MOLYBDENUM(V) CHLORIDE

ChemicalBook > CAS DataBase List > MOLYBDENUM(V) CHLORIDE

MOLYBDENUM(V) CHLORIDE

Physical Properties Preparation

Product Name: MOLYBDENUM(V) CHLORIDE
CAS No.: 10241-05-1
Chemical Name: MOLYBDENUM(V) CHLORIDE
Synonyms: MoCl5;MOLYBDENUM PENTACHLORIDE;ybdenum(V) chL;MOLYBDENUM CHLORIDE;MOLYBDENUMCHLORIDE(V);pentachloromolybdenum;MOLYBDENUM(+5)CHLORIDE;MOLYBDENUM(V) CHLORIDE;molybdenumchloride(mocl5);Molybdenum(V)pentachloride
CBNumber: CB1320424
Molecular Formula: Cl5Mo
Formula Weight: 273.2
MOL File: 10241-05-1.mol

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MOLYBDENUM(V) CHLORIDE Property

Melting point:: 194 °C (lit.)
Boiling point:: 268 °C (lit.)
Density: 2.928 g/mL at 25 °C (lit.)
vapor pressure: 1.75 mm Hg ( 25 °C)
solubility: Soluble in dry ether, dry alcohol, organic solvents and chlorinated solvents.
form: powder
color: White to gray
Specific Gravity: 2.928
Water Solubility: soluble in dry ether and dry alcohol, in other organic solvents [HAW93]
Sensitive: Moisture Sensitive
Stability:: Stable, but moisture and air-sensitive. Contact with water liberates toxic gas. Incompatible with water, strong oxidizing agents.
CAS DataBase Reference: 10241-05-1(CAS DataBase Reference)
EPA Substance Registry System: Molybdenum chloride (MoCl5) (10241-05-1)

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Safety

Hazard Codes: C
Risk Statements: 29-34-48/20/22-40
Safety Statements: 26-36/37/39-43-45
RIDADR: UN 2508 8/PG 3
WGK Germany: 3
RTECS: QA4690000
F: 1-3-10
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 28273985

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 208353
Product name: Molybdenum(V) chloride
Purity: 95%
Packaging: 25g
Price: $94.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 208353
Product name: Molybdenum(V) chloride
Purity: 95%
Packaging: 100g
Price: $232
Updated: 2024/03/01

Alfa Aesar

Product number: 011832
Product name: Molybdenum(V) chloride, 99.6% (metals basis)
Packaging: 5g
Price: $42.6
Updated: 2023/06/20

Alfa Aesar

Product number: 011832
Product name: Molybdenum(V) chloride, 99.6% (metals basis)
Packaging: 1kg
Price: $2066
Updated: 2023/06/20

Strem Chemicals

Product number: 42-1390
Product name: Molybdenum(V) chloride, anhydrous, 99.6%
Packaging: 50g
Price: $211
Updated: 2024/03/01

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MOLYBDENUM(V) CHLORIDE Chemical Properties,Usage,Production

Physical Properties

Greenish-black monoclinic crystals or dark red as liquid or vapor; paramagnetic; hygroscopic; critical temperature 577°C; critical volume 369 cm3/mol; soluble in dry ether, dry alcohol and many other organic solvents; reacts with water.

Preparation

Molybdenum pentachloride may be prepared by heating molybdenite in chlorine. Sulfur chloride formed in the reaction is removed by distillation:
2MoS2 + 7Cl2 → 2MoCl5 + 2S2Cl2
Also, the compound may be prepared by the action of chlorine on molybdenum metal at elevated temperatures (500°C):
2Mo + 5Cl2 → 2MoCl5
The pentachloride may be obtained from the tetrachloride, MoCl4. The latter, when heated in a sealed tube sublimes, and upon cooling, disproportionates to MoCl5 and the trichloride, MoCl3:
2MoCl4 → MoCl5 + MoCl3

Chemical Properties

Green-black solid, dark red as liquid orvapor.Hygroscopic,reacting with water and air. Soluble in dry ether,dry alcohol, and other organic solvents.

