MOLYBDENUM(V) CHLORIDE
Physical Properties Preparation- Product Name
- MOLYBDENUM(V) CHLORIDE
- CAS No.
- 10241-05-1
- Chemical Name
- MOLYBDENUM(V) CHLORIDE
- Synonyms
- MoCl5;MOLYBDENUM PENTACHLORIDE;ybdenum(V) chL;MOLYBDENUM CHLORIDE;MOLYBDENUMCHLORIDE(V);pentachloromolybdenum;MOLYBDENUM(+5)CHLORIDE;MOLYBDENUM(V) CHLORIDE;molybdenumchloride(mocl5);Molybdenum(V)pentachloride
- CBNumber
- CB1320424
- Molecular Formula
- Cl5Mo
- Formula Weight
- 273.2
- MOL File
- 10241-05-1.mol
MOLYBDENUM(V) CHLORIDE Property
- Melting point:
- 194 °C (lit.)
- Boiling point:
- 268 °C (lit.)
- Density
- 2.928 g/mL at 25 °C (lit.)
- vapor pressure
- 1.75 mm Hg ( 25 °C)
- solubility
- Soluble in dry ether, dry alcohol, organic solvents and chlorinated solvents.
- form
- powder
- color
- White to gray
- Specific Gravity
- 2.928
- Water Solubility
- soluble in dry ether and dry alcohol, in other organic solvents [HAW93]
- Sensitive
- Moisture Sensitive
- Stability:
- Stable, but moisture and air-sensitive. Contact with water liberates toxic gas. Incompatible with water, strong oxidizing agents.
- CAS DataBase Reference
- 10241-05-1(CAS DataBase Reference)
- EPA Substance Registry System
- Molybdenum chloride (MoCl5) (10241-05-1)
Safety
- Hazard Codes
- C
- Risk Statements
- 29-34-48/20/22-40
- Safety Statements
- 26-36/37/39-43-45
- RIDADR
- UN 2508 8/PG 3
- WGK Germany
- 3
- RTECS
- QA4690000
- F
- 1-3-10
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28273985
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H351Suspected of causing cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
N-Bromosuccinimide Price
- Product number
- 208353
- Product name
- Molybdenum(V) chloride
- Purity
- 95%
- Packaging
- 25g
- Price
- $94.7
- Updated
- 2024/03/01
- Product number
- 208353
- Product name
- Molybdenum(V) chloride
- Purity
- 95%
- Packaging
- 100g
- Price
- $232
- Updated
- 2024/03/01
- Product number
- 011832
- Product name
- Molybdenum(V) chloride, 99.6% (metals basis)
- Packaging
- 5g
- Price
- $42.6
- Updated
- 2023/06/20
- Product number
- 011832
- Product name
- Molybdenum(V) chloride, 99.6% (metals basis)
- Packaging
- 1kg
- Price
- $2066
- Updated
- 2023/06/20
- Product number
- 42-1390
- Product name
- Molybdenum(V) chloride, anhydrous, 99.6%
- Packaging
- 50g
- Price
- $211
- Updated
- 2024/03/01
MOLYBDENUM(V) CHLORIDE Chemical Properties,Usage,Production
Physical Properties
Greenish-black monoclinic crystals or dark red as liquid or vapor; paramagnetic; hygroscopic; critical temperature 577°C; critical volume 369 cm3/mol; soluble in dry ether, dry alcohol and many other organic solvents; reacts with water.
Preparation
Molybdenum pentachloride may be prepared by heating molybdenite in chlorine. Sulfur chloride formed in the reaction is removed by distillation:
2MoS2 + 7Cl2 → 2MoCl5 + 2S2Cl2
Also, the compound may be prepared by the action of chlorine on molybdenum metal at elevated temperatures (500°C):
2Mo + 5Cl2 → 2MoCl5
The pentachloride may be obtained from the tetrachloride, MoCl4. The latter, when heated in a sealed tube sublimes, and upon cooling, disproportionates to MoCl5 and the trichloride, MoCl3:
2MoCl4 → MoCl5 + MoCl3
Chemical Properties
Green-black solid, dark red as liquid orvapor.Hygroscopic,reacting with water and air. Soluble in dry ether,dry alcohol, and other organic solvents.
Uses
Chlorination catalyst, vapor-deposited molyb-denum coatings, component of fire-retardant resins,brazing and soldering flux, intermediate fororganometallic compounds, e.g., molybdenum hex-acarbonyl.
Uses
Molybdenum pentachloride (MoCl5) is used as a brazing and soldering flux and to make fire-retardant resins.
Uses
Molybdenum pentachloride MoCl5 is used as a catalyst for several polymerization reactions involving olefins, vinyl monomers, trioxane, ethylene, vinylcyclohexane, cyclopentene, and butadiene.
Definition
ChEBI: Molybdenum pentachloride is a molybdenum halide.
Air & Water Reactions
MOLYBDENUM(V) CHLORIDE may react with water to produce corrosive hydrochloric acid and toxic fumes.
Reactivity Profile
MOLYBDENUM(V) CHLORIDE is a corrosive, hygroscopic solid, on contact with water or steam MOLYBDENUM(V) CHLORIDE decomposes to form hydrochloric acid. When heated to decomposition MOLYBDENUM(V) CHLORIDE emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].
Hazard
Irritant.
Health Hazard
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Safety Profile
A poison. A corrosive irritant to skin, eyes, and mucous membranes. Reacts with moisture to form hydrochloric acid. When heated to decomposition it emits toxic fumes of Mo and Cl-.
MOLYBDENUM(V) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from MOLYBDENUM(V) CHLORIDE manufacturers
- Product
- Molybdenum(V) Chloride 10241-05-1
- Price
- US $990.00/Kg
- Min. Order
- 0.100Kg
- Purity
- 97
- Supply Ability
- 500 Kg
- Release date
- 2024-11-12
- Product
- MOLYBDENUM(V) CHLORIDE 10241-05-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- MOLYBDENUM(V) CHLORIDE 10241-05-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 85.0-99.8%
- Supply Ability
- 200kg
- Release date
- 2019-08-30