ChemicalBook > CAS DataBase List > 2-CHLOROPHENYLZINC IODIDE

2-CHLOROPHENYLZINC IODIDE

Product Name
2-CHLOROPHENYLZINC IODIDE
CAS No.
148651-35-8
Chemical Name
2-CHLOROPHENYLZINC IODIDE
Synonyms
2-CHLOROPHENYLZINC IODIDE;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
CBNumber
CB1436675
Molecular Formula
C6H4ClIZn
Formula Weight
303.84
MOL File
148651-35-8.mol
More
Less

2-CHLOROPHENYLZINC IODIDE Property

Density 
0.973 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Sensitive 
Air & Light Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference
148651-35-8
More
Less

Safety

Hazard Codes 
F,Xn
Risk Statements 
11-19-22-36/37/38-40-36/37
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 2056 3/PG 2
WGK Germany 
1
HazardClass 
4.3
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
499803
Product name
2-Chlorophenylzinc iodide solution
Purity
0.5M in THF
Packaging
50ml
Price
$273
Updated
2023/06/20
Alfa Aesar
Product number
H58383
Product name
2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$216
Updated
2021/12/16
Rieke Metals
Product number
2135
Product name
2-Chlorophenylzinciodide
Packaging
100mL
Price
$755
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005751
Product name
2-CHLOROPHENYLZINC IODIDE
Purity
95.00%
Packaging
50ML
Price
$2760.45
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005751
Product name
2-CHLOROPHENYLZINC IODIDE
Purity
95.00%
Packaging
100ML
Price
$3106.95
Updated
2021/12/16
More
Less

2-CHLOROPHENYLZINC IODIDE Chemical Properties,Usage,Production

Uses

2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:

  • Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
  • (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
  • Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.

2-CHLOROPHENYLZINC IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

2-CHLOROPHENYLZINC IODIDE Suppliers

China 11 India 1 Switzerland 1 United States 3 Global 16
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
Rieke Metals, Inc.
Tel
--
Fax
--
Email
sales@riekemetals.com
Country
United States
ProdList
6509
Advantage
69

148651-35-8, 2-CHLOROPHENYLZINC IODIDERelated Search:

4-ETHOXY-4-OXOBUTYLZINC BROMIDE 5-(1,3-DIOXOLAN-2-YL)-2-THIENYLZINC BROMIDE 1-HEXYLZINC BROMIDE CYCLOPROPYLZINC BROMIDE SOLUTION 0.5M I& (1,3-DIOXOLAN-2-YLETHYL)ZINC BROMIDE 4-CHLOROBUTYLZINC BROMIDE 1-METHYLHEXYLZINC BROMIDE PHENYLZINC BROMIDE 1-METHYLBUTYLZINC BROMIDE (1,3-DIOXAN-2-YLETHYL)ZINC BROMIDE 5-ETHOXY-5-OXOPENTYLZINC BROMIDE 6-ETHOXY-6-OXOHEXYLZINC BROMIDE 2,3-DICHLOROPHENYLZINC IODIDE 2,4-DICHLOROPHENYLZINC IODIDE 2-CHLORO-4-FLUOROPHENYLZINC IODIDE 2-CHLOROPHENYLZINC IODIDE 2,5-DICHLOROPHENYLZINC IODIDE 2-CHLORO-6-METHYLPHENYLZINC IODIDE

  • 2-CHLOROPHENYLZINC IODIDE
  • 2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
  • 2-chlorophenylzinc iodide solution
  • 2-Chlorophenylzinc iodide solution 0.5 in THF
  • 2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles
  • 2-Chlorophenylzinc iodide solution 0.5M in THF
  • 2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran
  • 2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
  • 148651-35-8
  • ClC6H4ZnI
  • Aryl
  • Organozinc Halides
  • Organometallic Reagents
  • Reike and Organozinc Reagents
  • Aryl
  • Organozinc Halides
  • Reike and Organozinc Reagents