(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

Reactions

Product Name: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
CAS No.: 415918-91-1
Chemical Name: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
Synonyms: (S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
CBNumber: CB1405194
Molecular Formula: C36H30NO2P
Formula Weight: 539.61
MOL File: 415918-91-1.mol

More

Less

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Property

Melting point:: 102-103 °C
alpha: +427° (c 0.83, CHCl3)
Boiling point:: 710.7±63.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: -0.57±0.20(Predicted)
color: white
Sensitive: moisture sensitive
CAS DataBase Reference: 415918-91-1

More

Less

Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39
WGK Germany: 3
HS Code: 2934.99.4400

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TCI Chemical

Product number: D4994
Product name: (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity: >98.0%(HPLC)
Packaging: 200mg
Price: $174
Updated: 2024/03/01

TCI Chemical

Product number: D4994
Product name: (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity: >98.0%(HPLC)
Packaging: 1g
Price: $531
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1520
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
Packaging: 100mg
Price: $86
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1520
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
Packaging: 500mg
Price: $335
Updated: 2024/03/01

TRC

Product number: D455833
Product name: (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine
Packaging: 50mg
Price: $110
Updated: 2021/12/16

More

Less

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Chemical Properties,Usage,Production

Reactions

A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
allylic esters.
Asymmetric hydrogenation.
Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
Asymmetric hydrovinylation.
Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
Palladium-catalyzed enantioselective diamination of alkyl dienes.

Uses

(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Suppliers

Americas 1 China 50 Europe 1 Germany 1 India 2 Japan 1 Switzerland 1 Ukraine 1 United States 8 Global 66

Yantai Sheng Kai Lun Biological Products Co. , Ltd.

Tel: 13356901049
Email: mark@sklnchem.cn
Country: China
ProdList: 14384
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7195
Advantage: 65

Tianjin Derchemist Science & Technology Co., Ltd.

Tel: 22-58627059 13920586291
Fax: 022-58620305
Email: zdcomcon@126.com
Country: China
ProdList: 3461
Advantage: 50

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

415918-91-1, (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCTRelated Search:

BARIUM DINONYLNAPHTHALENESULFONATE (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE (R)-N-(2-PROPYL)-1-PHENYLETHYLAMINE HYDROCHLORIDE (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (R)-MONOPHOS (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-(+)-N-BENZYL-1-PHENYLETHYLAMINE HYDROCHLORIDE (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][

(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%

(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS)

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine

(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a

3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct

R-(3,5-Dioxa-4-Phospha-Cyclohepta[2,1-A:3,4-A']Dinaphthalen-4-yl)Bis[(1R)-1-Phenylethyl]aMine

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%

(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f] [1,3,2]dioxaphosphepin-4-amine

]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.

(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f] [1,3,2]dioxaphosphepin-4-amine,99%e.e.

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]-, (11bR)-

(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine dichloromethane adduct

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT

(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE

(11bR)-N，N-Bis[(R)-1-phenylethyl]-dinaphtho[2，1-d:1'，2'-f][1，3，2]dioxaphosphepin-4-amine

415918-91-1

Privileged Ligands

DSM MonoPhos Phosphoramidites

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Chiral Phosphine

CPN