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Tetramethylammonium tribromide

Product Name
Tetramethylammonium tribromide
CAS No.
15625-56-6
Chemical Name
Tetramethylammonium tribromide
Synonyms
Einecs 239-700-8;TETRAMETHYLAMMONIUM TRIBROMIDE;Tetramethylammonium tribromide, 98+%;Mono(tetramethylammonium) tribromide;TETRAMETHYLAMMONIUM BROMIDE PERBROMIDE;n,n,n-trimethyl-methanaminiu(tribromide);Methanaminium, N,N,N-trimethyl-, (tribromide);Methanaminium, N,N,N-trimethyl-, (tribromide) (1:1)
CBNumber
CB1329760
Molecular Formula
C4H12Br3N-2
Formula Weight
313.86
MOL File
15625-56-6.mol
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Tetramethylammonium tribromide Property

Melting point:
115-118 °C
solubility 
slightly sol H2O, alcohols, other organic solvents; slowly dissolves in acetone, reacting to form a lachrymatory solution.
form 
powder
color 
orange
Sensitive 
Hygroscopic
BRN 
3914655
CAS DataBase Reference
15625-56-6
EPA Substance Registry System
Methanaminium, N,N,N-trimethyl-, (tribromide) (15625-56-6)
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3263 8/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S433764
Product name
TETRAMETHYLAMMONIUM TRIBROMIDE
Purity
AldrichCPR
Packaging
1g
Price
$179
Updated
2024/03/01
Alfa Aesar
Product number
B24237
Product name
Tetramethylammonium tribromide
Purity
98%
Packaging
100g
Price
$205
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0165054
Product name
TETRAMETHYLAMMONIUM TRIBROMIDE
Purity
98.00%
Packaging
1G
Price
$648.81
Updated
2021/12/16
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Tetramethylammonium tribromide Chemical Properties,Usage,Production

Preparation

Tetraalkylammonium salts that have poor stability can be freshly prepared by the procedure in eq 1. Stoichiometric amounts of tetraalkylammonium (methyl, ethyl, butyl…) bromide and sodium bromide are dissolved into hot water (1 L/mol of sodium bromide) and concd nitric acid (2.2 mol/mol NaBr) is slowly added with stirring. The reaction starts after few min and can be quite exothermic. When the temperature of the mixture returns to rt, the orange precipitate is filtered, washed with ethanol and ether, and dried.

storage

Tetramethylammonium tribromide is a hygroscopic solid and should be stored under dry conditions. Purity more than 98%; stable bromine degree (1 g = 3.18 mequiv Br2) when correctly handled. Avoid washing reaction vessels with acetone. Less toxic than bromine, but handle in a fume hood.

Tetramethylammonium tribromide Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetramethylammonium tribromide Suppliers

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15625-56-6, Tetramethylammonium tribromideRelated Search:


  • TETRAMETHYLAMMONIUM BROMIDE PERBROMIDE
  • TETRAMETHYLAMMONIUM TRIBROMIDE
  • n,n,n-trimethyl-methanaminiu(tribromide)
  • Einecs 239-700-8
  • Methanaminium, N,N,N-trimethyl-, (tribromide)
  • Methanaminium, N,N,N-trimethyl-, (tribromide) (1:1)
  • Mono(tetramethylammonium) tribromide
  • Tetramethylammonium tribromide, 98+%
  • 15625-56-6
  • C4H12N3Br
  • C4H12Br3N
  • CH34NBr3
  • C4H12NBr3
  • Synthetic Reagents
  • Phase Transfer Catalysts
  • Ammonium Salts