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5-ETHYLIDENE-2-NORBORNENE

Product Name
5-ETHYLIDENE-2-NORBORNENE
CAS No.
16219-75-3
Chemical Name
5-ETHYLIDENE-2-NORBORNENE
Synonyms
enb;ETHYLIDENE NORBORNENE;5-ETHYLENE-2-NORBORENE;ETHYLIDENE-2-NORBORNENE;5-Ethylidene norbornene;5-ethylidene-2-norbornen;5-ETHYLIDENE-2-NORBORNENE;5-Ethylidenenorborn-2-ene;5-ethylidene-5-norbornene;Ethylidene Norbornene(ENB
CBNumber
CB1309456
Molecular Formula
C9H12
Formula Weight
120.19
MOL File
16219-75-3.mol
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5-ETHYLIDENE-2-NORBORNENE Property

Melting point:
-80.15°C
Boiling point:
146 °C(lit.)
Density 
0.893 g/mL at 25 °C(lit.)
vapor density 
4.1 (vs air)
vapor pressure 
4.6 mm Hg ( 20 °C)
refractive index 
n20/D 1.49(lit.)
Flash point:
101 °F
storage temp. 
Flammables area
solubility 
Chloroform (Slightly), Hexanes (Slightly)
form 
Liquid
color 
Colorless to Almost colorless
explosive limit
~6.4%
Water Solubility 
Soluble in water (0.01% at 20C).
Exposure limits
ACGIH: TWA 2 ppm; STEL 4 ppm
NIOSH: Ceiling 5 ppm(25 mg/m3)
Stability:
Volatile
LogP
3.82 at 20℃
CAS DataBase Reference
16219-75-3(CAS DataBase Reference)
EPA Substance Registry System
5-Ethylidene-2-norbornene (16219-75-3)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
10-22-36/37/38-65-51/53-48/20-43-38-20
Safety Statements 
16-26-36/37/39-62-61
OEL
Ceiling: 5 ppm (25 mg/m3)
RIDADR 
UN 2929 6.1/PG 2
WGK Germany 
2
RTECS 
RB9450000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29021990
Hazardous Substances Data
16219-75-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H332Harmful if inhaled

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
151467
Product name
5-Ethylidene-2-norbornene
Purity
contains 100-200 ppm BHT as inhibitor, mixture of endo and exo, 99%
Packaging
100ml
Price
$63.9
Updated
2024/03/01
Sigma-Aldrich
Product number
151467
Product name
5-Ethylidene-2-norbornene
Purity
contains 100-200 ppm BHT as inhibitor, mixture of endo and exo, 99%
Packaging
2l
Price
$349
Updated
2024/03/01
TCI Chemical
Product number
E0244
Product name
5-Ethylidene-2-norbornene
Purity
>98.0%(GC)
Packaging
25mL
Price
$22
Updated
2024/03/01
TCI Chemical
Product number
E0244
Product name
5-Ethylidene-2-norbornene
Purity
>98.0%(GC)
Packaging
500mL
Price
$66
Updated
2024/03/01
Alfa Aesar
Product number
043972
Product name
5-Ethylidene-2-norbornene, endo + exo, 98%, stab. with 100ppm 4-tert-butylcatechol
Packaging
25ml
Price
$23.4
Updated
2021/12/16
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5-ETHYLIDENE-2-NORBORNENE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Chemical Properties

5-Ethylidene- 2-norbornene is a colorless liquid with a turpentine-like odor. The Odor Threshold is 0.007 ppm.

Uses

Ethylidene norbornene is the third monomer in EPDM (ethylene–propylene diene monomer) elastomers.

Uses

As third monomer in EPDM (ethylene- propylene diene monomer)

Uses

5-Ethylidene-2-norbornene is used as a self healing agent for polymeric composites. It is also used to reinforce multiwalled carbon nanotubes.

Definition

A diene used as the third monomer in EPDM elastomers.

General Description

Colorless liquid with an odor of turpentine. Flash point 101°F. Floats on water.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

5-ETHYLIDENE-2-NORBORNENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.

Hazard

Toxic.

Health Hazard

Inhalation of vapors causes headache, confusion, and respiratory distress. Ingestion causes irritation of entire digestive system. Aspiration causes severe pneumonia. Contact with liquid causes irritation of eyes and skin.

Fire Hazard

5-ETHYLIDENE-2-NORBORNENE is flammable.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation and sh contact. Human systemic effects by inhalation: conjunctiva, olfactory, and taste changes. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

5-Ethylidene-2-norbornene is used as the third monomer in terpolymer elastomers. Those engaged in the synthesis of pharmaceuticals; pesticides, or in the preparation of specialty resins.

Shipping

UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.

