2-METHYL-M-PHENYLENE DIISOCYANATE
- Product Name
- 2-METHYL-M-PHENYLENE DIISOCYANATE
- CAS No.
- 91-08-7
- Chemical Name
- 2-METHYL-M-PHENYLENE DIISOCYANATE
- Synonyms
- 2,6-TDI;hylenetic;2,6-TOLYLENE DIISOCYANATE;1,3-Diisocyanato-2-methylbenzene;Hylene tic;TDIPREPOLYMER;TOLUILENDIISOCYANATE;2-METHYL-M-PHENYLENE;Toluen 2,6-diisocyanate;2,6-Toluylendiisocyanat
- CBNumber
- CB1408074
- Molecular Formula
- C9H6N2O2
- Formula Weight
- 174.16
- MOL File
- 91-08-7.mol
2-METHYL-M-PHENYLENE DIISOCYANATE Property
- Melting point:
- 13°C
- Boiling point:
- 129-133 °C18 mm Hg(lit.)
- Density
- 1.225 g/mL at 25 °C(lit.)
- vapor pressure
- 2.78Pa at 25℃
- refractive index
- n20/D 1.571(lit.)
- Flash point:
- >230 °F
- storage temp.
- −20°C
- form
- Liquid
- color
- Clear colorless to light yellow
- Water Solubility
- It hydrolyzes in water.
- Sensitive
- Moisture Sensitive
- BRN
- 2211546
- Exposure limits
- ACGIH: TWA 0.001 ppm; STEL 0.005 ppm (Skin)
- Stability:
- Stability Reacts violently with water. Reacts very rapidly with compounds containing an active hydrogen, such as amines, alcohols and acids. Polymerizes rapidly in the presence of base. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 3.74
- CAS DataBase Reference
- 91-08-7(CAS DataBase Reference)
- EPA Substance Registry System
- Toluene-2,6-diisocyanate (91-08-7)
Safety
- Hazard Codes
- T+
- Risk Statements
- 26-36/37/38-40-42/43-52/53
- Safety Statements
- 23-36/37-45-61
- RIDADR
- UN 2078 6.1/PG 2
- WGK Germany
- 2
- RTECS
- CZ6310000
- F
- 8-10-19-21
- Autoignition Temperature
- >1148 °F
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29291090
- Hazardous Substances Data
- 91-08-7(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H330Fatal if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 223867
- Product name
- Tolylene-2,6-diisocyanate
- Purity
- 97%
- Packaging
- 1g
- Price
- $65.2
- Updated
- 2024/03/01
- Product number
- 33493
- Product name
- 2,6-TDI
- Purity
- analytical standard
- Packaging
- 100mg
- Price
- $90.1
- Updated
- 2024/03/01
- Product number
- 223867
- Product name
- Tolylene-2,6-diisocyanate
- Purity
- 97%
- Packaging
- 5g
- Price
- $213
- Updated
- 2024/03/01
- Product number
- T1153
- Product name
- Tolylene-2,6-diisocyanate
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $41
- Updated
- 2024/03/01
- Product number
- T1153
- Product name
- Tolylene-2,6-diisocyanate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $125
- Updated
- 2024/03/01
2-METHYL-M-PHENYLENE DIISOCYANATE Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Uses
2-Methyl-m-phenylene Diisocyanate is used in method for preparing breathable sweat-absorbing EVA foam shoe material.
Uses
2,6-TDI may be used as a reference standard for the quantification of residual 2,6-TDI in foam samples using high performance liquid chromatography coupled to coordination-ionspray tandem mass spectrometry (HPLC-CIS-MS/MS).
Definition
ChEBI: A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring.
Synthesis Reference(s)
The Journal of Organic Chemistry, 60, p. 257, 1995 DOI: 10.1021/jo00106a044
General Description
Liquid. Used in the manufacture of polyurethane foams, elastomers, and coatings; crosslinking agent for nylon 6.
Reactivity Profile
2-METHYL-M-PHENYLENE DIISOCYANATE reacts violently with amines, alcohols, bases and warm water, causing fire and explosion hazards. [Handling Chemcials Safely 1980. p. 907]. Reaction with water to form Carbon Dioxide [Merck 11th ed. 1989].
Health Hazard
Classified as slightly toxic orally. Probable oral lethal dose in humans is 5 to 15 g/kg or between 1 pint and 1 quart for a 70 (l50 lb.) person. Particularly poisonous when breathed. This is among the most poisonous of isocyanates. Acute and chronic exposures to low concentrations may produce asthmatic attacks.
Fire Hazard
When heated to decomposition, 2-METHYL-M-PHENYLENE DIISOCYANATE emits toxic fumes of nitrogen oxides. Ventilation should be adequate. If polyurethane products are heated, protection against isocyanate release is necessary. Avoid decomposing heat.
Flammability and Explosibility
Non flammable
Safety Profile
Confirmed carcinogen. Poison by ingestion and inhalation. Human systemic effects by inhalation: olfactory, eye, and pulmonary changes. Flammable liquid. When heated to decomposition it emits toxic fumes of NOx. See also CYANATES.
Purification Methods
It is purified by fractional distillation in a vacuum. Store it under N2 in sealed dark ampoules as it is water and light sensitive. Like the preceding 2,4-isomer, it has a sharp pungent odour, is TOXIC and is IRRITATING TO THE EYES. [Beilstein 13 IV 259.]
2-METHYL-M-PHENYLENE DIISOCYANATE Preparation Products And Raw materials
Raw materials
Preparation Products
2-METHYL-M-PHENYLENE DIISOCYANATE Suppliers
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View Lastest Price from 2-METHYL-M-PHENYLENE DIISOCYANATE manufacturers
- Product
- 2-METHYL-M-PHENYLENE DIISOCYANATE 91-08-7
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2023-01-10
- Product
- 2-METHYL-M-PHENYLENE DIISOCYANATE 91-08-7
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-15