ketones and to aryloxy nitriles providing benzofurans.

Synthesis

To a two-neck 250mL round bottom flask, triisopropyl borate (3.30mL, 29.06mmol) and 3-bromoquinoline (3.00g, 14.49mmol) was dissolved in dry THF (100mL), then n-butyllithium (14.50mL of a 2M solution in hexane, 29.00mmol) was added dropwise via a dropping funnel over 1h under N2 at-78°C. After 2h, the acetone/dry ice bath was removed, and the reaction solution was allowed to warm to 0°C. The reaction was then quenched with a 2M HCl solution, and the pH value was adjusted to 7 with a solution of 2M NaHCO3. The resulting solution was extracted with ethyl acetate (EA) (3×100mL). The combined organic layers were dried with MgSO4 and evaporated to dryness. n-Hexane was then added to precipitated the product 2-Naphthaleneboronic acid as a white solid (80% yield).

2-Naphthaleneboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate Tetrahydrofuran 2-Naphthol n-Butyllithium 2-Bromonaphthalene

Preparation Products

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2-Naphthaleneboronic acid Suppliers

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View Lastest Price from 2-Naphthaleneboronic acid manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 2-Naphthaleneboronic acid 32316-92-0
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-11-18

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: 2-Naphthaleneboronic acid 32316-92-0
Price: US $999.00-666.00/ton
Min. Order: 1ton
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-09

Hebei Dangtong Import and export Co LTD

Product: 2-Naphthaleneboronic acid 32316-92-0
Price: US $510.00-460.00/kilograms
Min. Order: 100kilograms
Purity: 99%
Supply Ability: 100tons
Release date: 2023-02-24

32316-92-0, 2-Naphthaleneboronic acidRelated Search:

Boric acid Citric acid Fluoroboric acid Zinc borate ALPHA-NAPHTHYLBORIC ACID,1-NAPHTHALENEBORONIC ACID,1-Naphthaleneboronic Acid (contains varying amounts of Anhydride) Ascoric Acid 3-(4-FLUOROPHENYL)AMINOCARBONYLPHENYLBORONIC ACID 4-FLUORO-3-(PHENYLCARBAMOYL)BENZENEBORONIC ACID 4-BROMO-1-FLUORO-2-NAPHTHALENEBORONIC ACID 6-Benzyloxy-2-naphthaleneboronic acid 6-HYDROXY-2-NAPHTHALENEBORONIC ACID 2-Naphthaleneboronic acid, pinacol ester ,98%,2-NAPHTHALENEBORONIC ACID, PINACOL ESTER 3-(PHENYLAMINOCARBONYL)-5-NITROPHENYLBORONIC ACID 6-T-BUTYLDIMETHYSILYLOXY-2-NAPHTHALENEBORONIC ACID 3-(4-CYANOPHENYL)AMINOCARBONYLPHENYLBORONIC ACID 6-ETHOXY-2-NAPHTHALENEBORONIC ACID (S)-2,2'-Dimethoxy-1,1'-binaphthyl-3,3'-diyldiboronic acid 3-(4-FLUOROPHENYL)AMINOCARBONYLPHENYLBORONIC ACID PINACOL ESTER

AKOS BRN-0020

AKOS BRN-0041

ALPHA-NAPHTHYLBORIC ACID

1-NAPHTHYLENEBORONIC ACID

2-NAPHTHYLBORONIC ACID

2-NAPHTHENEBORONIC ACID

2-NAPHTHALENEYLBORONIC ACID

2-NAPHTHALENEBORONIC ACID

RARECHEM AH PB 0125

RARECHEM AH PB 0126

NAPHTHALEN-2-YLBORONIC ACID

NAPHTHALEN-1-YLBORONIC ACID

Naphthalene-2-boronic acid,2-Naphthylboronic acid

Boronic acid,B-2-naphthalenyl-

2-NAPHTHALENEBORONI

naphthalen-1-yl hydrogen boronate

2-Borononaphthalene

2-Naphthaleneboronic acid 2-Naphthylboronic acid

2-Naphthylboronic acid >=95.0%

Naphthalen-2-boronic acid

2-Naphthylboronic acid(contains varying amounts of Anhydride)

Boronic acid, 2-naphthalenyl-

NAPHTHALENYL-1-BORONIC ACID

NAPHTHALENYL-2-BORONIC ACID

NAPHTHALENE-2-BORONIC ACID

NAPHTHALENE-1-BORONIC ACID

2-Naphthalene Boric Acid

2-Naphthylboronic caid

2-NAPHTHYLBORONSAEURE

NAPHTHALENE-2-BORONIC ACID 98%

Naphthalene-2-BoronicAcid2-NaphthaleneboronicAcid/2-NaphtheneBoronicAcid

2-Naphthene

2-NAPHTHENE BORONIC ACID, NAPHTHALENE-2-BORONIC ACID, 2-NAPHTHYLBORONIC ACID

2-NAPHTHALENYLBORONICACID

2-Naphthaleneboronicacid,97%

(2-Naphthalyl)boronic acid

2-NAPHTHYLBORONIC ACID HPLC 98+%

2-Naphthaleneboronic Acid (contains varying amounts of Anhydride)

2-Naphthylboronic acid, May contain varying amounts of anhydride, 97%

2-Naphthaleneboronic

2-Naphthaleneboronic acid ,98%

2-Naphtahaleneboronic acid

eneboronic Acid

naphthalen-2-ylboronicaci

Boronic acid, B-2-naphthalenyI-

2-Naphthylboric acid

2-Naphthaleneboronic acid 99.5%

2-Naphthalboronic acid

B-2-Naphthalenylboronic acid

32316-92-0

32313-92-0

C10H9BO2

C10H7BOH2

BORONIC ACID

Organometallic Reagents

B (Classes of Boron Compounds)

Boronic Acids

Boronic Acids and Derivatives