ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
Reactions- Product Name
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
- CAS No.
- 415918-91-1
- Chemical Name
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
- Synonyms
- (S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
- CBNumber
- CB1405194
- Molecular Formula
- C36H30NO2P
- Formula Weight
- 539.61
- MOL File
- 415918-91-1.mol
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Property
- Melting point:
- 102-103 °C
- alpha
- +427° (c 0.83, CHCl3)
- Boiling point:
- 710.7±63.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- -0.57±0.20(Predicted)
- color
- white
- Sensitive
- moisture sensitive
- CAS DataBase Reference
- 415918-91-1
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Safety
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 2934.99.4400
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- D4994
- Product name
- (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
- Purity
- >98.0%(HPLC)
- Packaging
- 200mg
- Price
- $174
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D4994
- Product name
- (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
- Purity
- >98.0%(HPLC)
- Packaging
- 1g
- Price
- $531
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1520
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
- Packaging
- 100mg
- Price
- $86
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1520
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
- Packaging
- 500mg
- Price
- $335
- Updated
- 2024/03/01
TRC
- Product number
- D455833
- Product name
- (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine
- Packaging
- 50mg
- Price
- $110
- Updated
- 2021/12/16
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Chemical Properties,Usage,Production
Reactions
- A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
- Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
- allylic esters.
- Asymmetric hydrogenation.
- Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
- Asymmetric hydrovinylation.
- Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
- Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
- Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
- Palladium-catalyzed enantioselective diamination of alkyl dienes.
Uses
(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Suppliers
415918-91-1, (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCTRelated Search:
BARIUM DINONYLNAPHTHALENESULFONATE
(R)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE
(R)-N-(2-PROPYL)-1-PHENYLETHYLAMINE HYDROCHLORIDE
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(R)-MONOPHOS
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(R)-(+)-N-BENZYL-1-PHENYLETHYLAMINE HYDROCHLORIDE
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE
(R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][