ChemicalBook > CAS DataBase List > 5-Norbornene-2-carbonitrile

5-Norbornene-2-carbonitrile

Product Name
5-Norbornene-2-carbonitrile
CAS No.
95-11-4
Chemical Name
5-Norbornene-2-carbonitrile
Synonyms
2-Cyano-5-nor;TIMTEC-BB SBB007934;2-Cyano-5-norbornene;5-Cyano-2-norbornene;2-Cyanonorborn-5-ene;5-Diopatene-2-nitrile;5-Norbornene-2-carbonitriL;5-NORBORNENE-2-CARBONITRILE;Norborn-5-ene-2-carbonitrile;5-Norbornene-2-methanonitrile
CBNumber
CB0153050
Molecular Formula
C8H9N
Formula Weight
119.16
MOL File
95-11-4.mol
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5-Norbornene-2-carbonitrile Property

Melting point:
12-14 °C(lit.)
Boiling point:
82-86 °C10 mm Hg(lit.)
Density 
0.999 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.488(lit.)
Flash point:
150 °F
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Light yellow to Amber to Dark green
InChI
InChI=1S/C8H9N/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-8H,3-4H2
InChIKey
BMAXQTDMWYDIJX-UHFFFAOYSA-N
SMILES
C12CC(C=C1)CC2C#N
CAS DataBase Reference
95-11-4(CAS DataBase Reference)
NIST Chemistry Reference
Bicyclo[2.2.1]hept-5-ene-2-carbonitrile(95-11-4)
EPA Substance Registry System
Bicyclo[2.2.1]hept-5-ene-2-carbonitrile (95-11-4)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
RTECS 
RB7930000
HS Code 
29269090
Toxicity
LD50 ivn-mus: 10 mg/kg CSLNX* NX#00780
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
PH001332
Product name
BICYCLO[2.2.1]HEPT-5-ENE-2-CARBONITRILE
Purity
AldrichCPR
Packaging
25MG
Price
$398
Updated
2023/06/20
Sigma-Aldrich
Product number
150576
Product name
5-Norbornene-2-carbonitrile, mixture of isomers
Purity
98%
Packaging
10g
Price
$89.2
Updated
2023/01/07
TCI Chemical
Product number
N0897
Product name
5-Norbornene-2-carbonitrile (mixture of isomers)
Purity
>98.0%(GC)
Packaging
5g
Price
$66
Updated
2025/07/31
TCI Chemical
Product number
N0897
Product name
5-Norbornene-2-carbonitrile (mixture of isomers)
Purity
>98.0%(GC)
Packaging
25g
Price
$195
Updated
2025/07/31
TRC
Product number
B626420
Product name
Bicyclo[2.2.1]hept-2-ene-5-carbonitrile
Packaging
500mg
Price
$75
Updated
2021/12/16
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5-Norbornene-2-carbonitrile Chemical Properties,Usage,Production

Chemical Properties

clear colourless liquid

Uses

Bicyclo[2.2.1]hept-2-ene-5-carbonitrile is used in method for continuously preparing cyanonorbornene by using microchannel reactor.

General Description

The hydrogenation of 5-norbornene-2-carbonitrile was studied using real-time mass spectrometric analysis.

Safety Profile

A poison by intravenous route.When heated to decomposition it emits toxic vapors ofNOx.

Synthesis

67403-76-3

121-46-0

2436-90-0

95-11-4

The general procedure for the synthesis of 3,7-dimethylocta-1,6-diene and bicyclo[2.2.1]hept-5-ene-2-carbonitrile from the compound (CAS:67403-76-3) and dicycloheptadiene was as follows: to a 4 mL screw-capped vial in an argon-protected glove box were added sequentially the compound 69 (82.6 mg, 0.50 mmol), norepiglottidiene 8 (51 μL, 0.5 mmol), hexane solution of 1.0 M AIMe2Cl (50 μL, 10.0 mol%, 0.05 mmol), Ni(COD)2 (3.45 mg, 2.5 mol%, 12.5 μmol), and DPEphos (6.75 mg, 2.5 mol%, 12.5 μmol) in THF ( 1.0 mL) solution. The vials were removed from the glove box and the reaction temperature was controlled at 28°C. The reaction mixture was stirred at 28 °C for 16 h and then concentrated under reduced pressure. The residue was purified by silica gel fast column chromatography (100% pentane as eluent) to afford product 70 (49.0 mg, 71% yield). The structure of the product was confirmed by 1H NMR (500 MHz, CDCl3) and 13C NMR (125 MHz, CDCl3) as follows: 1H NMR δ 5.74-5.64 (m, 1H), 5.13-5.06 (m, 1H), 4.99-4.88 (m, 2H), 2.12 (p, J=7.0 Hz, 1H ), 2.01-1.89 (m, 2H), 1.68 (s, 3H), 1.60 (s, 3H), 1.35-1.26 (m, 2H), 0.99 (d, J=6.9Hz, 3H); 13C NMR δ 144.91, 131.44, 124.80, 112.61, 37.51, 36.89, 25.88, 20.30, 17.83.

References

[1] Patent: WO2017/93149, 2017, A1. Location in patent: Page/Page column 28

5-Norbornene-2-carbonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 5-Norbornene-2-carbonitrile manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
5-Norbornene-2-carbonitrile 95-11-4
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-07-29
Hebei Chuanghai Biotechnology Co., Ltd
Product
5-Norbornene-2-carbonitrile 95-11-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2025-03-14
Shaanxi Dideu Medichem Co. Ltd
Product
5-Norbornene-2-carbonitrile 95-11-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-08-14

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