5-Norbornene-2-carbonitrile
- Product Name
- 5-Norbornene-2-carbonitrile
- CAS No.
- 95-11-4
- Chemical Name
- 5-Norbornene-2-carbonitrile
- Synonyms
- 2-Cyano-5-nor;TIMTEC-BB SBB007934;2-Cyano-5-norbornene;5-Cyano-2-norbornene;2-Cyanonorborn-5-ene;5-Diopatene-2-nitrile;5-Norbornene-2-carbonitriL;5-NORBORNENE-2-CARBONITRILE;Norborn-5-ene-2-carbonitrile;5-Norbornene-2-methanonitrile
- CBNumber
- CB0153050
- Molecular Formula
- C8H9N
- Formula Weight
- 119.16
- MOL File
- 95-11-4.mol
5-Norbornene-2-carbonitrile Property
- Melting point:
- 12-14 °C(lit.)
- Boiling point:
- 82-86 °C10 mm Hg(lit.)
- Density
- 0.999 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.488(lit.)
- Flash point:
- 150 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- clear liquid
- color
- Light yellow to Amber to Dark green
- InChI
- InChI=1S/C8H9N/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-8H,3-4H2
- InChIKey
- BMAXQTDMWYDIJX-UHFFFAOYSA-N
- SMILES
- C12CC(C=C1)CC2C#N
- CAS DataBase Reference
- 95-11-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Bicyclo[2.2.1]hept-5-ene-2-carbonitrile(95-11-4)
- EPA Substance Registry System
- Bicyclo[2.2.1]hept-5-ene-2-carbonitrile (95-11-4)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39-36/37
- WGK Germany
- 3
- RTECS
- RB7930000
- HS Code
- 29269090
- Toxicity
- LD50 ivn-mus: 10 mg/kg CSLNX* NX#00780
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- PH001332
- Product name
- BICYCLO[2.2.1]HEPT-5-ENE-2-CARBONITRILE
- Purity
- AldrichCPR
- Packaging
- 25MG
- Price
- $398
- Updated
- 2023/06/20
- Product number
- 150576
- Product name
- 5-Norbornene-2-carbonitrile, mixture of isomers
- Purity
- 98%
- Packaging
- 10g
- Price
- $89.2
- Updated
- 2023/01/07
- Product number
- N0897
- Product name
- 5-Norbornene-2-carbonitrile (mixture of isomers)
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $66
- Updated
- 2025/07/31
- Product number
- N0897
- Product name
- 5-Norbornene-2-carbonitrile (mixture of isomers)
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $195
- Updated
- 2025/07/31
- Product number
- B626420
- Product name
- Bicyclo[2.2.1]hept-2-ene-5-carbonitrile
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
5-Norbornene-2-carbonitrile Chemical Properties,Usage,Production
Chemical Properties
clear colourless liquid
Uses
Bicyclo[2.2.1]hept-2-ene-5-carbonitrile is used in method for continuously preparing cyanonorbornene by using microchannel reactor.
General Description
The hydrogenation of 5-norbornene-2-carbonitrile was studied using real-time mass spectrometric analysis.
Safety Profile
A poison by intravenous route.When heated to decomposition it emits toxic vapors ofNOx.
Synthesis
67403-76-3
121-46-0
2436-90-0
95-11-4
The general procedure for the synthesis of 3,7-dimethylocta-1,6-diene and bicyclo[2.2.1]hept-5-ene-2-carbonitrile from the compound (CAS:67403-76-3) and dicycloheptadiene was as follows: to a 4 mL screw-capped vial in an argon-protected glove box were added sequentially the compound 69 (82.6 mg, 0.50 mmol), norepiglottidiene 8 (51 μL, 0.5 mmol), hexane solution of 1.0 M AIMe2Cl (50 μL, 10.0 mol%, 0.05 mmol), Ni(COD)2 (3.45 mg, 2.5 mol%, 12.5 μmol), and DPEphos (6.75 mg, 2.5 mol%, 12.5 μmol) in THF ( 1.0 mL) solution. The vials were removed from the glove box and the reaction temperature was controlled at 28°C. The reaction mixture was stirred at 28 °C for 16 h and then concentrated under reduced pressure. The residue was purified by silica gel fast column chromatography (100% pentane as eluent) to afford product 70 (49.0 mg, 71% yield). The structure of the product was confirmed by 1H NMR (500 MHz, CDCl3) and 13C NMR (125 MHz, CDCl3) as follows: 1H NMR δ 5.74-5.64 (m, 1H), 5.13-5.06 (m, 1H), 4.99-4.88 (m, 2H), 2.12 (p, J=7.0 Hz, 1H ), 2.01-1.89 (m, 2H), 1.68 (s, 3H), 1.60 (s, 3H), 1.35-1.26 (m, 2H), 0.99 (d, J=6.9Hz, 3H); 13C NMR δ 144.91, 131.44, 124.80, 112.61, 37.51, 36.89, 25.88, 20.30, 17.83.
References
[1] Patent: WO2017/93149, 2017, A1. Location in patent: Page/Page column 28
5-Norbornene-2-carbonitrile Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 5-Norbornene-2-carbonitrile manufacturers
- Product
- 5-Norbornene-2-carbonitrile 95-11-4
- Price
- US $2.00-6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-07-29
- Product
- 5-Norbornene-2-carbonitrile 95-11-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2025-03-14
- Product
- 5-Norbornene-2-carbonitrile 95-11-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000KG
- Release date
- 2024-08-14