4-(MORPHOLINOMETHYL)BENZYLAMINE
- Product Name
- 4-(MORPHOLINOMETHYL)BENZYLAMINE
- CAS No.
- 91271-84-0
- Chemical Name
- 4-(MORPHOLINOMETHYL)BENZYLAMINE
- Synonyms
- AKOS BB-8919;BUTTPARK 98\57-94;AKOS BBS-00002727;TIMTEC-BB SBB011151;4-(MORPHOLINOMETHYL)BENZYLAMINE;4-MORPHOLIN-4-YLMETHYLBENZYLAMINE;4-Morpholino-4ylmethylbenzylamine;4-(4-MORPHOLINYLMETHYL)BENZYLAMINE;-(Morpholin-4-ylmethyl)benzylamine;4-[4-(Aminomethyl)benzyl]morpholine
- CBNumber
- CB1372544
- Molecular Formula
- C12H18N2O
- Formula Weight
- 206.28
- MOL File
- 91271-84-0.mol
4-(MORPHOLINOMETHYL)BENZYLAMINE Property
- Melting point:
- 54-56°C
- Boiling point:
- 324.7±32.0 °C(Predicted)
- Density
- 1.103±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- pka
- 9.18±0.10(Predicted)
- Appearance
- White to off-white Solid
- CAS DataBase Reference
- 91271-84-0
Safety
- Hazard Codes
- C
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- Hazard Note
- Corrosive
- HazardClass
- IRRITANT
- HS Code
- 2934999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- B497313
- Product name
- (4-(Morpholinomethyl)phenyl)methanamine
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- W9366
- Product name
- 4-Morpholin-4-ylmethylbenzylamine
- Packaging
- 1g
- Price
- $136
- Updated
- 2021/12/16
- Product number
- 4H56-1-WV
- Product name
- 4-(Morpholin-4-ylmethyl)benzylamine
- Purity
- 97.0%
- Packaging
- 250mg
- Price
- $96
- Updated
- 2021/12/16
- Product number
- 054432
- Product name
- 4-Morpholin-4-ylmethyl-benzylamine
- Packaging
- 500mg
- Price
- $205
- Updated
- 2021/12/16
- Product number
- 4H56-1-WV
- Product name
- 4-(Morpholin-4-ylmethyl)benzylamine
- Purity
- 97.0%
- Packaging
- 1g
- Price
- $237
- Updated
- 2021/12/16
4-(MORPHOLINOMETHYL)BENZYLAMINE Chemical Properties,Usage,Production
Synthesis
37812-51-4
91271-84-0
General procedure for the synthesis of 4-(morpholinomethyl)benzylamine: lithium aluminum hydride (1.13 g, 29.7 mmol) was slowly added to tetrahydrofuran (THF, 50 mL) at 0 °C under nitrogen protection, followed by the dropwise addition of 4-(morpholin-4-ylmethyl)benzyl nitrile (2 g, 9.89 mmol) in THF solution (10 mL). The reaction mixture was stirred at 0 °C for 1 h and then brought to room temperature and continued to stir overnight. Upon completion of the reaction, the mixture was cooled to 0 °C and the reaction was quenched by the slow addition of water (1.15 mL). Next, ether (125 mL) and 3N NaOH aqueous solution (1.15 mL) were added followed by water (3.45 mL) and stirred for 1 hour at room temperature. The solid residue was removed by filtration and the filtrate was concentrated in vacuum to give 4-(morpholinomethyl)benzylamine as a colorless oil (1.87 g, 94% yield). Mass spectrum (APCI+) m/z: 207 ([M + H]+).
References
[1] Patent: WO2007/28083, 2007, A2. Location in patent: Page/Page column 91-92
[2] European Journal of Medicinal Chemistry, 2018, vol. 152, p. 31 - 52
4-(MORPHOLINOMETHYL)BENZYLAMINE Preparation Products And Raw materials
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View Lastest Price from 4-(MORPHOLINOMETHYL)BENZYLAMINE manufacturers
- Product
- -(Morpholin-4-ylmethyl)benzylamine 91271-84-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 5mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-06