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Norbornene

Product Name
Norbornene
CAS No.
498-66-8
Chemical Name
Norbornene
Synonyms
NSC;BICYCLO[2.2.1]HEPT-2-ENE;2-NORBORNENE;NORBORNYLENE;Norborn-2-ene;NORBORNENE HP;2-Norbornylene;453563775-60-8;BICYCLO[2.2.1]-2-HEPTENE;2,8-Dihydroxy-6-Mercaptopurine-13C3 SodiuM Dihydrate
CBNumber
CB9170038
Molecular Formula
C7H10
Formula Weight
94.15
MOL File
498-66-8.mol
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Norbornene Property

Melting point:
44-46 °C (lit.)
Boiling point:
96 °C (lit.)
Density 
0.955
vapor pressure 
30.06kPa at 59℃
refractive index 
1.4770 (estimate)
Flash point:
5 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Soluble), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Crystalline Mass
Specific Gravity
0.85
color 
White
Water Solubility 
Soluble in ethanol, ether and most organic solvents. Insoluble in water.
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
1098544
Exposure limits
ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
LogP
4.101 at 25℃
CAS DataBase Reference
498-66-8(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[2.2.1]hept-2-ene (498-66-8)
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Safety

Hazard Codes 
F,N,Xi
Risk Statements 
11-51/53-36
Safety Statements 
9-16-29-33-61-26
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
1
RTECS 
RB7900000
13
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
II
HS Code 
29021990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H319Causes serious eye irritation

H361Suspected of damaging fertility or the unborn child

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
N32407
Product name
Bicyclo[2.2.1]hept-2-ene
Purity
99%
Packaging
100g
Price
$43.1
Updated
2024/03/01
Sigma-Aldrich
Product number
N32407
Product name
Bicyclo[2.2.1]hept-2-ene
Purity
99%
Packaging
500g
Price
$127
Updated
2024/03/01
TCI Chemical
Product number
N0166
Product name
2-Norbornene
Purity
>99.0%(GC)
Packaging
25g
Price
$21
Updated
2024/03/01
TCI Chemical
Product number
N0166
Product name
2-Norbornene
Purity
>99.0%(GC)
Packaging
400g
Price
$77
Updated
2024/03/01
Alfa Aesar
Product number
L11103
Product name
Norbornene, 99%
Packaging
100g
Price
$38.8
Updated
2024/03/01
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Norbornene Chemical Properties,Usage,Production

Chemical Properties

white crystalline mass

Uses

Norbornene is used as a monomer and as an intermediate in organic synthesis. It is also used to prepare pharmaceutical intermediates and specialty fragrances. It reacts with ethylene to get cyclic olefin copolymer. Further, it is used in transition metal catalysis to affect migration of electrophilic transition metals. It acts as a monomer in ring-opening metathesis polymerizations with the Grubbs' catalyst. Its polymer, polynorbornene is used in the rubber industry for anti-vibration, anti-impact in personal protective equipment and grip improvement in toy tires, racing tires and transmission system.

Definition

ChEBI: Norbornene is a bridged compound that is cyclohexane with a methylene bridge between carbons 1 and 4 and a double bond at position 2. It is a bridged compound, a carbobicyclic compound and a cyclic olefin.

General Description

The vinylic polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) with Co(II) compounds and the metallocene [η5-(C5Me5)Co-η2-Cl]2, in chlorobenzene activated with methylaluminoxane (MAO) has been reported. Co(II) catalyzed polymerization of bicyclo[2.2.1]hept-2-ene in the presence of ethene has been reported.

Flammability and Explosibility

Non flammable

Purification Methods

Reflux it over Na, and distil it [Gilliom & Grubbs J Am Chem Soc 108 733 1986]. It has also been purified by sublimation in vacuo onto an ice-cold finger. [Woon et al. J Am Chem Soc 108 7990 1986, Beilstein 5 IV 394.]

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Norbornene Suppliers

Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
391
Advantage
55
skychemical Co.Ltd
Tel
021-20960837,QQ1332204249
Fax
021-20960837
Email
sales@skychemical.com
Country
China
ProdList
3317
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
xinxiang runyu material co.,Ltd
Tel
15690792173 15690792173
Fax
0373-7759608
Email
sales@runvmat.com
Country
China
ProdList
389
Advantage
58
Henan Evonik Biotechnology Co. LTD
Tel
16650615803
Email
hnyingchuang@163.com
Country
China
ProdList
3970
Advantage
58
Shanghai Kuanglin Tech LTD Co
Tel
13701867986
Email
13701867986@163.com
Country
China
ProdList
88
Advantage
58
Hubei Changxinsheng Pharm Co.,Ltd
Tel
18971203904; 18971238634
Email
2189484023@qq.com
Country
China
ProdList
495
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
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View Lastest Price from Norbornene manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
NORBORNENE 498-66-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99.7%
Supply Ability
200000kg
Release date
2024-04-23
Hebei Guanlang Biotechnology Co., Ltd.
Product
Norbornene 498-66-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-01-10
Hebei Mojin Biotechnology Co., Ltd
Product
Norbornene 498-66-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-26

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