ChemicalBook > CAS DataBase List > 1,2,3,5-Tetrachlorobenzene

1,2,3,5-Tetrachlorobenzene

Product Name
1,2,3,5-Tetrachlorobenzene
CAS No.
634-90-2
Chemical Name
1,2,3,5-Tetrachlorobenzene
Synonyms
1,2,3,5-tcb;1,2,3,5-Tetrachlorob;1,3,4,5-Tetrachlorbenzol;,2,3,5-TETRACHLOROBENZENE;Nicotinamide Impurity 249;1,2,3,5-TETRACHLOROBENZENE;tetrachloro1,2,3,5-benzene;1,2,4,6-tetrachlorobenzene;1,2,3,5-tetrachloro-benzen;1,3,4,5-Tetrachlorobenzene
CBNumber
CB1395743
Molecular Formula
C6H2Cl4
Formula Weight
215.89
MOL File
634-90-2.mol
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1,2,3,5-Tetrachlorobenzene Property

Melting point:
54.5°C
Boiling point:
246°C
Density 
1.5578 (estimate)
vapor pressure 
0.07 at 25 °C (extrapolated, Mackay et al., 1982)
refractive index 
1.5348 (estimate)
Flash point:
113 °C
storage temp. 
APPROX 4°C
solubility 
Soluble in alcohol, benzene, ether, and ligroin (Weast, 1986)
color 
White to Almost white
Water Solubility 
4.016mg/L(25 ºC)
BRN 
1618864
Henry's Law Constant
58.0 at 25 °C (gas stripping-GC, Shiu and Mackay, 1997)
CAS DataBase Reference
634-90-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1,2,3,5-tetrachloro-(634-90-2)
EPA Substance Registry System
1,2,3,5-Tetrachlorobenzene (634-90-2)
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Safety

Hazard Codes 
Xn,T,F
Risk Statements 
22-39/23/24/25-23/24/25-11
Safety Statements 
22-24/25-45-36/37-16-7
RIDADR 
UN 1230 3/PG 2
WGK Germany 
3
RTECS 
DB9445000
HS Code 
2903.99.8001
Hazardous Substances Data
634-90-2(Hazardous Substances Data)
Toxicity
Acute oral LD50 for rats 1,727 mg/kg (quoted, RTECS, 1985).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
36928
Product name
1,2,3,5-Tetrachlorobenzene
Purity
PESTANAL
Packaging
250mg
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
T0870
Product name
1,2,3,5-Tetrachlorobenzene
Packaging
5G
Price
$153
Updated
2024/03/01
TCI Chemical
Product number
T0870
Product name
1,2,3,5-Tetrachlorobenzene
Packaging
25G
Price
$425
Updated
2024/03/01
TRC
Product number
T291995
Product name
1,2,3,5-Tetrachlorobenzene
Packaging
10g
Price
$185
Updated
2021/12/16
Matrix Scientific
Product number
098293
Product name
1,2,3,5-Tetrachlorobenzene
Purity
95+%
Packaging
1g
Price
$57
Updated
2021/12/16
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1,2,3,5-Tetrachlorobenzene Chemical Properties,Usage,Production

Uses

1,2,3,5-Tetrachlorobenzene is used in the synthesis of several organic compounds including that of polyarylated benzenes by multiple Suzuki-Miyaura reactions. It was used as part of study which investigated the antimicrobial activity of tetra substituted benzene derivatives which suggested antimicrobial activity tended to decrease with increasing size of halogen substituents.

Definition

ChEBI: A tetrachlorobenzene carrying chloro groups at positions 1, 2, 3 and 5.

General Description

White crystals or off-white solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Simple aromatic halogenated organic compounds, such as 1,2,3,5-Tetrachlorobenzene , are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 1,2,3,5-Tetrachlorobenzene may react with oxidizers. .

Health Hazard

ACUTE/CHRONIC HAZARDS: 1,2,3,5-Tetrachlorobenzene may cause irritation on contact.

Fire Hazard

1,2,3,5-Tetrachlorobenzene is probably combustible.

Environmental Fate

Biological. A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,3,5-tetrachlorobenzene to 2,3,4,6-tetrachlorophenol (Ballschiter and Scholz, 1980). The half-life of 1,2,3,5- tetrachlorobenzene in an anaerobic enrichment culture was 1.8 d (Beurskens et al., 1993).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,3,5- tetrachlorobenzene underwent reductive dechlorination to 1,2,4- and 1,3,5-trichlorobenzene at relative molar yields of 7 and 93%, respectively. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 94 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. Irradiation (λ ≥285 nm) of 1,2,3,5-tetrachlorobenzene (1.1–1.2 mM/L) in an acetonitrile-water mixture containing acetone (0.553 mM/L) as a sensitizer gave the following products (% yield): 1,2,3-trichlorobenzene (5.3), 1,2,4-trichlorobenzene (4.9), 1,3,5-trichlorobenzene (49.3), 1,3-dichlorobenzene (1.8), 2,3,4,4′,5,5′,6-heptachlorobiphenyl (1.41), 2,2′,3,4,4′,6,6′- heptachlorobiphenyl (1.10), 2,2′,3,3′,4,5′,6-heptachlorobiphenyl (4.50), four hexachlorobiphenyls (4.69), one pentachlorobiphenyl (0.64), trichloroacetophenone, 1-(trichlorophenyl)-2-propanone, and (trichlorophenyl)acetonitrile (Choudhry and Hutzinger, 1984). Without acetone, the identified photolysis products (% yield) included 1,2,3-trichlorobenzene (trace), 1,2,4-trichlorobenzene (24.3), 1,3,5-trichlorobenzene (11.7), 1,3-dichlorobenzene (0.5), 1,4-dichlorobenzene (3.3), pentachlorobenzene (1.43), 1,2,3,4-tetrachlorobenzene (5.99), two heptachlorobiphenyls (1.40), two hexachlorobiphenyls (<0.01), and one pentachlorobiphenyl (0.75) (Choudhry and Hutzinger, 1984).

Purification Methods

Crystallise it from EtOH. [Beilstein 5 II 157, 5 III 551, 5 IV 668.]

1,2,3,5-Tetrachlorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2,3,5-Tetrachlorobenzene Suppliers

TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
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Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
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57
Wuhan Haizheng Industry & Trade Development Co. Ltd
Tel
027-8866 0053/88660577/88660578
Fax
027-8899 1911
Country
China
ProdList
1073
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Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
T&W GROUP
Tel
021-61551611 13296011611
Fax
+86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
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View Lastest Price from 1,2,3,5-Tetrachlorobenzene manufacturers

Career Henan Chemical Co
Product
1,2,3,5-Tetrachlorobenzene 634-90-2
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
as request
Release date
2018-12-24

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