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THALLIUM(I) CHLORIDE

Product Name
THALLIUM(I) CHLORIDE
CAS No.
7791-12-0
Chemical Name
THALLIUM(I) CHLORIDE
Synonyms
TlCl;chlorothallium;thallouschloride0;THALLOUS CHLORIDE;THALLIUM CHLORIDE;Thallium(Ⅰ)chloride;Thalium(I) chloride;rcrawastenumberu216;THALLIUM(I) CHLORIDE;THALLIUM(+1)CHLORIDE
CBNumber
CB1329649
Molecular Formula
ClTl
Formula Weight
239.84
MOL File
7791-12-0.mol
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THALLIUM(I) CHLORIDE Property

Melting point:
430 °C(lit.)
Boiling point:
720 °C
Density 
7 g/mL at 25 °C(lit.)
vapor pressure 
10 mm Hg ( 517 °C)
refractive index 
2.247
storage temp. 
Poison room
solubility 
ethanol: insoluble(lit.)
form 
beads
color 
White to off-white
Specific Gravity
7.004
Water Solubility 
Slightly soluble in water. Insoluble in alcohol, and acetone.
Crystal Structure
CsCl type
Sensitive 
Air Sensitive
Merck 
14,9260
crystal system
Cube
Space group
Pm3m
Solubility Product Constant (Ksp)
pKsp: 3.73
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.38420.38420.38429090900.0567
Exposure limits
ACGIH: TWA 0.02 mg/m3 (Skin)
NIOSH: IDLH 15 mg/m3; TWA 0.1 mg/m3
Dielectric constant
32.700000000000003
Dielectric constant
32.700000000000003
Dielectric constant
2.2(20℃)
CAS DataBase Reference
7791-12-0(CAS DataBase Reference)
EPA Substance Registry System
Thallium(I) chloride (7791-12-0)
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Safety

Hazard Codes 
T+,N
Risk Statements 
26/28-33-51/53
Safety Statements 
13-28-45-61
RIDADR 
UN 1707 6.1/PG 2
WGK Germany 
3
RTECS 
XG4200000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
28273985
Hazardous Substances Data
7791-12-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
229962
Product name
Thallium(I) chloride
Purity
99.999% trace metals basis
Packaging
10g
Price
$163
Updated
2024/03/01
Sigma-Aldrich
Product number
224898
Product name
Thallium(I) chloride
Purity
99%
Packaging
25g
Price
$139
Updated
2024/03/01
Alfa Aesar
Product number
011839
Product name
Thallium(I) chloride
Purity
99.999% (metals basis)
Packaging
25g
Price
$235.65
Updated
2024/03/01
Alfa Aesar
Product number
011839
Product name
Thallium(I) chloride
Purity
99.999% (metals basis)
Packaging
5g
Price
$61.4
Updated
2023/06/20
Alfa Aesar
Product number
035721
Product name
Thallium(I) chloride, ultra dry
Purity
99.999% (metals basis)
Packaging
5g
Price
$123.65
Updated
2024/03/01
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THALLIUM(I) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

White, crystalline powder; becomes violet on exposure to light. Slightly soluble in water; insoluble in alcohol, ammonium hydroxide.

Uses

Catalyst (chlorination), suntan lamp monitors.

Uses

It is used as a catalyst in chlorination's and in suntan lamps. The low solubility of TlCl is exploited in chemical synthesis: treatment of metal chloride complexes with TlPF6, gives the corresponding metal hexafluorophosphate derivative. It is used as a tracer in medical imaging.

Uses

Used to prepare cage, dinuclear complexes (TI-cyclodiphosphazanes) which possess interesting metal-metal interactions.

Definition

ChEBI: Thallium monochloride is a thallium molecular entity and an inorganic chloride.

Preparation

Thallium chloride may be prepared by heating the metal with chlorine.

General Description

White, crystalline powder, becomes violet on exposure to light. Used as a catalyst in chlorinations and in suntan lamps.

Reactivity Profile

Fluorine and THALLIUM(I) CHLORIDE react violently, melting the product [Mellor Supp. 1:63 1956]. When heated to decomposition, THALLIUM(I) CHLORIDE emits very toxic fumes of chloride and thallium. Thallium(I) chloride is vigorously attacked by cold fluorine. A mixture of potassium and THALLIUM(I) CHLORIDE produces a weak explosion on impact [EPA, 1998].

Hazard

Thallium chloride is highly toxic. Acute toxic effects are those of thallium poisoning.

Health Hazard

(Non-Specific -- Thallium Salts) Poisonous if swallowed. Inhalation of dust is poisonous.

Fire Hazard

(Non-Specific -- Thallium Salts) Fire may produce irritating or poisonous gases. When heated to decomposition, THALLIUM(I) CHLORIDE emits very toxic fumes of chloride and thallium. Thallium(I) chloride is vigorously attacked by cold fluorine. A mixture of potassium and THALLIUM(I) CHLORIDE produces a weak explosion on impact.

Safety Profile

Poison by ingestion and intraperitoneal routes. An experimental teratogen. Mutation data reported. Incompatible with F2. When heated to decomposition it emits very toxic fumes of Cland T1. See also THALLIUM COMPOUNDS and CHLORIDES.

Purification Methods

Crystallise it from 1% HCl and wash it until acid-free, or crystallise it from hot water (50mL/g), then dry it at 140o and store it in brown bottles. Also purify it by subliming it in a vacuum, followed by treatment with dry HCl gas and filtering while molten. (It is soluble in 260 parts of cold water and 70 parts of boiling water). POISONOUS.

THALLIUM(I) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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THALLIUM(I) CHLORIDE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shanghai Witofly Chemical Co. ,Ltd.
Tel
021-5063062 15300832537
Email
sales@witofly.com
Country
China
ProdList
1603
Advantage
55
Guangzhou Jhd Chemical Reagent Co., Ltd.
Tel
020-84383047
Fax
020-84380294
Email
sales@jhd.com.cn
Country
China
ProdList
9186
Advantage
65
Aikon International Limited
Tel
025-66113011 18112977050
Fax
(5)02557626880
Email
cb6@aikonchem.com
Country
China
ProdList
15494
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Hubei Jusheng Technology Co.,Ltd.
Tel
18871490254
Fax
027-59599243
Email
linda@hubeijusheng.com
Country
CHINA
ProdList
28172
Advantage
58
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View Lastest Price from THALLIUM(I) CHLORIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
THALLIUM(I) CHLORIDE 7791-12-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

7791-12-0, THALLIUM(I) CHLORIDERelated Search:


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