ChemicalBook > CAS DataBase List > (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

Product Name
(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
CAS No.
179866-74-1
Chemical Name
(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
Synonyms
(R)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOX&;6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(R)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(S)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl;(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXYBINAPHTHALENE);(R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene;(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(1R)-6,6'-dibroMo-2,2'-bis(MethoxyMethoxy)-1,1'-binaphthalene;(S)-(-)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
CBNumber
CB1423787
Molecular Formula
C24H20Br2O4
Formula Weight
532.22
MOL File
179866-74-1.mol
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(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Property

Melting point:
129-133 °C(lit.)
alpha 
+13° (c 0.22, CHCl3)
Boiling point:
553.0±50.0 °C(Predicted)
Density 
1.524±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Toluene
form 
powder to crystal
color 
White to Almost white
CAS DataBase Reference
179866-74-1
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Safety

Hazard Codes 
Xi
Risk Statements 
41
Safety Statements 
25-26-36/39
WGK Germany 
3
HS Code 
2909.30.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
D4882
Product name
(R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
Purity
>98.0%(HPLC)(T)
Packaging
1g
Price
$177
Updated
2024/03/01
TCI Chemical
Product number
D4882
Product name
(R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$526
Updated
2024/03/01
Strem Chemicals
Product number
08-0152
Product name
(R)-(+)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene, min. 98% (99% ee)
Packaging
100mg
Price
$72
Updated
2024/03/01
Strem Chemicals
Product number
08-0152
Product name
(R)-(+)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene, min. 98% (99% ee)
Packaging
500mg
Price
$302
Updated
2024/03/01
Strem Chemicals
Product number
08-0620
Product name
(R)-(+)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl, min. 98%
Packaging
250mg
Price
$70
Updated
2024/03/01
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(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Chemical Properties,Usage,Production

Uses

An intermediate in the symmetric synthesis of BINOL-terpyridine ligands.

Uses

An intermediate in the symmetric synthesis of BINOL-terpyridine ligands, and the starting material for the preparation of a variety of 6,6' and 3,3'-substituted BINOLS. .

(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Suppliers

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Advantage
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179866-74-1, (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYLRelated Search:

(R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL (R)-(+)-1,1'-Bi-2-naphthol (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL (R)-(+)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL (S)-2'-Methoxy-[1,1']binaphthalenyl-2-ol 2-Bromo-6-methoxynaphthalene

  • 6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXYBINAPHTHALENE)
  • (R)-(+)-6,6''-DIBROMO-2,2''-BIS(METHOXYMETHOXY)-1,1''-BINAPHTHYL, MIN. 98%
  • (R)-(+)-6,6'-Dibromo-2,2'-Bis(Methoxymethoxy)-1,1'-Binaphthyl,98%
  • 1,1'-Binaphthalene,6,6'-dibroMo-2,2'-bis(MethoxyMethoxy)-, (1R)-
  • (1R)-6,6'-dibroMo-2,2'-bis(MethoxyMethoxy)-1,1'-binaphthalene
  • (<i>R</i>)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
  • (R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphth alene, 99%e.e.
  • (R)-(+)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene, min. 98% (99% ee)
  • (R)-(+)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • (R)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • (S)-(-)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHALENE
  • (S)-(-)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • (S)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • (R)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOX&
  • (R)-(+)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl,min.98%
  • (r)-(+)-6,6'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene
  • (R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
  • (R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene
  • 179866-74-1
  • CH3OCH2OC10H5Br2
  • C24H20Br2O4
  • Privileged Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • BINOLs
  • BINOL Series
  • Chiral Oxygen
  • Aromatics
  • Chiral Reagents
  • Intermediates & Fine Chemicals
  • Pharmaceuticals