ChemicalBook > CAS DataBase List > 4-(MORPHOLINOMETHYL)BENZYLAMINE

4-(MORPHOLINOMETHYL)BENZYLAMINE

Product Name
4-(MORPHOLINOMETHYL)BENZYLAMINE
CAS No.
91271-84-0
Chemical Name
4-(MORPHOLINOMETHYL)BENZYLAMINE
Synonyms
AKOS BB-8919;BUTTPARK 98\57-94;AKOS BBS-00002727;TIMTEC-BB SBB011151;4-(MORPHOLINOMETHYL)BENZYLAMINE;4-MORPHOLIN-4-YLMETHYLBENZYLAMINE;4-Morpholino-4ylmethylbenzylamine;4-(4-MORPHOLINYLMETHYL)BENZYLAMINE;-(Morpholin-4-ylmethyl)benzylamine;4-[4-(Aminomethyl)benzyl]morpholine
CBNumber
CB1372544
Molecular Formula
C12H18N2O
Formula Weight
206.28
MOL File
91271-84-0.mol
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4-(MORPHOLINOMETHYL)BENZYLAMINE Property

Melting point:
54-56°C
Boiling point:
324.7±32.0 °C(Predicted)
Density 
1.103±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
9.18±0.10(Predicted)
Appearance
White to off-white Solid
CAS DataBase Reference
91271-84-0
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Safety

Hazard Codes 
C
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Corrosive
HazardClass 
IRRITANT
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC
Product number
B497313
Product name
(4-(Morpholinomethyl)phenyl)methanamine
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
W9366
Product name
4-Morpholin-4-ylmethylbenzylamine
Packaging
1g
Price
$136
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-WV
Product name
4-(Morpholin-4-ylmethyl)benzylamine
Purity
97.0%
Packaging
250mg
Price
$96
Updated
2021/12/16
Matrix Scientific
Product number
054432
Product name
4-Morpholin-4-ylmethyl-benzylamine
Packaging
500mg
Price
$205
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-WV
Product name
4-(Morpholin-4-ylmethyl)benzylamine
Purity
97.0%
Packaging
1g
Price
$237
Updated
2021/12/16
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4-(MORPHOLINOMETHYL)BENZYLAMINE Chemical Properties,Usage,Production

Synthesis

37812-51-4

91271-84-0

General procedure for the synthesis of 4-(morpholinomethyl)benzylamine: lithium aluminum hydride (1.13 g, 29.7 mmol) was slowly added to tetrahydrofuran (THF, 50 mL) at 0 °C under nitrogen protection, followed by the dropwise addition of 4-(morpholin-4-ylmethyl)benzyl nitrile (2 g, 9.89 mmol) in THF solution (10 mL). The reaction mixture was stirred at 0 °C for 1 h and then brought to room temperature and continued to stir overnight. Upon completion of the reaction, the mixture was cooled to 0 °C and the reaction was quenched by the slow addition of water (1.15 mL). Next, ether (125 mL) and 3N NaOH aqueous solution (1.15 mL) were added followed by water (3.45 mL) and stirred for 1 hour at room temperature. The solid residue was removed by filtration and the filtrate was concentrated in vacuum to give 4-(morpholinomethyl)benzylamine as a colorless oil (1.87 g, 94% yield). Mass spectrum (APCI+) m/z: 207 ([M + H]+).

References

[1] Patent: WO2007/28083, 2007, A2. Location in patent: Page/Page column 91-92
[2] European Journal of Medicinal Chemistry, 2018, vol. 152, p. 31 - 52

4-(MORPHOLINOMETHYL)BENZYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-(MORPHOLINOMETHYL)BENZYLAMINE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
-(Morpholin-4-ylmethyl)benzylamine 91271-84-0
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-06

91271-84-0, 4-(MORPHOLINOMETHYL)BENZYLAMINERelated Search:


  • TIMTEC-BB SBB011151
  • AKOS BBS-00002727
  • AKOS BB-8919
  • 4-(4-MORPHOLINYLMETHYL)BENZYLAMINE
  • 4-MORPHOLIN-4-YLMETHYLBENZYLAMINE
  • 4-(MORPHOLINOMETHYL)BENZYLAMINE
  • BUTTPARK 98\57-94
  • {4-[(Morpholin-4-yl)methyl]phenyl}methylamine 97%
  • 4-[(Morpholin-4-yl)methyl]benzylamine, 4-[4-(Aminomethyl)benzyl]morpholine
  • (4-(MorpholinoMethyl)phenyl)MethanaMine
  • {4-[(Morpholin-4-yl)methyl]phenyl}methylamine97%
  • 4-Morpholino-4ylmethylbenzylamine
  • 4-(Morpholin-4-ylmethyl)benzylamine 97%
  • 4-MORPHOLIN-4-YLMETHYLBENZYLAMINE, 95+%
  • 1-[4-(MORPHOLIN-4-YLMETHYL)PHENYL]METHANAMINE
  • -(Morpholin-4-ylmethyl)benzylamine
  • 4-[4-(Aminomethyl)benzyl]morpholine
  • Benzenemethanamine, 4-(4-morpholinylmethyl)-
  • {4-[(Morpholin-4-yl)methyl]phenyl}methylamine
  • 91271-84-0
  • 91274-84-0