METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE

Product Name: METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE
CAS No.: 34918-57-5
Chemical Name: METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE
Synonyms: METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE;Benzeneacetic acid, 3-bromo-4-hydroxy-, methyl ester
CBNumber: CB13561567
Molecular Formula: C9H9BrO3
Formula Weight: 245.07
MOL File: 34918-57-5.mol

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METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Property

Boiling point:: 302.2±27.0 °C(Predicted)
Density: 1.562±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 8.23±0.18(Predicted)
Appearance: Colorless to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 100mg
Price: $30
Updated: 2021/12/16

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 250mg
Price: $40
Updated: 2021/12/16

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 1g
Price: $98
Updated: 2021/12/16

Ambeed

Product number: A213006
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 5g
Price: $327
Updated: 2021/12/16

Chemenu

Product number: CM252396
Product name: Methyl2-(3-bromo-4-hydroxyphenyl)acetate
Purity: 95%
Packaging: 1g
Price: $385
Updated: 2021/12/16

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METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Chemical Properties,Usage,Production

Synthesis

67-56-1

38692-80-7

34918-57-5

Step 1: Synthesis of methyl 2-(3-bromo-4-hydroxyphenyl)acetate 3-Bromo-4-hydroxyphenylacetic acid (0.3 g, 1.3 mmol, 1.0 equiv) and concentrated H2SO4 (2.77 μL, 0.05 mmol, 0.04 equiv) were dissolved in methanol (10 mL). The reaction mixture was stirred for 1 h at room temperature. Upon completion of the reaction, the reaction was quenched with NaOH solution and subsequently extracted with ethyl acetate (EtOAc). The organic layers were combined, dried with anhydrous Na2SO4 and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane/EtOAc = 5:1) to afford the target compound methyl 2-(3-bromo-4-hydroxyphenyl)acetate (0.2 g, 63% yield).LCMS m/z 245.0 [M + 1]+.

References

[1] Patent: WO2004/62661, 2004, A1. Location in patent: Page/Page column 28
[2] Patent: WO2010/138901, 2010, A1. Location in patent: Page/Page column 155
[3] Yakugaku Zasshi, 1933, vol. 53, p. 557,563; dtsch. Ref. S. 92
[4] Chem.Abstr., 1933, p. 4223
[5] Patent: WO2004/50637, 2004, A2. Location in patent: Page 74

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE Suppliers

China 25 India 1 United States 3 Global 29

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34918-57-5, METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATERelated Search:

METHYL 2-(3-BROMO-4-HYDROXYPHENYL)ACETATE

Benzeneacetic acid, 3-bromo-4-hydroxy-, methyl ester

34918-57-5