Incompatibilities

May form explosive mixture with air. Reacts violently with strong oxidants. Violent reaction with oxygen and strong oxidizers. May accumulate static electrical charges, and may cause ignition of its vapors. The substance may polymerize. Inhibit peroxide formation with tert-butyl catechol. ENB should be stored in a nitrogen atmosphere since it reacts with oxygen

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

5-ETHYLIDENE-2-NORBORNENE Preparation Products And Raw materials

Raw materials

1,3-Butadiene Calcium oxide Dicyclopentadiene 3-Chloro-1-butene Norbornene 1,3-Cyclopentadiene

Preparation Products

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5-ETHYLIDENE-2-NORBORNENE Suppliers

Americas 1 Belgium 4 Canada 1 China 125 Europe 2 France 2 Germany 4 India 2 Japan 5 South Korea 1 Switzerland 3 United Kingdom 5 United States 21 USA 1 Global 177
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
K. Sakai & Co., Ltd.
Tel
--
Fax
--
Email
em@ksakai.co.jp
Country
Japan
ProdList
957
Advantage
58
NIPPON OIL CORPORATION
Tel
--
Fax
--
Country
Japan
ProdList
5
Advantage
82
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from 5-ETHYLIDENE-2-NORBORNENE manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
5-ethylidene-2-norbornene 16219-75-3
Price
US $8.60/KG
Min. Order
1KG
Purity
98%
Supply Ability
5000kg
Release date
2024-08-09
Henan Fengda Chemical Co., Ltd
Product
5-ETHYLIDENE-2-NORBORNENE 16219-75-3
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
5-ETHYLIDENE-2-NORBORNENE 16219-75-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

16219-75-3, 5-ETHYLIDENE-2-NORBORNENERelated Search:

Sodium p-styrenesulfonate Sodium decyl-sulfonate Sulfamic acid Adamantane Dicyclopentadiene 4-Allylanisole Norbornene Comphene Camphene 4-tert-Butylcatechol 5-ETHYLIDENE-2-NORBORNENE, POLYMER WITH ETHYLENE AND PROPENE) 5-METHYLENE-2-NORBORNENE 5-ETHYLIDENE-2-NORBORNENE

  • ETHYLIDENE NORBORNENE
  • ETHYLIDENE-2-NORBORNENE
  • (5E)-5-Ethylidenebicyclo[2.2.1]hept-2-ene
  • 2-Norbornene, 5-ethylidene-
  • 2-norbornene,5-ethylidene-
  • 5-Ethylidene bicyclo[2,2,1]heptene
  • 5-ethylidene-2-norbornen
  • bicyclo[2.2.1]hept-2-ene,5-ethylidene-
  • enb
  • mixcis+trans-5-ethylidenebicyclo[2.2.1]hept-2-ene
  • 5-ETHYLIDENE-2-NORBORNENE
  • 5-Ethylidene-2-norbornene contains 100-200 ppM BHT as inhibitor, Mixture of endo and exo, 99%
  • 5-Ethylidene-2-norbornene, endo + exo, Stabilized with 100ppm 4-tert-butylcatechol
  • 5-Ethylidene-2-norbornene, 98%, mixture of endo and exo
  • 5-ethylidene-2-norbornene,mixt.ofendo-andexo-isomers
  • 5-ethylidenebicyclo(2,2,1)hep-2-ene
  • 5-ethylidene-bicyclo(2.2.1)hept-2-en
  • 5-ethylidenebicyclo(2.2.1)hept-2-ene
  • 5-Ethylidenebicyclo[2,2,1]hept-2-nen
  • 5-Ethylidenebicyclo[2.2.1]-2-heptene
  • 5-ethylidene-bicyclo[2.2.1]hept-2-en
  • 5-ethylidene-Bicyclo[2.2.1]hept-2-ene
  • 5-Ethylidenebicyclo[2.2.1]hept-2-ene
  • 5-ethylidene-8,9,10-trinorborn-2-ene
  • 5-ETHYLIDENE-2-NORBORNENE, 99%, MIXTURE OF ENDO AND EXO
  • 5-ETHYLIDENE-2-NORBORNENE, MIXTURE OF ENDO- AND EXO-ISOMERS STABILIZED 98+%
  • 5-Ethylidene-2-norbornene,stabilized
  • 5-Ethylidene norbornene
  • 5-Ethylidene-2-norbornene, mixt. of endo- and exo-isomers, stabilized, 98+%
  • 5-ethylidene-2-norbornene, endo + exo
  • 5-ethylidene-2-norbornene, mixture of endo and exo
  • 5-ETHYLENE-2-NORBORENE
  • 5-Ethyliden-8,9,10-trinorborn-2-en
  • 5-ETHYLIDENE-2-NORBORNENE (ENDO AND EXO)
  • 5-Ethylidene-2-norbornene, endo + exo, 98%, stab. with 100ppm p-tert-butylcatechol
  • 5-Ethylidenebicyclo[2,2,1]-hent-2-ene
  • 5-Ethylidene-2-norbornene, mixt. of endo- and exo-isomers, stabilized
  • (5E)-5-Ethylidenenorbornan-2-ene
  • 2-Ethylidenenorborna-5-ene
  • 5-Ethylidenenorborn-2-ene
  • 5-Ethylidene-2-norbornene, endo + exo, 98%, stab. with 100ppm 4-tert-butylcatechol
  • 5-ethylidene-5-norbornene
  • 5-Ethylidene-2-norbornene,98+%,mixt. of endo-and exo-isomers, stabilized
  • Ethylidene Norbornene(ENB
  • (E)-5-ethylidenebicyclo[2.2.1]hept-2-ene
  • 5-Ethylidene-2-norbornene, Mixt. of endo- and exo-isoMers, stabilized, 98+% 500GR
  • 5-Ethylidene-2-norbornene&gt
  • 5-Ethylidene-2-norbornene (Mixture of endo and ex)
  • ETHYLIDENE NORBORNENE(ENB0
  • 5-ETHYLIDENE-2-NORBORNENE ISO 9001：2015 REACH
  • Ethylidene Norborene (ENB)
  • 16219-75-3
  • Organic Building Blocks
  • Building Blocks
  • Alkenes
  • Acyclic
  • Acyclic
  • Alkenes