BIS(TRIMETHYLSILYL)PEROXIDE

Product Name: BIS(TRIMETHYLSILYL)PEROXIDE
CAS No.: 5796-98-5
Chemical Name: BIS(TRIMETHYLSILYL)PEROXIDE
Synonyms: Peroxybis(trimethylsilane);Bis-(trimethylsilyl)peroxid;BIS(TRIMETHYLSILYL)PEROXIDE;Silane, 1,1'-dioxybis[1,1,1-triMethyl-;triMethyl[(triMethylsilyl)peroxy]silane;Bis(trimethylsilyl)peroxide ~50% in HMDS;Bis(trimethylsilyl) Peroxide (ca. 30% in Hexane);Bis(triMethylsilyl) Peroxide (contains HexaMethyldisiloxane);Bis(trimethylsilyl) Peroxide (contains Hexamethyldisiloxane) (ca. 30% in Hexane)
CBNumber: CB1330326
Molecular Formula: C6H18O2Si2
Formula Weight: 178.38
MOL File: 5796-98-5.mol

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BIS(TRIMETHYLSILYL)PEROXIDE Property

Melting point:: <0°C
Boiling point:: 35 °C
Density: 0.829
Flash point:: <40°C
storage temp.: below 5° C
solubility: highly sol aprotic organic solvents.
form: Colourless Solution
Specific Gravity: 0.829
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
CAS DataBase Reference: 5796-98-5

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Safety

Risk Statements: 8-10
Safety Statements: 17-36/37/39
RIDADR: 3103
TSCA: No
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: B535285
Product name: Bis(trimethylsilyl)peroxide~50%inHMDS
Packaging: 100mg
Price: $475
Updated: 2021/12/16

TRC

Product number: B535285
Product name: Bis(trimethylsilyl)peroxide~50%inHMDS
Packaging: 250mg
Price: $1050
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0005351
Product name: BIS-(TRIMETHYLSILYL)PEROXIDE
Purity: 95.00%
Packaging: 100G
Price: $1323
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0005351
Product name: BIS-(TRIMETHYLSILYL)PEROXIDE
Purity: 95.00%
Packaging: 5MG
Price: $504.66
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0005351
Product name: BIS-(TRIMETHYLSILYL)PEROXIDE
Purity: 95.00%
Packaging: 10G
Price: $522.81
Updated: 2021/12/16

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BIS(TRIMETHYLSILYL)PEROXIDE Chemical Properties,Usage,Production

Physical properties

bp 41°C/30 mmHg;7 n20 D 1.3970.

Uses

Bis(trimethylsilyl) peroxide is an organosilicon compound used as a reagent for Bayer-Villiger oxidation of ketones.

Uses

Bis(trimethylsilyl) peroxide (1) functions as an electrophilic hydroxylating agent for aliphatic, aromatic, and heteroaromatic anions.Reaction of their lithium or Grignard compounds with (1) often affords trimethylsiloxy intermediates, which undergo desilylation with HCl in methanol to give the corresponding alcohols in good yields. In the presence of a catalytic amount of trifluoromethanesulfonic acid, (1) reacts with aromatic compounds to produce the corresponding phenols after acidic workup.In these reactions the Me3SiO? moiety is considered as a synthon of the hydroxyl cation (i.e. OH+).

Preparation

obtained in 80–96% yields by reaction of chlorotrimethylsilane with 1,4-diazabicyclo[2.2.2]octane· (H2O2)2,hexamethylenetetramine·H2O2,or hydrogen peroxide–urea in CH2Cl2.

BIS(TRIMETHYLSILYL)PEROXIDE Preparation Products And Raw materials

Raw materials

Hydrogen peroxide Chlorotrimethylsilane Dichloromethane Hexamethylenetetramine

Preparation Products

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BIS(TRIMETHYLSILYL)PEROXIDE Suppliers

China 21 Germany 2 India 1 Japan 1 Singapore 1 United Kingdom 2 United States 4 Global 32

J & K SCIENTIFIC LTD.

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3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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TOKYO CHEMICAL INDUSTRY CO., LTD.

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Candia Thamtech Company Limited

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9ding chemical ( Shanghai) Limited

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Suzhou Siso new material Co.,Ltd.

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Zhengzhou Acme Chemical Co., Ltd.

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5796-98-5, BIS(TRIMETHYLSILYL)PEROXIDERelated Search:

Tetramethylsilane Poly(dimethylsiloxane) BIS(TRIMETHYLSILYL)PEROXIDE

Bis(trimethylsilyl) Peroxide (contains Hexamethyldisiloxane) (ca. 30% in Hexane)

triMethyl[(triMethylsilyl)peroxy]silane

Silane, 1,1'-dioxybis[1,1,1-triMethyl-

Bis(trimethylsilyl) Peroxide (ca. 30% in Hexane)

Bis(triMethylsilyl) Peroxide (contains HexaMethyldisiloxane)

Peroxybis(trimethylsilane)

BIS(TRIMETHYLSILYL)PEROXIDE

Bis-(trimethylsilyl)peroxid

Bis(trimethylsilyl)peroxide ~50% in HMDS

5796-98-5

C6H18O2Si2

Industrial/Fine Chemicals