Bis(pyridine)iodonium tetrafluoroborate

Product Name: Bis(pyridine)iodonium tetrafluoroborate
CAS No.: 15656-28-7
Chemical Name: Bis(pyridine)iodonium tetrafluoroborate
Synonyms: IPY2BF4;Barluengas;BARLUENGA'S REAGENT;SKL215;iodanium;BarluengaReagentIpy2Bf4;Barluenga’S Reagent Ipy2Bf4;Iodanium pyridine tetrafluoroborate;iodonium pyridine tetrafluoroborate;BIS(PYRIDINE)IODONIUM TETRAFLUOROBORATE
CBNumber: CB1347762
Molecular Formula: C10H10BF4IN2
Formula Weight: 371.91
MOL File: 15656-28-7.mol

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Bis(pyridine)iodonium tetrafluoroborate Property

Melting point:: 137-141 °C (lit.)
storage temp.: 2-8°C
solubility: sol CH2Cl2, DMSO, MeCN, pyridine, DMF; modestly sol CHCl3; insol ether, THF, hexane
form: Powder
color: Yellow
Water Solubility: Hydrolyzes in water.
Sensitive: Moisture & Light Sensitive
Merck: 14,1302
BRN: 4284739
CAS DataBase Reference: 15656-28-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,T
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
RIDADR: 1759
WGK Germany: 3
Hazard Note: Toxic/Irritant
HazardClass: MOISTURE SENSITIVE, KEEP COLD, LIGHT SENSITIVE
PackingGroup: II
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 531634
Product name: Bis(pyridine)iodonium tetrafluoroborate
Packaging: 1g
Price: $72.2
Updated: 2024/03/01

TCI Chemical

Product number: B2539
Product name: Bis(pyridine)iodonium Tetrafluoroborate
Purity: >95.0%(T)
Packaging: 1g
Price: $184
Updated: 2024/03/01

Alfa Aesar

Product number: L19385
Product name: Bis(pyridine)iodonium tetrafluoroborate, 97%
Packaging: 250mg
Price: $27.65
Updated: 2024/03/01

Alfa Aesar

Product number: L19385
Product name: Bis(pyridine)iodonium tetrafluoroborate, 97%
Packaging: 1g
Price: $66.65
Updated: 2024/03/01

TRC

Product number: I706520
Product name: Bis(pyridine)iodonium Tetrafluoroborate
Packaging: 100mg
Price: $75
Updated: 2021/12/16

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Bis(pyridine)iodonium tetrafluoroborate Chemical Properties,Usage,Production

Description

Bis(pyridine)iodonium tetrafluoroborate is iodinating agent for the selective functionalization of unsaturated compounds; can also mediate C-C bond formation.

Preparation

Bis(pyridine)iodonium tetrafluoroborate is prepared by the reaction of HgO/HBF4-SiO2 with iodine and pyridine in dry CH2Cl2 at rt. Solids are filtered off, and the reagent is isolated by precipitation from CH2Cl2 solution by addition of cold ether, repeating the operation several times until a negative test for mercury(II) is obtained (i.e. absence of precipitation of mercury by treatment of an aliquot with NaBH4/NaOH).

Chemical Properties

Yellow powder

Uses

Bis(pyridine)iodonium tetrafluoroborate is used as mild iodinating and oxidizing reagent. It is also useful for selective iodination of free phenolic groups in tyrosine residues during solid-phase synthesis.

storage

Bis(pyridine)iodonium tetrafluoroborate can be safely stored under a nitrogen atmosphere (in the dark at 4 °C) for long periods of time (up to 3 months has been observed) without changing either properties or physical appearance.

Purification Methods

recrystallization from CH2Cl2-CHCl3 (white solid)

Bis(pyridine)iodonium tetrafluoroborate Preparation Products And Raw materials

Raw materials

Silica gel Mercuric Oxide Fluoroboric acid Iodine Pyridine

Preparation Products

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Bis(pyridine)iodonium tetrafluoroborate Suppliers

Americas 1 Belgium 1 China 54 Europe 3 France 1 Germany 3 India 4 Japan 1 South Korea 1 Spain 2 Switzerland 2 United Kingdom 12 United States 28 Global 113

J & K SCIENTIFIC LTD.

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Hunan Hui Bai Shi Biotechnology Co., Ltd.

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Thermo Fisher Scientific

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View Lastest Price from Bis(pyridine)iodonium tetrafluoroborate manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: Bis(pyridine)iodonium tetrafluoroborate 15656-28-7
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: Bis(pyridine)iodonium tetrafluoroborate 15656-28-7
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-10

15656-28-7, Bis(pyridine)iodonium tetrafluoroborateRelated Search:

Dimefluthrin Pyridine Sodium tetrafluoroborate AZURE B TETRAFLUOROBORATE Propidium iodide Bis(pyridine)iodonium tetrafluoroborate

BIS(PYRIDINE)IODONIUM(1)TETRAFLUOROBORATE

BARLUENGAS REAGENT IPY2BF4 BIS(PYRIDINE)IODONIUM(I) ETRAFLUOROBORATE

Iodanium pyridine tetrafluoroborate

BarluengaReagentIpy2Bf4

Bis(pyridine)iodonium tetrafluoroborate,97%

Bis(pyridine)iodonium tetrafluoroborate≥ 97% (NMR)

IPY2BF4

BIS(PYRIDINE)IODONIUM (I) TETRAFLUOROBORATE

BIS(PYRIDINE)IODONIUM TETRAFLUOROBORATE

BARLUENGA'S REAGENT

Barluengas

iodonium pyridine tetrafluoroborate

Barluenga’S Reagent Ipy2Bf4

Bis(pyridine)iodonium Tetrafluoroborate &gt

Iodine(1+), bis(pyridine)-, tetrafluoroborate(1-) (1:1)

SKL215

iodanium

15656-28-7

2C5H5NBF4I

C10H10BF4IN2

C10H12IN2

C10H10IN2BF4

Hypervalent Iodine

Oxidation

Synthetic Reagents

Hypervalent Iodine

Oxidation

Synthetic Reagents