4-tert-Butylphenylboronic acid

Product Name: 4-tert-Butylphenylboronic acid
CAS No.: 123324-71-0
Chemical Name: 4-tert-Butylphenylboronic acid
Synonyms: AKOS BRN-0058;CAS:123324-71-0;RARECHEM AH PB 0112;4-tert-Butylphenylbo;P-tert-butylbenzeneboronic;4-T-BUTYLPHENYLBORONIC ACID;P-T-BUTYLPHENYLBORONIC ACID;4-t-Butylbenzeneboronic acid;4-tert-Butylphenylboronicaci;4-TERT-BUTYLPHENYLBORONIC ACID
CBNumber: CB1432682
Molecular Formula: C10H15BO2
Formula Weight: 178.04
MOL File: 123324-71-0.mol

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4-tert-Butylphenylboronic acid Property

Melting point:: 191-196 °C (lit.)
Boiling point:: 296.7±33.0 °C(Predicted)
Density: 1.02±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
pka: 8.79±0.10(Predicted)
form: Crystalline Powder
color: White to off-white
BRN: 5330959
InChI: InChI=1S/C10H15BO2/c1-10(2,3)8-4-6-9(7-5-8)11(12)13/h4-7,12-13H,1-3H3
InChIKey: MNJYZNVROSZZQC-UHFFFAOYSA-N
SMILES: B(C1=CC=C(C(C)(C)C)C=C1)(O)O
CAS DataBase Reference: 123324-71-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 36/37/38-22-20/21/22-R36/37/38
Safety Statements: 37/39-26-36-S37/39-S26
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 480053
Product name: 4-tert-Butylphenylboronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $26.8
Updated: 2025/07/31

Sigma-Aldrich

Product number: 480053
Product name: 4-tert-Butylphenylboronic acid
Purity: ≥95.0%
Packaging: 25g
Price: $48.7
Updated: 2025/07/31

TCI Chemical

Product number: B2251
Product name: 4-tert-Butylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $23
Updated: 2025/07/31

TCI Chemical

Product number: B2251
Product name: 4-tert-Butylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 25g
Price: $92
Updated: 2025/07/31

TRC

Product number: B809363
Product name: 4-t-ButylphenylboronicAcid
Packaging: 1g
Price: $55
Updated: 2021/12/16

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4-tert-Butylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

suzuki reaction

Uses

4-t-Butylphenylboronic acid is a cross-coupling building block used in the preparation of tetracyclnes and tetracycline derivatives.

Uses

Cross-coupling building block used in synthesis of tetracycline derivatives.

Synthesis

3972-65-4

123324-71-0

4-tert-butylbromobenzene was used as starting material and 4-tert-butylphenylboronic acid (4b) was synthesized according to the method described in literature [22] in 72.8% reaction yield. The resulting product was a white solid with a melting point of 158-160 °C (literature value: 160 °C). The structure of the product was confirmed by 1H NMR spectrum (CD3Cl as solvent, 300 MHz): δ 8.17 (d, 2H, J = 6.6 Hz), 7.42-7.54 (m, 2H), 1.38 (s, 9H).

References

[1] Tetrahedron Letters, 2003, vol. 44, # 30, p. 5747 - 5750
[2] Macromolecules, 2003, vol. 36, # 7, p. 2327 - 2332
[3] Organic and Biomolecular Chemistry, 2012, vol. 10, # 33, p. 6693 - 6704
[4] Dyes and Pigments, 2012, vol. 95, # 3, p. 679 - 688
[5] Journal of the Chemical Society. Perkin Transactions 2, 2001, # 11, p. 2166 - 2173

4-tert-Butylphenylboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate 1-Bromo-4-tert-butylbenzene Magnesium

Preparation Products

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4-tert-Butylphenylboronic acid Suppliers

Americas 1 Belgium 3 China 326 Europe 5 France 4 Germany 17 India 29 Italy 1 Japan 4 Jordan 1 Russia 1 South Korea 1 Switzerland 2 Ukraine 1 United Kingdom 20 United States 60 Global 476

