Terephthaloyl chloride
- Product Name
- Terephthaloyl chloride
- CAS No.
- 100-20-9
- Chemical Name
- Terephthaloyl chloride
- Synonyms
- TCL;Terephtaloyl chloride;TEREPHTHALOYL DICHLORIDE;1,4-Benzenedicarbonyl dichloride;P-PHTHALOYL CHLORIDE;TEREPHTHALYL CHLORIDE;1,4-dichloroformylbenzene;p-PhthaL;bis(forMaldehyde);phenylchloranuide
- CBNumber
- CB5852556
- Molecular Formula
- C8H4Cl2O2
- Formula Weight
- 203.02
- MOL File
- 100-20-9.mol
Terephthaloyl chloride Property
- Melting point:
- 79-81 °C(lit.)
- Boiling point:
- 266 °C(lit.)
- Density
- 1,34 g/cm3
- vapor density
- 7 (vs air)
- vapor pressure
- 0.02 mm Hg ( 25 °C)
- refractive index
- 1.5684 (estimate)
- Flash point:
- 356 °F
- storage temp.
- 2-8°C
- solubility
- ethanol: 5%, clear
- form
- flakes
- color
- White to Almost white
- PH
- <0.5 (H2O)
- explosive limit
- 1.5-8.9%(V)
- Water Solubility
- REACTS
- Sensitive
- Moisture Sensitive
- BRN
- 607796
- InChIKey
- LXEJRKJRKIFVNY-UHFFFAOYSA-N
- CAS DataBase Reference
- 100-20-9(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,4-Benzenedicarbonyl dichloride(100-20-9)
- EPA Substance Registry System
- 1,4-Benzenedicarbonyl dichloride (100-20-9)
Safety
- Hazard Codes
- C,T
- Risk Statements
- 34-23-35
- Safety Statements
- 26-27-36/37/39-45-38-28B
- RIDADR
- UN 2923 8/PG 3
- WGK Germany
- 3
- RTECS
- WZ1797000
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29173980
- Hazardous Substances Data
- 100-20-9(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H331Toxic if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 120871
- Product name
- Terephthaloyl chloride
- Purity
- ≥99%, flakes
- Packaging
- 5g
- Price
- $36.4
- Updated
- 2024/03/01
- Product number
- 120871
- Product name
- Terephthaloyl chloride
- Purity
- ≥99%, flakes
- Packaging
- 1kg
- Price
- $139
- Updated
- 2024/03/01
- Product number
- T0017
- Product name
- Terephthaloyl Chloride
- Purity
- >99.0%(GC)(T)
- Packaging
- 100g
- Price
- $23
- Updated
- 2024/03/01
- Product number
- T0017
- Product name
- Terephthaloyl Chloride
- Purity
- >99.0%(GC)(T)
- Packaging
- 25g
- Price
- $18
- Updated
- 2024/03/01
- Product number
- A11224
- Product name
- Terephthaloyl chloride, 99%
- Packaging
- 250g
- Price
- $47.7
- Updated
- 2024/03/01
Terephthaloyl chloride Chemical Properties,Usage,Production
Chemical Properties
monoclinic crystals or white crystalline flakes. Soluble in ethanol and organic solvents.
Uses
Terephthaloyl chloride and Isophthaloyl dichloride have many similar uses as monomers for the synthesis of specialty fibers and as raw materials for polymers such as polyamides and polyesters. Dyemanufacture; synthetic fibers, resins, films; UV absorption; pharmaceuticals; rubber chemicals; cross-linking agent for polyurethanes and polysulfides.
Uses
Terephthaloyl chloride acts as a monomer with p-phenylenediamine used in the preparation of polymer viz. poly paraphenylene terephthalamide. It is an active component in performance polymers and aramid fibers, which gives flame resistance, chemical resistance, temperature stability, light weight, and very high strength. It is also used as an effective water scavenger, utilized to stabilize isocyanates and urethane prepolymers. Further, it is used in the preparation of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates. In addition to this, it is involved in the condensation reaction with difunctional alfa, μ-diaminopolystyrene to get chain-extended polystyrene containing amide bonds along the polymer backbone.
Preparation
Synthesis of terephthaloyl chloride by thionyl chloride method: terephthalic acid is mixed with thionyl chloride, refluxed at 80℃ for 10-12h, then the thionyl chloride is evaporated, and the resulting crude product is distilled under reduced pressure to obtain the finished product.
General Description
Terephthaloyl chloride undergoes condensation reaction with difunctional α,ω-diaminopolystyrene to yield chain-extended polystyrene containing amide bonds along the polymer backbone. It undergoes interfacial reaction with bovine serum albumin to form thin cross-linked films.
Hazard
Skin irritant.
Flammability and Explosibility
Non flammable
Safety Profile
Moderately toxic by ingestion. Corrosive. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORIDES.
Purification Methods
Crystallise the acid chloride from dry hexane. [Beilstein 9 IV 3318.]
Terephthaloyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Terephthaloyl chloride manufacturers
- Product
- Terephthaloyl chloride 100-20-9
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20 tons
- Release date
- 2023-11-28
- Product
- Terephthaloyl chloride 100-20-9
- Price
- US $9.50/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100ton
- Release date
- 2024-08-23
- Product
- Terephthaloyl chloride 100-20-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-11-29