Uses

Chlorination catalyst, vapor-deposited molyb-denum coatings, component of fire-retardant resins,brazing and soldering flux, intermediate fororganometallic compounds, e.g., molybdenum hex-acarbonyl.

Uses

Molybdenum pentachloride (MoCl5) is used as a brazing and soldering flux and to make fire-retardant resins.

Uses

Molybdenum pentachloride MoCl5 is used as a catalyst for several polymerization reactions involving olefins, vinyl monomers, trioxane, ethylene, vinylcyclohexane, cyclopentene, and butadiene.

Definition

ChEBI: Molybdenum pentachloride is a molybdenum halide.

Air & Water Reactions

MOLYBDENUM(V) CHLORIDE may react with water to produce corrosive hydrochloric acid and toxic fumes.

Reactivity Profile

MOLYBDENUM(V) CHLORIDE is a corrosive, hygroscopic solid, on contact with water or steam MOLYBDENUM(V) CHLORIDE decomposes to form hydrochloric acid. When heated to decomposition MOLYBDENUM(V) CHLORIDE emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].

Hazard

Irritant.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A poison. A corrosive irritant to skin, eyes, and mucous membranes. Reacts with moisture to form hydrochloric acid. When heated to decomposition it emits toxic fumes of Mo and Cl-.

MOLYBDENUM(V) CHLORIDE Preparation Products And Raw materials

Raw materials

Metal mo

Preparation Products

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View Lastest Price from MOLYBDENUM(V) CHLORIDE manufacturers

R&D Scientific Inc.

Product: Molybdenum(V) Chloride 10241-05-1
Price: US $990.00/Kg
Min. Order: 0.100Kg
Purity: 97
Supply Ability: 500 Kg
Release date: 2024-11-12

Zhuozhou Wenxi import and Export Co., Ltd

Product: MOLYBDENUM(V) CHLORIDE 10241-05-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: MOLYBDENUM(V) CHLORIDE 10241-05-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 85.0-99.8%
Supply Ability: 200kg
Release date: 2019-08-30

10241-05-1, MOLYBDENUM(V) CHLORIDERelated Search:

Phosphorus pentoxide Cerium Nitrate Magnesium chloride Molybdenum carbide Barium sulfate Potassium chromate Tungsten hexacarbonyl Vanadium(V) oxide Manganese chloride Nickel chloride Lead(II) chloride Nickel(II) chloride hexahydrate Lanthanum(III) chloride Sodium chloride Rubidium chloride Aluminum chloride Neodymium(III) chloride hexahydrate Manganese chloride tetrahydrate

MOLYBDENUM(V) CHLORIDE

MOLYBDENUM CHLORIDE

MOLYBDENUM PENTACHLORIDE

MOLYBDENUM(+5)CHLORIDE

MoCl5

Molybdenum chloride (MoCl5)

molybdenumchloride(mocl5)

Molybdenum(V)chloride,anhydrous,99.6%

MOLYBDENUM(V) CHLORIDE, ANHYDROUS, POWD&

MOLYBDENUM(V) CHLORIDE, 99.9+%

Molybdenum(V)chloride,99.6%(metalsbasis)

Molybdenum(V)pentachloride

Molybdenum(V) chloride, anhydrous

MOLYBDENUMCHLORIDE(V)

MOLYBDENUM(V) CHLORIDE, 99.99%

Molybdenum(V) chloride,95%

Molybdenum(V) chloride (metals basis)

Molybdenum(V) chloride/ 99+%

MOLYBDENUM CHLORIDE (V), 99.9%

MolybdenuM(V) chloride, 95% 100GR

MolybdenuM(V) chloride, 95% 10GR

MolybdenuM(V) chloride 95%

MolybdenuM(V) chloride anhydrous, powder, 99.99% trace Metals basis (excluding W)

Molybdenum(V) chloride, 99.5% trace metals basis

ybdenum(V) chL

pentachloromolybdenum

10241-05-1

0241-05-1

Cl5Mo

Molybdenum

Catalysis and Inorganic Chemistry

metal halide

Catalysis and Inorganic Chemistry

Chemical Synthesis

Molybdenum Salts

MolybdenumMetal and Ceramic Science

Salts

Crystal Grade Inorganics

Metal and Ceramic Science