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View Lastest Price from 4-tert-Butylphenylboronic acid manufacturers

Yancheng Green Chemicals Co.,Ltd

Product: 4-tert-Butylphenylboronic acid 123324-71-0
Price: US $171.50-4287.50/kg
Min. Order: 1kg
Purity: ≥99.0%
Supply Ability: 10 tons
Release date: 2023-08-09

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 4-tert-Butylphenylboronic acid 123324-71-0
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-12-06

Henan Fengda Chemical Co., Ltd

Product: 4-tert-Butylphenylboronic acid 123324-71-0
Price: US $34.00-1.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

123324-71-0, 4-tert-Butylphenylboronic acidRelated Search:

4-tert-Butylphenol n-Butylboronic acid Butyl acetate 4-tert-Butylcatechol Cyhalofop-butyl tert-Butyl peroxyacetate tert-Butanol Phenylboronic acid Methyl 4-tert-butylbenzoate tert-Butyl hydroperoxide Di-tert-butyl peroxide Buprofezin tert-Butyldimethylsilyl chloride tert-Butyl methyl ether 4-Tolylboronic acid tert-Butylbenzene Methyl p-tert-butylphenylacetate tert-Butyl acetate

4-T-BUTYLPHENYLBORONIC ACID

4-TERT-BUTYLBENZENEBORONIC ACID

4-TERT-BUTYLPHENYLBORONIC ACID

AKOS BRN-0058

RARECHEM AH PB 0112

P-T-BUTYLPHENYLBORONIC ACID

[4-(1,1-Dimethylethyl)phenyl]boronic acid

4-t-Butylbenzeneboronic acid

p-tert-Butylbenzeneboronic acid

4-<i>tert</i>-Butylphenylboronic acid (contains varying amounts of anhydride)

4-tert-Butylphenylboronic acid >=95.0%

AKOS BRN-0058;4-T-BUTYLPHENYLBORONIC ACID;4-TERT-BUTYLBENZENEBORONIC ACID;4-TERT-BUTYLPHENYLBORONIC ACID;RARECHEM AH PB 0112;P-T-BUTYLPHENYLBORONIC ACID;4-TERT-BUTYLPHENYLBORONICACID97+%;4-TERT-BUTYLBENZENEBORONIC ACI

4-Tert-ButylphenylboronicAcid97+%

4-TERT-BUTYLBENZENEBORONIC ACID 97%

4-tert-Butylphenylboronic Acid (contains varying amounts of Anhydride)

4-tert-Butylbenzeneboronic acid ,98%

4-(tert-Butyl)phenylboronic acid, May contain varying amounts of anhydride, 97%

4-tert-Butylphenylbo

4-tert-Butylphenylboronic acid, 97% 5GR

4-TERT-BUTYLBENZENEBORONIC ACID; 4-(TERT-BUTYL)PHENYLBORONIC ACID

para-tert-butylphenylboronic acid

(p-tert-Butylphenyl)boronic acid

4-tert-Butylphenylboronic acid，98%

Boronic acid, B-[4-(1,1-dimethylethyl)phenyl]-

4-tert-Butylphenylboronicaci

123324-71-0 4-tert-Butylphenylboronic acid

CAS:123324-71-0

4-<i>tert</i>-Butylphenylboronic acid

(4-(tert-Butyl)phenyl)boronic acid - [B2080]

P-tert-butylbenzeneboronic

123324-71-0

12324-71-0

123324-79-4

CH33CC6H4BOH2

C10H15BO2

B (Classes of Boron Compounds)

Boronic Acids

BORONIC ACID

Organometallic Reagents

Aryl

Boronic Acids and Derivatives

Heterocyclic Compounds

Boronic Acid

Aryl

Organoborons

Substituted Boronic Acids

Boron, Nitrile, Thio,& TM-Cpds

Boronic Acids

Boronic Acids and Derivatives

B (Classes of Boron Compounds)

Boronic acids

blocks

BoronicAcids

Boronic Acid series