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Terephthalaldehyde

Product Name
Terephthalaldehyde
CAS No.
623-27-8
Chemical Name
Terephthalaldehyde
Synonyms
1,4-PHTHALALDEHYDE;Terephthaldehyde;1,4-BENZENEDICARBOXALDEHYDE;TEREPHTHALDICARBOXALDEHYDE;P-benzaldehyde;P-PHTHALALDEHYDE;TPAL;Benzene-1,4-dialdehyde;4-Formylbenzaldehyde;Terephtaldehyde
CBNumber
CB1425781
Molecular Formula
C8H6O2
Formula Weight
134.13
MOL File
623-27-8.mol
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Terephthalaldehyde Property

Melting point:
114-116 °C (lit.)
Boiling point:
245-248 °C (lit.)
Density 
1,06 g/cm3
vapor pressure 
0.25-0.46Pa at 20-25℃
refractive index 
1.4800 (estimate)
Flash point:
76 °C
storage temp. 
Store below +30°C.
solubility 
3g/l
form 
Crystalline Powder
color 
White to light yellow
Water Solubility 
3 g/L (50 ºC)
Sensitive 
Air Sensitive
BRN 
385863
InChIKey
KUCOHFSKRZZVRO-UHFFFAOYSA-N
LogP
1 at 20.1℃ and pH6.6-6.8
CAS DataBase Reference
623-27-8(CAS DataBase Reference)
NIST Chemistry Reference
1,4-Benzenedicarboxaldehyde(623-27-8)
EPA Substance Registry System
1,4-Benzenedicarboxaldehyde (623-27-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36/37
Safety Statements 
22-24/25-36-26-37/39
WGK Germany 
1
RTECS 
WZ0430000
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29122900
Hazardous Substances Data
623-27-8(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
T2207
Product name
Terephthalaldehyde
Purity
ReagentPlus , 99%
Packaging
5g
Price
$40.6
Updated
2024/03/01
Sigma-Aldrich
Product number
T2207
Product name
Terephthalaldehyde
Purity
ReagentPlus , 99%
Packaging
100g
Price
$74.4
Updated
2024/03/01
Sigma-Aldrich
Product number
8.08617
Product name
Terephthaldialdehyde
Purity
for synthesis
Packaging
100g
Price
$78.8
Updated
2024/03/01
TCI Chemical
Product number
T0010
Product name
Terephthalaldehyde
Purity
>98.0%(GC)
Packaging
25g
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
T0010
Product name
Terephthalaldehyde
Purity
>98.0%(GC)
Packaging
100g
Price
$86
Updated
2024/03/01
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Terephthalaldehyde Chemical Properties,Usage,Production

Description

Terephthalaldehyde is an aromatic dialdehyde. Theoretically, the two aldehydes of terephthalaldehyde (TPA) are equivalent, so the single or double Schiff base from TPA and d-glucosamine (Glc) may be formed at the same time. It is used as an intermediate for the preparation of dyes and fluorescent whitening agents and in the synthesis of polyimines by reacting with aliphatic diamines. It is also used as a precursor for the preparation of paramagnetic microporous polymeric organic frameworks (POFs) through copolymerization with pyrrole, indole, and carbazole. As a good crosslinking agent, it could used in crosslinked chitosan hydrogel for the selective removal of anionic dyes[1].

Chemical Properties

WHITE TO LIGHT YELLOW CRYSTALLINE POWDER

Uses

Terephthalaldehyde (cas# 623-27-8) is a compound useful in organic synthesis.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 3, p. 788, 1955
Tetrahedron Letters, 36, p. 2285, 1995 DOI: 10.1016/0040-4039(95)00191-E

Purification Methods

Terephthalaldehyde [623-27-8] M 134.1, m 116o, b 245 -248o/771mm. Crystallise terephthalaldehyde from water. [Beilstein 7 IV 2140.]

References

[1] Weng Q, et al. Controllable Synthesis and Biological Application of Schiff Bases from d-Glucosamine and Terephthalaldehyde. ACS Omega, 2020; 5: 24864–24870.

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Terephthalaldehyde Suppliers

Molekula Limited
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Key Organics Ltd.
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Manchester Organics
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Apollo Scientific Ltd.
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Tokyo Chemical Industry UK Ltd.
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Apin Chemicals Limited (UK)
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Leancare Ltd.
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Hawks Scientific Ltd
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CARBONE SCIENTIFIC CO.,LTD
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Eurolabs Limited
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MOLEKULA Ltd.
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ARIAC - Armenian Institute of Applied Chemistry
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VWR International
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View Lastest Price from Terephthalaldehyde manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Terephthalaldehyde 623-27-8
Price
US $180.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-13
Hebei Longbang Technology Co., Ltd
Product
Terephthalaldehyde 623-27-8
Price
US $6.00/kg
Min. Order
1kg
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-05-27
Hebei Saisier Technology Co., LTD
Product
Terephthalaldehyde 623-27-8
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/MONTH
Release date
2024-04-22

623-27-8, TerephthalaldehydeRelated Search:


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