4'-METHOXY-2-METHYL-BIPHENYL
Synthesis
- Product Name
- 4'-METHOXY-2-METHYL-BIPHENYL
- CAS No.
-
92495-54-0
- Chemical Name
- 4'-METHOXY-2-METHYL-BIPHENYL
- Synonyms
- AKOS BAR-1281;4-o-Tolylanisole;Anisole, p-(o-tolyl)- (7CI);4'-methoxy-2-methylbiphenyl;4'-METHOXY-2-METHYL-BIPHENYL;4-METHOXY-2'-METHYL-1,1'-BIPHENYL;4'-Methoxy-2-methyl-1,1'-biphenyl;1-methoxy-4-(2-methylphenyl)benzene
- CBNumber
- CB1400391
- Molecular Formula
- C14H14O
- Formula Weight
- 198.26
- MOL File
- 92495-54-0.mol
4'-METHOXY-2-METHYL-BIPHENYL Property
- Melting point:
- 97.8-98.6℃
- Boiling point:
- 140-141.5℃ (13 Torr)
- Density
- 1.016±0.06 g/cm3(Predicted)
Hazard and Precautionary Statements (GHS)
N-Bromosuccinimide Price
American Custom Chemicals Corporation
- Product number
- CHM0150682
- Product name
- 4'-METHOXY-2-METHYL-BIPHENYL
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $495.45
- Updated
- 2021/12/16
Alichem
- Product number
- 52008943
- Product name
- 4-Methoxy-2-methylbiphenyl
- Packaging
- 1g
- Price
- $1490
- Updated
- 2021/12/16
4'-METHOXY-2-METHYL-BIPHENYL Chemical Properties,Usage,Production
Synthesis
Open to the atmosphere, 4-bromoanisole (1.87 g, 10 mmol), o-tolylboronic acid (1.50 g, 11 mmol), KF (spray dried, dried in an oven overnight prior to use, 1.92 g, 33 mmol), and THF (10 mL) were added to a 100-ml round-bottomed Schlenk flflask equipped with a stir bar. The reaction system was flflushed with argon for about 5 min. P(t-Bu)3 (1.9 × 10–4 M stock solution in THF; 2.31 mL, 5.0 × 10–5 mmol) and Pd2(dba)3 (2.16 × 10–5 M stock solution in THF; 2.31 mL, 5.0 × 10–5 mmol) in THF were added sequentially. After 48 h at room temperature, the reaction mixture was diluted with ether or EtOAc, fifiltered through a pad of silica gel with copious washings, and then concentrated. The crude product was then purifified via column chromatography eluting with 5% ether in hexane to yield 1.94 g (98%) of 4-methoxy-2´-methylbiphenyl as a colorless liquid.
4'-METHOXY-2-METHYL-BIPHENYL Preparation Products And Raw materials
Raw materials
Preparation Products
4'-METHOXY-2-METHYL-BIPHENYL Suppliers
- Tel
- --
- Fax
- --
- Email
- synthesis@chimmed.ru
- Country
- Russia
- ProdList
- 5006
- Advantage
- 81
92495-54-0, 4'-METHOXY-2-METHYL-BIPHENYLRelated Search:
4'-METHOXY-2-METHYL-BIPHENYL
4-METHOXY-2'-METHYL-1,1'-BIPHENYL
AKOS BAR-1281
Anisole, p-(o-tolyl)- (7CI)
4-o-Tolylanisole
1-methoxy-4-(2-methylphenyl)benzene
4'-Methoxy-2-methyl-1,1'-biphenyl
4'-methoxy-2-methylbiphenyl
92495-54-0