ChemicalBook > CAS DataBase List > 4-tert-Butylphenylboronic acid

4-tert-Butylphenylboronic acid

Product Name
4-tert-Butylphenylboronic acid
CAS No.
123324-71-0
Chemical Name
4-tert-Butylphenylboronic acid
Synonyms
AKOS BRN-0058;CAS:123324-71-0;RARECHEM AH PB 0112;4-tert-Butylphenylbo;P-tert-butylbenzeneboronic;4-T-BUTYLPHENYLBORONIC ACID;P-T-BUTYLPHENYLBORONIC ACID;4-t-Butylbenzeneboronic acid;4-tert-Butylphenylboronicaci;4-TERT-BUTYLPHENYLBORONIC ACID
CBNumber
CB1432682
Molecular Formula
C10H15BO2
Formula Weight
178.04
MOL File
123324-71-0.mol
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4-tert-Butylphenylboronic acid Property

Melting point:
191-196 °C (lit.)
Boiling point:
296.7±33.0 °C(Predicted)
Density 
1.02±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Methanol
pka
8.79±0.10(Predicted)
form 
Crystalline Powder
color 
White to off-white
BRN 
5330959
InChI
InChI=1S/C10H15BO2/c1-10(2,3)8-4-6-9(7-5-8)11(12)13/h4-7,12-13H,1-3H3
InChIKey
MNJYZNVROSZZQC-UHFFFAOYSA-N
SMILES
B(C1=CC=C(C(C)(C)C)C=C1)(O)O
CAS DataBase Reference
123324-71-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-22-20/21/22-R36/37/38
Safety Statements 
37/39-26-36-S37/39-S26
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
480053
Product name
4-tert-Butylphenylboronic acid
Purity
≥95.0%
Packaging
5g
Price
$26.8
Updated
2025/07/31
Sigma-Aldrich
Product number
480053
Product name
4-tert-Butylphenylboronic acid
Purity
≥95.0%
Packaging
25g
Price
$48.7
Updated
2025/07/31
TCI Chemical
Product number
B2251
Product name
4-tert-Butylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$23
Updated
2025/07/31
TCI Chemical
Product number
B2251
Product name
4-tert-Butylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
25g
Price
$92
Updated
2025/07/31
TRC
Product number
B809363
Product name
4-t-ButylphenylboronicAcid
Packaging
1g
Price
$55
Updated
2021/12/16
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4-tert-Butylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

suzuki reaction

Uses

4-t-Butylphenylboronic acid is a cross-coupling building block used in the preparation of tetracyclnes and tetracycline derivatives.

Uses

Cross-coupling building block used in synthesis of tetracycline derivatives.

Synthesis

3972-65-4

123324-71-0

4-tert-butylbromobenzene was used as starting material and 4-tert-butylphenylboronic acid (4b) was synthesized according to the method described in literature [22] in 72.8% reaction yield. The resulting product was a white solid with a melting point of 158-160 °C (literature value: 160 °C). The structure of the product was confirmed by 1H NMR spectrum (CD3Cl as solvent, 300 MHz): δ 8.17 (d, 2H, J = 6.6 Hz), 7.42-7.54 (m, 2H), 1.38 (s, 9H).

References

[1] Tetrahedron Letters, 2003, vol. 44, # 30, p. 5747 - 5750
[2] Macromolecules, 2003, vol. 36, # 7, p. 2327 - 2332
[3] Organic and Biomolecular Chemistry, 2012, vol. 10, # 33, p. 6693 - 6704
[4] Dyes and Pigments, 2012, vol. 95, # 3, p. 679 - 688
[5] Journal of the Chemical Society. Perkin Transactions 2, 2001, # 11, p. 2166 - 2173

4-tert-Butylphenylboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate 1-Bromo-4-tert-butylbenzene Magnesium

Preparation Products

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4-tert-Butylphenylboronic acid Suppliers

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View Lastest Price from 4-tert-Butylphenylboronic acid manufacturers

Yancheng Green Chemicals Co.,Ltd
Product
4-tert-Butylphenylboronic acid 123324-71-0
Price
US $171.50-4287.50/kg
Min. Order
1kg
Purity
≥99.0%
Supply Ability
10 tons
Release date
2023-08-09
Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-tert-Butylphenylboronic acid 123324-71-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-06
Henan Fengda Chemical Co., Ltd
Product
4-tert-Butylphenylboronic acid 123324-71-0
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08

123324-71-0, 4-tert-Butylphenylboronic acidRelated Search:

4-tert-Butylphenol n-Butylboronic acid Butyl acetate 4-tert-Butylcatechol Cyhalofop-butyl tert-Butyl peroxyacetate tert-Butanol Phenylboronic acid Methyl 4-tert-butylbenzoate tert-Butyl hydroperoxide Di-tert-butyl peroxide Buprofezin tert-Butyldimethylsilyl chloride tert-Butyl methyl ether 4-Tolylboronic acid tert-Butylbenzene Methyl p-tert-butylphenylacetate tert-Butyl acetate

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  • CAS:123324-71-0
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  • 123324-71-0
  • 12324-71-0
  • 123324-79-4
  • CH33CC6H4BOH2
  • C10H15BO2
  • B (Classes of Boron Compounds)
  • Boronic Acids
  • BORONIC ACID
  • Organometallic Reagents
  • Aryl
  • Boronic Acids and Derivatives
  • Heterocyclic Compounds
  • Boronic Acid
  • Aryl
  • Organoborons
  • Substituted Boronic Acids
  • Boron, Nitrile, Thio,& TM-Cpds
  • Boronic Acids
  • Boronic Acids and Derivatives
  • B (Classes of Boron Compounds)
  • Boronic acids
  • blocks
  • BoronicAcids
  • Boronic Acid series